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33746793059
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note
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This may be attributable to the fact that the central double bond rotated when the reactant was on a Pd atom. However, the possibility that stray light triggered the E→Z photoisomerization in the reaction pot or during purification cannot be excluded.
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26
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33746842099
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2 = 0.0935 [I > 2.00σ(I)]. CCDC 600138 ((E)-1) and 600139 ((Z)-1) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/ data_request/cif.
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27
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33746830235
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note
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Cut-off filter Y-47 and IR cut-off filter IRA-25S by Asahi Techno Glass Inc. were used to extract light with wavelengths of 546 nm and 578 nm.
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28
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15444375592
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29
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33746807102
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note
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Light with a wavelength of 546 nm was separated with a Jasco CT-10T monochromator.
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30
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33947466685
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31
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33746845925
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note
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Photon flux was measured with Q8230 and Q82311, a semi-conductor photon counter, by ADVANTEST.
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32
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33746806513
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note
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The CV simulation was implemented with Digisim 3.03b. See Supporting Information for the detailed parameters used in the simulation.
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33
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22944455559
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