Characteristics of SME biodiesel-fueled diesel particle emissions and the kinetics of oxidation

Environmental Science and Technology

Volumn 40, Issue 16, 2006, Pages 4949-4956

  Jung, Heejung ^a   Kittelson, David B ^b   Zachariah, Michael R ^c  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b University of Minnesota   (United States)

^c Bldg 142   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BIODIESEL; DIESEL PARTICULATE FILTER (DPF); OXIDATION KINETICS; PARTICLE EMISSIONS;

ESTERS; OXIDATION; PARTICULATE EMISSIONS; REACTION KINETICS;

SYNTHETIC FUELS;

BIODIESEL; BIOFUEL; ESTER; SOY METHYL ESTER; UNCLASSIFIED DRUG;

ESTERS; OXIDATION; PARTICULATE EMISSIONS; REACTION KINETICS; SYNTHETIC FUELS;

BIOFUEL; DIESEL; EMISSION; KINETICS; OXIDATION; PARTICULATE MATTER;

ARTICLE; DIESEL ENGINE; EXHAUST GAS; FILTER; OXIDATION KINETICS; PARTICLE SIZE; PARTICULATE MATTER;

AIR POLLUTANTS; AIR POLLUTION; CATALYSIS; ENVIRONMENTAL MONITORING; GASOLINE; HYDROCARBONS; KINETICS; MOTOR VEHICLES; OXYGEN; PARTICLE SIZE; PLANT OILS; SOYBEAN OIL; SOYBEANS; TEMPERATURE; VEHICLE EMISSIONS;

EID: 33747459281     PISSN: 0013936X     EISSN: None     Source Type: Journal    
DOI: 10.1021/es0515452     Document Type: Article

References (52)

1. Song, J.; Alam, M.; Boehman, A. Effect of alternative fuels on soot properties and regeneration of diesel particulate filters. In Proceedings of the DEER Conference; 2005.
2. Song, J.; Alam, M.; Boehman, A. L.; Miller, K. Characterization of diesel and biodiesel soot. ACS Prepr. 2004, 49, 767-769.
3. Mahadevan, R.; Lee, D.; Sakurai, H.; Zachariah, M. R. Measurement of condensed-phase reaction kinetics in the aerosol phase using single particle mass spectrometry. J. Phys. Chem. A. 2002, 106, 11083-11092.
4. Mayer, A.; Czerwinski, J.; Wyser, M.; Mattrel, P.; Heitzer, Impact of RME/diesel blends on particle formation, particle filtration and PAH emissions. SAE Tech. Pap. Ser. 2005, 2005-2001-1728.
5. Wang, S. C.; Flagan, R. C. Scanning electrical mobility spectrometer. Aerosol Sci. Technol. 1990, 13, 230-240.
6. Graboski, M. S.; McCormick, R. L. Combustion of fat and vegetable oil derived fuels in diesel engines. Prog. Energy Combust. Sci. 1998, 24, 125-164.
7. Babu, A. K.; Devaradjane, G. Vegetable oils and their derivatives as fuels for CI engines: An overview. SAE Tech. Pap. Ser. 2003, 2003-2001-0767.
8. Schröder, O.; Krahl, J.; Munack, A.; Bünger, J. Environmental and health effects caused by the use of biodiesel. SAE Tech. Pap. Ser. 1999, 1999-1901-3561.
9. Monyem, A.; Van Gerpen, J. H. The effect of biodiesel oxidation on engine performance and emissions. Biomass Bioenergy 2001, 20, 317-325.
10. Bagley, S. T.; Gratz, L. D.; Johnson, J. H.; McDonald, J. F. Effects of an oxidation catalytic converter and a biodiesel fuel on the chemical, mutagenic, and particle size characteristics of emissions from a Diesel engine. Environ. Sci. Technol. 1998, 32, 1183-1191.
11. Krahl, J.; Munack, A.; Schröder, O.; Stein, H.; Bünger, J. Influence of biodiesel and different designed diesel fuels on the exhaust gas emissions and health effects. SAE Tech. Pap. Ser. 2003, 2003-2001-3199.
12. McDonald, J. F.; Purcell, D. L.; McClure, B. T.; Kittelson, D. B. Emissions characteristics of soy methyl ester fuels in an IDI compression ignition engine. SAE Tech. Pap. Ser. 1995, 950400.
13. Purcell, D. L.; McClure, B. T.; McDonald, J. F.; Basu, H. N. Transient testing of soy methyl ester fuels in an indirect injection, compression ignition engine. J. Am. Oil Chem. Soc. 1996, 73, 381.
14. x emissions; Presented at California Air Resources Board; U.S. Department of Energy, National Renewable Energy Laboratory: Golden, CO, 2005; http://www.nrel.gov/ vehiclesandfuels/npbf/pdfs/38296.pdf.
15. Bouche, T.; Hinz, M.; Pittermann, R.; Herrmann, M. Optimising tractor C1 engines for biodiesel operation. SAE Spec. Publ. 2000, SP-1545, 57-64.
16. McCormick, R. L.; Alvarez, J. R.; Graboski, M. S.; Tyson, K. S.; Vertin, K. Fuel additive and blending approaches to reducing NOx emissions from biodiesel. SAE Tech. Pap. Ser. 2002, 2002-2001-1658.
17. Yoshimoto, Y.; Tamaki, H. Reduction of NOx and smoke emissions in a diesel engine fueled by biodiesel emulsion combined with EGR. SAE Spec. Publ. 2001, SP-1608, 225-233.
18. Tat, M. E.; Van Gerpen, J. H. Biodiesel blend detection with a fuel composition sensor. Appl. Eng. Agric. 2003, 19, 125-131.
19. Szybist, J. P.; Boehman, A. L.; Taylor, J. D.; McCormick, R. L. Evaluation of formulation strategies to eliminate the biodiesel NOx effect. Fuel Process. Technol. 2005, 86, 1109-1126.
20. Kinney, A. J.; Clemente, T. E. Modifying soybean oil for enhanced performance in biodiesel blends. Fuel Process. Technol. 2005, 86, 1137-1147.
21. Finch, G. L.; Hobbs, C. H.; Blair, L. F.; Barr, E. B.; Hahn, F. F.; Jaramillo, R. J.; Kubatko, J. E.; March, T. H.; White, R. K.; Krone, J. R.; Ménache, M. G.; Nikula, K. J.; Mauderly, J. L.; Van Gerpen, J.; Merceica, M. D.; Zielinska, B.; Stankowski, L.; Burling, K.; Howell, S. Effects of subchronic inhalation exposure of rats to emissions from a diesel engine burning soybean oil-derived biodiesel fuel. Inhalation Toxicol. 2002, 14, 1017-1048.
22. Williams, J. B. Production of biodiesel in Europe - the markets. Eur. J. Lipid Sci. Technol. 2002, 104, 361-362.
23. Korbitz, W. Biodiesel production in Europe and north America, an encouraging prospect. Renewable Energy 1999, 16, 1078-1083.
24. Pereira, R. L.; Maria, W. H. Current status of biodiesel development in Brazil. Appl. Biochem. Biotechnol. 2005, 121, 807.
25. Brazil to export vegetable oil-based biodiesel, says president Lula da Silva, 2004; http://www.soyatech.com/bluebook/news/viewarticle.ldml?a=20041214- 20041216
26. Monyem, A.; Van Gerpen, J. H.; Canakci, M. The effect of timing and oxidation on emissions from biodiesel-fueled engines. Trans. ASAE 2001, 44, 35-42.
27. Jung, H.; Kittelson, D. B.; Zachariah, M. R. The influence of engine lubricating oil on diesel nanoparticle emissions and kinetics of oxidation. SAE Tech. Pap. Ser. 2003, 2003-2001-3179.
28. Higgins, K. J.; Jung, H.; Kittelson, D. B.; Roberts, J. T.; Zachariah, M. R. Kinetics of diesel nanoparticle oxidation. Environ. Sci. Technol. 2003, 37, 1949-1954.
29. Abdul-Khalek, I.; Kittelson, D. B.; Brear, F. The influence of dilution conditions on diesel exhaust particle size distribution measurements. SAE Tech. Pap. Ser. 1999, 1999-1901-1142.
30. Khalek, I. A.; Kittelson, D. B.; Brear, F. Nanoparticle growth during dilution and cooling of diesel exhaust: Experimental investigation and theoretical assessment. SAE Tech. Pap. Ser. 2000, 2000-2001-0515.
31. Abdul-Khalek, I.; Kittelson, D. B. Real time measurement of volatile and solid exhaust particles using a catalytic stripper. SAE Tech. Pap. Ser. 1995, 950236.
32. Ng, I. P. Aethalometer performance with diesel particles. Masters thesis, University of Minnesota, Twin Cities, MN, 2002.
33. Kittelson, D. B.; Watts, W. F.; Savstrom, J. C.; Johnson, J. P. Influence of a catalytic stripper on the response of real time aerosol instruments to diesel exhaust aerosol. J. Aerosol. Sci. 2005, 36, 1089-1107.
34. Jung, H.; Kittelson, D. B.; Zachariah, M. R. The influence of a cerium additive on ultrafine diesel particle emissions and kinetics of oxidation. Combust. Flame 2005, 142, 276-288.
35. Kittelson, D. B. Engines and nanoparticles: A review. J. Aerosol Sci. 1998, 29, 575-588.
36. Hallgren, B. E.; Heywood, J. B. Effects of oxygenated fuels on DI diesel combustion and emissions. SAE Tech. Pap. Ser. 2001, 2001-2001-0648.
37. Kitamura, T.; Ito, T.; Senda, J.; Fujimoto, H. Mechanism of smokeless diesel combustion with oxygenated fuels based on the dependence of the equivalence ratio and temperature on soot particle formation. Int. J. Engine Res. 2002, 3, 223-248.
38. Sakurai, H.; Park, K.; McMurry, P. H.; Zarling, D. D.; Kittelson, D. B.; Ziemann, P. J. Size-dependent mixing characteristics of volatile and nonvolatile components in diesel exhaust aerosols. Environ. Sci. Technol. 2003, 37, 5487-5495.
39. Abdul-Khalek, I. S.; Kittelson, D. B.; Graskow, B. R.; Wei, Q.; Brear, F. Diesel exhaust particle size: Measurement issues and trends. SAE Tech. Pap. Ser. 1998, 980525.
40. Higgins, K. J.; Jung, H.; Kittelson, D. B.; Roberts, J. T.; Zachariah, M. R. Size-selected nanoparticle chemistry: Kinetics of soot oxidation. J. Phys. Chem. A. 2002, 106, 96-103.
41. Park, K.; Cao, F.; Kittelson, D. B.; McMurry, P. H. Relationship between particle mass and mobility for diesel exhaust particles. Environ. Sci. Technol. 2003, 37, 577-583.
42. Kim, S. H.; Fletcher, R. A.; Zachariah, M. R. Understanding the difference in oxidative properties between flame and diesel soot nanoparticles: The role of metals. Environ. Sci. Technol. 2005, 39, 4021.
43. Retailleau, L.; Vonarb, R.; Perrichon, V.; Jean, E.; Bianchi, D. Catalytic oxidation of a diesel soot formed in the presence of a cerium additive. I. Characterization of the cerium fraction using magnetic susceptibility and temperature-programmed desorption. Energy Fuels 2004, 18, 872-882.
44. Vander Wal, R. L.; Tomasek, A. J. Soot oxidation: dependence upon initial nanostructure. Combust. Flame 2003, 134, 1-9.
45. Vander Wal, R. L.; Tomasek, A. J. Soot nanostructure: Definition, quantification and implication. AAAR: Atlanta, GA, 2004.
46. Boehman, A. L.; Song, J.; Alam, M. Impact of biodiesel blending on diesel soot and the regeneration of particulate filters. Energy Fuels 2005, 19, 1857-1864.
47. Nagle, J.; Strickland-Constable, R. F. Oxidation of carbon between 1000 and 2000 °C. In Fifth Carbon Conference; Pergamon: Oxford, 1962; pp 154-164.
48. Miyamoto, N.; Hou, Z.; Ogawa, H. Catalytic effects of metallic fuel additives on oxidation characteristics of trapped diesel soot. SAE Tech. Pap. Ser. 1988, 881224.
49. Gilot, P.; Bonnefoy, F.; Marcuccilli, F.; Prado, G. Determination of kinetic data for soot oxidation. Modeling of competition between oxygen diffusion and reaction during thermogravimetric analysis. Combust. Flame 1993, 95, 87.
50. Neeft, J. P. A.; Nijhuis, T.X.; Smakman, E.; Makkee, M.; Moulijin, J. A. Kinetics of the oxidation of diesel soot. Fuel 1997, 76, 1129.
51. Otto, K.; Sieg, M. H.; Zinbo, M.; Bartosiewicz, L. The oxidation of soot deposits from diesel engines. SAE Tech. Pap. Ser. 1980, 800336.
52. Ahlström, A. F.; Odenbrand, C. U. I. Combustion characteristics of soot deposits from diesel engines. Carbon 1989, 3, 475.