The enantioselective synthesis of (R)-(+)-6-isopropenyl-3-methyl-2- cycloheptenone

Journal of the Brazilian Chemical Society

Volumn 17, Issue 4, 2006, Pages 792-796

  Brocksom, Timothy J ^a   Brocksom, Ursula ^a   Barbosa, Fernanda P ^a  

^a FEDERAL UNIVERSITY OF SÃO CARLOS   (Brazil)

Author keywords

Carvone; Cycloheptenone; Enantioselectivity; Perhydroazulene; Ring expansion

Indexed keywords

EID: 33746677447     PISSN: 01035053     EISSN: 01035053     Source Type: Journal    
DOI: 10.1590/S0103-50532006000400023     Document Type: Article

References (12)

1. Fraga, B. M.; Nat. Prod. Rep. 2005, 22, 465.
2. Brocksom, T. J.; Pesquero, E. T. C.; Lopes, F. T.; Synth. Commun. 1990, 20, 1181.
3. De Faria, M. L.; Magalhães, R. de A.; Silva, F. C.; Matias, L. G. de O.; Ceschi, M. A.; Brocksom, U.; Brocksom, T. J.; Tetrahedron: Asymmetry 2000, 11, 4093.
4. Brocksom, T. J.; Brocksom, U.; de Sousa, D. P.; Frederico, D.; Tetrahedron: Asymmetry 2005, 16, 3628.
5. Zukerman-Schpector, J.; Caracelli, I.; Carvalho, C. C.; de Faria, M. L.; Silva, F. C.; Matias, L. G. de O.; Brocksom, T. J.; J. Braz. Chem. Soc. 2001, 12, 154.
6. Brocksom, T. J.; Brocksom, U.; Frederico, D.; Tetrahedron Lett. 2004, 45, 9289.
7. Marques, F. A.; Ferreira, J. B.; Piers, E.; J. Braz. Chem. Soc. 2000, 11, 502. We thank Prof. Marques for helpful discussions on this methodology.
8. Furukawa, J.; Kawabata, N.; Nishimura, J., Tetrahedron 1968, 24, 53.
9. Smith, R. D.; Simmons, H. E.; Org. Synth. Coll. 1973, 5, 855.
10. Miyano, S.; Hashimoto, H.; Chem. Commun. 1971, 1418.
11. Charette, A. B.; Jolicoeur, E.; Bydlinski, G. A. S.; Org. Lett. 2001, 3, 3293.
12. Ito, Y.; Fujii, S.; Nakatsuka, M.; Kawamoto, F.; Saegusa, T.; Org. Synth. Coll. 1998, 6, 327.