Relaxivity in paramagnetic systems: Theory and mechanisms

Progress in Nuclear Magnetic Resonance Spectroscopy

Volumn 49, Issue 1, 2006, Pages 45-64

  Helm, Lothar ^a  

^a INSTITUTE OF CHEMICAL SCIENCES AND ENGINEERING   (Switzerland)

Author keywords

EPR relaxation; MRI contrast agents; Paramagnetic NMR relaxation; Zero field splitting

Indexed keywords

MAGNETIC FIELDS; MOLECULAR ORIENTATION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PARAMAGNETIC RESONANCE; PARAMAGNETISM; RELAXATION PROCESSES;

EPR RELAXATION; MRI CONTRAST AGENTS; PARAMAGNETIC NMR RELAXATION; ZERO-FIELD SPLITTING;

PARAMAGNETIC MATERIALS;

EID: 33748116158     PISSN: 00796565     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.pnmrs.2006.03.003     Document Type: Review

References (112)

1. Banci L., Bertini I., and Luchinat C. Nuclear and Electron Relaxation (1991), VCH, Weinheim
2. Bertini I., and Luchinat C. Coord. Chem. Rev. 150 (1996) 1
3. Bertini I., Luchinat C., and Parigi G. Solution NMR of Paramagnetic Molecules vol. 2 (2001), Elsevier, Amsterdam
4. Bertini I., Luchinat C., and Parigi G. Prog. NMR Spectrosc. 40 (2002) 249
5. Bertini I., Luchinat C., Parigi G., and Pierattelli R. Chem. Biol. Chem. 6 (2005) 1536
6. Bertini I., Luchinat C., and Parigi G. In: van Eldik R., and Bertini I. (Eds). Advances in Inorganic Chemistry vol. 57 (2005), Elsevier, San Diego 105-172
7. Aime S., Botta M., Fasano M., Crich S.G., and Terreno E. Coord. Chem. Rev. 185-186 (1999) 321
8. Caravan P., Ellison J.J., McMurry T.J., and Lauffer R.B. Chem. Rev. 99 (1999) 2293
9. In: Merbach A.E., and Tóth E. (Eds). The Chemistry of Contrast Agents in Medical Magnetic Resonance Imaging (2001), John Wiley & Sons, Chichester
10. Aime S., Cabella C., Colombatto S., Crich S.G., Gianolio E., and Maggioni F. J. Magn. Reson. Imag. 16 (2002) 394
11. Helm L., Tóth E., and Merbach A.E. In: Sigel H., and Sigel A. (Eds). Lanthanides and Their Interrelations with Biosystems vol. 40 (2003), Marcel Dekker Inc, New York 589-641
12. Tóth E., Helm L., and Merbach A.E. In: Ward M. (Ed). Applications of Coordination Chemistry vol. 9 (2004), Elsevier, Oxford 841-881
13. Aime S., Botta M., and Terreno E. In: van Eldik R., and Bertini I. (Eds). Advances in Inorganic Chemistry vol. 57 (2005), Elsevier, San Diego 173-237
14. Muller R.N., Vander Elst L., Roch A., Peters J.A., Csajbok E., Gillis P., and Gossuin Y. In: van Eldik R., and Bertini I. (Eds). Advances in Inorganic Chemistry vol. 57 (2005), Elsevier, San Diego 239-292
15. Swift T.J. In: La Mar G.N., et al. (Ed). NMR of Paramagnetic Molecules vol. (1973), Academic Press, New York 53-83
16. Luz Z., and Meiboom S. J. Chem. Phys. 40 (1964) 2686
17. Swift T.J., and Connick R.E. J. Chem. Phys. 37 (1962) 307
18. Swift T.J., and Connick R.E. J. Chem. Phys. 41 (1964) 2553
19. Helm L., Nicolle G.M., and Merbach A.E. In: van Eldik R., and Bertini I. (Eds). Advances in Inorganic Chemistry vol. 57 (2005), Elsevier, San Diego 327-379
20. Koenig S.H., and Schillinger W.E. J. Biol. Chem. 244 (1969) 3283
21. Luchinat C. Magn. Reson. Chem. 31 (1993) S145
22. Kimmich R. NMR - Tomography, Diffusometry, Relaxometry (1997), Springer, Berlin
23. Noack F. Prog. NMR Spectrosc. 18 (1986) 171
24. Koenig S.H., and Brown III R.D. Prog. NMR Spectrosc. 22 (1990) 487
25. Anoardo E., Galli G., and Ferrante G. Appl. Magn. Reson. 20 (2001) 365
26. Ferrante G., and Sykora S. In: van Eldik R., and Bertini I. (Eds). Advances in Inorganic Chemistry vol. 57 (2005), Elsevier, San Diego 405-470
27. Johannesson H., Denisov V.P., and Halle B. Protein Sci. 6 (1997) 1756
28. V.P. Denisov, C. Hall, Biochemistry 37 (1098) 9595.
29. Törnblom M., Sitnikov R., and Henriksson U. J. Phys. Chem. B 104 (2000) 1529
30. Chen sJ.W., Belford R.L., and Clarkson R.B. J. Phys. Chem. A 102 (1998) 2117
31. Chen J.W., Clarkson R.B., and Belford R.L. J. Phys. Chem. 100 (1996) 8093
32. Solomon I. Phys. Rev. 99 (1955) 559
33. Bloembergen N. J. Chem. Phys. 27 (1957) 572
34. Bloembergen N., and Morgan L.O. J. Chem. Phys. 34 (1961) 842
35. Kowalewski J., Nordenskiöld L., Benetis N., and Westlund P. Prog. NMR Spectrosc. 17 (1985) 141
36. McConnell J.R. The Theory of Nuclear Magnetic Relaxation in Liquids (1987), Cambridge University Press, Cambridge
37. Solomon I., and Bloembergen N. J. Chem. Phys. 25 (1956) 261
38. Hwang L., and Freed J.H. J. Chem. Phys. 63 (1975) 4017
39. Freed J.H. J. Chem. Phys. 69 (1978) 4034
40. Ayant Y., Belorizky E., Alizon J., and Gallice J. J. de Physque 36 (1975) 991
41. Ayant Y., Belorizky E., Fries P.H., and Rosset J. J. de Physque 38 (1977) 325
42. Botta M. Eur. J. Inorg. Chem. (2000) 399
43. Rudovsky J., Cigler P., Kotek J., Hermann P., Vojtisek P., Lukes I., Peters J.A., Vander Elst L., and Muller R.N. Chem. Eur. J. 11 (2005) 2373
44. Borel A., Helm L., and Merbach A.E. Chem. Eur. J. 7 (2001) 600
45. Nilsson T., and Kowalewski J. J. Magn. Reson. 146 (2000) 345
46. Kruk D., and Kowalewski J. J. Magn. Reson. 162 (2003) 229
47. Rast S., Fries P.H., and Belorizky E. J. Chem. Phys. 113 (2000) 8724
48. Schaefle N., and Sharp R. J. Chem. Phys. 121 (2004) 5387
49. Schaefle N., and Sharp R. J. Magn. Reson. 176 (2005) 160
50. Kruk D., and Kowalewski J. Mol. Phys 101 (2003) 2861
51. Bertini I., Kowalewski J., Luchinat C., Nilsson T., and Parigi G. J. Chem. Phys. 111 (1999) 5795
52. Kruk D., Nilsson T., and Kowalewski J. Phys. Chem. Chem. Phys. 3 (2001) 4907
53. Kowalewski J., Kruk D., and Parigi G. In: van Eldik R., and Bertini I. (Eds). Advances in Inorganic Chemistry vol. 57 (2005), Elsevier, San Diego 42-104
54. Kowalewski J. In: Grant D.M., and Harris R.K. (Eds). Encyclopedia of Nuclear Magnetic Resonance (1996), John Wiley & Sons, Chichester 3456-3462
55. Redfield A.G. IBM J. Res. Dev. 1 (1957) 19
56. Redfield A.G. In: Waugh J.S. (Ed). Adv. Magn. Reson. vol. 1 (1965), Academic Press Inc, Ney York 1-32
57. Rubinstein M., Baram A., and Luz Z. Mol. Phys. 20 (1971) 67
58. Nordenskiöld L., Laaksonen A., and Kowalewski J. J. Am. Chem. Soc. 104 (1982) 379
59. Yazyev O.V., Helm L., Malkin V.G., and Malkina O.L. J. Phys. Chem. A 109 (2005) 10997
60. Gueron M. J. Magn. Reson. 19 (1975) 58
61. Vega A., and Fiat D. Mol. Phys. 31 (1976) 347
62. Powell D.H., Merbach A.E., Gonzalez G., Brücher E., Micskei K., Ottaviani M.F., Köhler K., von Zelewsky A., Grinberg O.Y., and Lebedev Y.S. Helv. Chim. Acta 76 (1993) 2129
63. Benetis N., Kowalewski J., Nordenskiöld L., Wennerström H., and Westlund P. Mol. Phys. 48 (1983) 329
64. Westlund P. In: Delpuech J.-J. (Ed). Dynamics of Solutions and Fluid Mixtures by NMR (1995), John Wiley & Sons, Chichester 174-229
65. Kowalewski J., Luchinat C., Nilsson T., and Parigi G. J. Phys. Chem. A 106 (2002) 7376
66. Nilsson T., and Kowalewski J. Mol. Phys. 99 (2001) 369
67. Nilsson T., and Kowalewski J. Mol. Phys. 98 (2000) 1617
68. Nilsson T., Svoboda J., Westlund P., and Kowalewski J. J. Chem. Phys. 109 (1998) 6364
69. Westlund P., Benetis N., and Wennerström H. Mol. Phys. 61 (1987) 177
70. Sharp R.R. J. Chem. Phys. 93 (1990) 6921
71. Sharp R.R. J. Chem. Phys. 98 (1993) 912
72. Sharp R., Abernathy S.M., and Lohr L.L. J. Chem. Phys. 107 (1997) 7620
73. Abernathy S.M., and Sharp R.R. J. Chem. Phys. 106 (1997) 9032
74. Sharp R., Lohr L.L., and Miller J. Prog. NMR Spectrosc. 38 (2001) 115
75. Sharp R., and Lohr L. J. Chem. Phys. 115 (2001) 5005
76. Bertini I., Luchinat C., and Kowalewski J. J. Magn. Reson. 62 (1985) 235
77. Fries P.H., and Belorizky E. J. Chem. Phys. 123 (2005) 124510
78. Rast S., Fries P.H., Belorizky E., Borel A., Helm L., and Merbach A.E. J. Chem. Phys. 115 (2001) 7554
79. Kannan D. An Introduction to Stochastic Processes (1979), Elsevier North Holland, New York
80. Bauer H. Wahrscheinlichkeitstheorie (1991), de Gruyter, Berlin
81. Borel A., Yerly F., Helm L., and Merbach A.E. J. Am. Chem. Soc. 124 (2002) 2042
82. Sharp R. J. Magn. Reson. 154 (2002) 269
83. Westlund P.-O. J. Chem. Phys. 108 (1998) 4945
84. Goldman M. J. Magn. Reson. 149 (2001) 160
85. Bertini I., Galas O., Luchinat C., and Parigi G. J. Magn. Reson. A 113 (1995) 151
86. Abragam A. The Principles of Nuclear Magnetism (1961), Clarendon Press, Oxford
87. Belorizky E., and Fries P.H. Phys. Chem. Chem. Phys. 6 (2004) 2341
88. Poupko R., Baram A., and Luz Z. Mol. Phys. 27 (1974) 1345
89. Borel A., Tóth E., Helm L., and Merbach A.E. Phys. Chem. Chem. Phys. 2 (2000) 1311
90. Werbelow L.G. J. Chem. Phys. 70 (1979) 5381
91. Kumar A., Grace R.C.R., and Madhu P.K. Prog. NMR Spectrosc. 37 (2000) 191
92. Strandberg E., and Westlund P.-O. J. Magn. Reson. A 122 (1996) 179
93. Strandberg E., and Westlund P.-O. J. Magn. Reson. 137 (1999) 333
94. Zhou X., Caravan P., Clarkson R.B., and Westlund P.-O. J. Magn. Res. 167 (2004) 147
95. Zhou X., and Westlund P.-O. J. Magn. Reson. 173 (2005) 75
96. Zhou X., and Westlund P.-O. Spectrochim. Acta A: Mol. Biomol. Spectrosco. 62 (2005) 76
97. Dwek R.A. Nuclear Magnetic Resonance (NMR) in the Biochemistry. Applications to enzyme systems (1973), Oxford University Press, London
98. Zhou X., and Westlund P. Spectrochim. Acta A: Mol. Biomol. Spectrosc. 62 (2005) 335
99. Polnaszek C.F., and Bryant R.G. J. Chem. Phys. 81 (1984) 4038
100. Albrand J.P., Taieb M.C., Fries P.H., and Belorizky E. J. Chem. Phys. 78 (1983) 5809
101. Fries P.H., Albrand J.P., Taieb M.C., Belorizky E., and Minier M. J. Magn. Reson. 54 (1983) 177
102. Fries P.H., and Belorizky E. J. Phys. Fr. 39 (1983) 1263
103. Fries P.H., Gateau C., and Mazzanti M. J. Am. Chem. Soc. 127 (2005) 15801
104. Sacco A., Belorizky E., Jeannin M., Gorecki W., and Fries P.H. J. Phys. II Fr. 7 (1997) 1299
105. Favier A., Chapon D., Fries P.H., Rast S., and Belorizky E. Chem. Phys. Lett. 320 (2000) 49
106. Rast S., Belorizky E., Fries P.H., and Travers J.P. J. Phys. Chem. B 105 (2001) 1978
107. Fries P.H., and Belorizky E. J. de Physque 39 (1978) 1263
108. Vigouroux C., Bardet M., Belorizky E., and Fries P.H. Chem. Phys. Lett. 286 (1998) 93
109. Vigouroux C., Belorizky E., and Fries P.H. Eur. Phys. J. D 5 (1999) 243
110. Bayburt T., and Sharp R.R. J. Chem. Phys. 92 (1990) 5892
111. Kruk D., Nilsson T., and Kowalewski J. Mol. Phys. 99 (2001) 1435
112. Lumry R., Matsumiya H., Bovey F.A., and Kowalsky A. J. Phys. Chem. 65 (1961) 837