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Volumn 128, Issue 31, 2006, Pages 9988-9989

Tuning the sensitivity of a foldamer-based mercury sensor by its folding energy

Author keywords

[No Author keywords available]

Indexed keywords

BIOPOLYMER; FOLDAMER; MERCURY; UNCLASSIFIED DRUG;

EID: 33746908181     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja062001i     Document Type: Article
Times cited : (227)

References (36)
  • 32
    • 33746862429 scopus 로고    scopus 로고
    • note
    • See Supporting Information.
  • 33
    • 33746902651 scopus 로고    scopus 로고
    • note
    • The folded oligocholate resembles a unimolecular reversed micelle. The most "folding-friendly" solvents are nonpolar ones mixed with a small amount of a polar solvent. Because the interior of a folded conformer prefers polar molecules, microphase separation of solvents happens during folding. MeOH is completely miscible with EA but barely miscible with hexane. Therefore, demixing should be easier in MeOH/hexane/EA than in MeOH/EA.
  • 36
    • 33746905757 scopus 로고    scopus 로고
    • Unpublished work. Only 5% of water can be dissolved in MTHF/THF (2/1). We are currently investigating why folding is particularly difficult in aqueous mixtures
    • Zhao, Y.; Zhong, Z. Unpublished work. Only 5% of water can be dissolved in MTHF/THF (2/1). We are currently investigating why folding is particularly difficult in aqueous mixtures.
    • Zhao, Y.1    Zhong, Z.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.