A combined experimental and theoretical study of the kinetics and mechanism of the addition of alcohols to electronically stabilized silenes: A new mechanism for the addition of alcohols to the Si=C bond

Journal of the American Chemical Society

Volumn 128, Issue 33, 2006, Pages 10772-10783

  Leigh, William J ^a   Owens, Thomas R ^a   Bendikov, Michael ^b   Zade, Sanjio S ^b   Apeloig, Yitzhak ^c  

^a MCMASTER UNIVERSITY   (Canada)

^b WEIZMANN INSTITUTE OF SCIENCE   (Israel)

^c TECHNION ISRAEL INSTITUTE OF TECHNOLOGY   (Israel)

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOLS; DIMERS; REACTION KINETICS; SILANES; SOLUTIONS; SPECTROPHOTOMETRY; ULTRAVIOLET RADIATION;

ADAMANTYLIDENESILANES; HYDROGEN-BONDED DIMERS; TRISILACYCLOBUTANE DERIVATIVES;

AROMATIC COMPOUNDS;

1 TERT BUTYLDIMETHYLSILYL 1 TRIMETHYLSILYL 2 ADAMANTYLIDENESILANE; 1,1 BIS(SILYL) 2,2 DIMETHYLSILENE; 1,1 BIS(TRIMETHYLSILYL) 2 ADAMANTYLIDENESILANE; ALCOHOL; CARBON; CYCLOBUTANE DERIVATIVE; HEXANE; METHANOL; OXYGEN; SILANE DERIVATIVE; SILICON DERIVATIVE; UNCLASSIFIED DRUG; WATER;

ABSORPTION SPECTROSCOPY; ADDITION REACTION; ARTICLE; DENSITY FUNCTIONAL THEORY; DIMERIZATION; ENERGY; HYDROGEN BOND; KINETICS; LASER; PHOTOLYSIS; PROTON NUCLEAR MAGNETIC RESONANCE; ULTRAVIOLET SPECTROPHOTOMETRY;

EID: 33747801405     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0613557     Document Type: Article

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