Neutron diffraction and neutron vibrational spectroscopy studies of hydrogen adsorption in the prussian blue analogue Cu 3[Co(CN) 6] 2

Chemistry of Materials

Volumn 18, Issue 14, 2006, Pages 3221-3224

  Hartman, Michael R ^a   Peterson, Vanessa K ^a   Liu, Yun ^a   Kaye, Steven S ^b   Long, Jeffrey R ^b  

^a NATIONAL INSTITUTE OF STANDARDS AND TECHNOLOGY   (United States)

^b UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

MOLECULAR HYDROGEN; NEUTRON DATA; NEUTRON VIBRATIONAL SPECTROSCOPY; PRUSSIAN BLUE ANALOGUE;

ADSORPTION; COPPER COMPOUNDS; IONIZATION; MOLECULAR STRUCTURE; NEUTRON DIFFRACTION; SPECTROSCOPIC ANALYSIS;

HYDROGEN;

EID: 33746624769     PISSN: 08974756     EISSN: None     Source Type: Journal    
DOI: 10.1021/cm0608600     Document Type: Article

References (10)

1. Kaye, S. S.; Long, J. R. J. Am. Chem. Soc. 2005, 127, 6507.
2. Chapman, K. W.; Southon, P. D.; Weeks, C. L.; Kepert, C. J. Chem. Commun. 2005, 3322.
3. Larson, A. C.; Von Dreele, R. B. General Structure Analysis System (GSAS); Report LAUR 86-748; Los Alamos National Laboratory: Los Alamos, NM, 2000.
4. Toby, B. H. J. Appl. Crystallogr. 2001, 34, 210.
5. For the neutron powder diffraction experiments, hydrogen gas enriched in deuterium (99.9% D) was used instead of hydrogen gas with the normal isotopic ratio to eliminate the large incoherent scattering associated with hydrogen.
6. Udovic, T. J.; Neumann, D. A.; Leão, J.; Brown, C. M. Nucl. Instrum. Methods Phys. Res., A 2004, 517, 189.
7. Franz, P.; Ambrus, C.; Hauser, A.; Chernyshov, D.; Hostettler, M.; Hauser, J.; Keller, L.; Krämer, K.; Stoeckli-Evans, H.; Pattison, P.; Bürgi, H.-B.; Decurtins, S. J. Am. Chem. Soc. 2004, 126, 16472.
8. Chapman K. W.; Chupas P. J.; Kepert, C. J. J. Am. Chem. Soc. 2005, 127, 11232.
9. Rosi, N. L.; Eckert, J.; Eddaoudi, M.; Vodak, D. T.; Kim, J.; O'Keeffe, M.; Yaghi, O. M. Science 2003, 300, 1127.
10. Roswell, J. C.; Eckert, J.; Yaghi, O. M. J. Am. Chem. Soc. 2005, 127, 14904.