Fac versus mer coordination for a tridentate diethylene glycloiate ligand in tantalum complexes: A combined experimental and theoretical study

Organometallics

Volumn 25, Issue 14, 2006, Pages 3336-3344

  Bo, Carles ^b,c   Fandos, Rosa ^a   Feliz, Marta ^b,c   Hernández, Carolina ^a   Otero, Antonio ^a   Rodríguez, Ana ^a   Ruiz, Maria José ^a   Pastor, César ^d  

^a UNIVERSITY OF CASTILLA LA MANCHA   (Spain)

^b INSTITUTE OF CHEMICAL RESEARCH OF CATALONIA ICIQ   (Spain)

^c UNIVERSITAT ROVIRA I VIRGILI   (Spain)

^d UNIVERSIDAD AUTÓNOMA DE MADRID   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

COMPLEXATION; MOLECULAR STRUCTURE; NUCLEAR MAGNETIC RESONANCE; SINGLE CRYSTALS; SPECTROSCOPIC ANALYSIS; SYNTHESIS (CHEMICAL);

DIETHYLENE GLYCLOIATE LIGANDS; ELEMENTAL ANALYSIS; INSERTION PROCESSES; TANTALUMOXO BORANE-STABILIZED COMPLEX;

TANTALUM COMPOUNDS;

EID: 33746617594     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om060254e     Document Type: Article

References (65)

1. Roesky, H. W.; Haiduc, I.; Hosmane, N. S. Chem. Rev. 2003, 103, 2579.
2. Bradley, D. C.; Mehrotra, R. C.; Singh, A.; Rothwell, I. P. Alkoxo and Aryloxo Derivatives of Metals; Academic Press: London, 2001.
3. Sobota, P. Coord. Chem. Rev. 2004, 248, 1047.
4. (a) Basset, J.-M.; Gates, B. C.; Candy, J. P.; Choplin, A.; Leconte, M.; Quignard, F.; Santini, C. Surface Organometallic Chemistry: Molecular Approaches to Surface Catalysis; Kluwer: Dordrecht, The Netherlands, 1988.
5. (b) Coperet, C.; Chabanas, M.; Saint-Arroman, R. P.; Basset, J. M. Angew. Chem., Int. Ed. 2003, 42, 156.
6. Sanchez, C.; Soler-Illia, G. J. de A. A.; Ribot, F.; Lalot, T.; Mayer, C. R.; Cabuil, V. Chem. Mater. 2001, 13, 3061.
7. (a) Rothwell, I. P. Acc. Chem. Res. 1988, 21, 153.
8. (b) Rothwell, I. P. Chem. Commun. 1997, 1331.
9. (a) Tshuva, E. Y.; Groysman, S.; Goldberg, I.; Kol, M. Organometallics 2002, 21, 662.
10. (b) Tshuva, E. Y.; Goldberg, I.; Kol, M. J. Am. Chem. Soc. 2000, 122, 10706.
11. (c) Shao, P.; Gendron, R. A. L.; Berg, D. J.; Bushnell, G. W. Organometallics 2000, 19, 509.
12. Antiñolo, A.; Carrillo-Hermosilla, F.; Corrochano, A. E.; Fandos, R.; Fernández-Baeza, J.; Rodríguez, A. M.; Ruiz, M. J.; Otero, A. Organometallics 1999, 18, 5219.
13. Fandos, R.; Hernández, C.; Otero, A.; Rodríguez, A. M.; Ruiz, M. J.; Terreros, P. J. Chem. Soc., Dalton Trans. 2000, 2990.
14. 2, diethylene glycolate = digol.
15. (a) Hirashima, Y.; Shiokawa, J. Chem. Lett. 1979, 463.
16. (b) Hirashima, Y.; Tsutsui, T.; Shiokawa, J. Chem. Lett. 1981, 1501.
17. (c) Hirashima, Y.; Tsutsui, T.; Shiokawa, J. Chem. Lett. 1982, 1405.
18. (d) Hirashima, Y.; Kanetsuki, K.; Shiokawa, J.; Tanaka, N. Bull. Chem. Soc. Jpn. 1981, 54, 1567.
19. (e) Hirashima, Y.; Kanetsuki, K.; Yonezu, I.; Kamakura, K.; Shiokawa, J. Bull. Chem. Soc. Jpn. 1983, 56, 738.
20. (f) Rogers, R. D.; Voss, E. J.; Etzenhouser, R. D. Inorg. Chem. 1988, 27, 533.
21. (a) Sieger, H.; Vogtle, F. Tetrahedron Lett. 1978, 30, 2709.
22. (b) Singh, T. P.; Reinhardt, R.; Poonia, N. S. Inorg.-Nucl. Chem. Lett. 1980, 16, 293.
23. (c) Ohmoto, H.; Kai, Y.; Yasuoka, N.; Kasai, N.; Yanagida S.; Okahara, M. Bull. Chem. Soc. Jpn. 1979, 52, 1209.
24. Sobota, P.; Utko, J.; Sztajnowska, K.; Jerzykiewicz, L. B. New J. Chem. 1998, 851.
25. Yi-Yeol, L.; Jin-Heong, Y. (Samsung General Chemicals Co., Ltd., S. Korea) Eur. Pat. Appl. EP9640e4, 1999.
26. De Castro, I.; Galakhov, M. V.; Gómez, M.; Gómez-Sal, P.; Martín, A.; Royo, P. J. Organomet. Chem. 1996, 514, 51.
27. Fandos, R.; Hernández, C.; López-Solera, I.; Otero, A.; Rodríguez, A. M.; Ruiz, M. J.; Terreros, P. Organometallics 2000, 19, 5318.
28. Cardin, D. J.; Lappert, M. F.; Raston, C. L. Chemistry of OrganoZirconium and Hafmium Compounds', Ellis Horwood Limited; Halsted Press: New York, 1986.
29. Albrecht, M.;, van Koten, G. Angew. Chem., Int. Ed. 2001, 40, 3750.
30. del Rio, D.; Galindo, A.; Vicente, R.; Mealli, C.; Ienco, A.; Masi, D. J. Chem. Soc., Dalton Trans. 2003, 1813.
31. Grirrane, A.; Pastor, A.; Ienco, A.; Mealli, C.; Galindo, A. J. Chem. Soc., Dalton Trans. 2002, 3771.
32. Harvey, J. N.; Heslop, K. M.; Orpen, G. A.; Pringle, P. G. Chem. Commun. 2003, 278.
33. Neculai, D.; Roesky, H. W.; Neculai, A. M.; Magull, J.; Walfort, B.; Stalke, D. Angew. Chem., Int. Ed. 2002, 41, 4294.
34. Antiñolo, A.; Carrillo-Hermosilla, F.; del Hierro, I.; Otero, A.; Fajardo, M.; Mugnier, Y. Organometallics 1997, 16, 4161.
35. Sánchez-Nieves, J.; Frutos, L. M.; Royo, P.; Castaño, O.; Herdtweck, E. Organometallics 2005, 24, 2004.
36. Gómez, M.; Gómez-Sal, P.; Jiménez, G.; Martín, A.; Royo, P.; Sánchez-Nieves, J. Organometallics 1996, 15, 3579.
37. Parkin, G.; Asselt, A. V.; Leahy, D. J.; Whinnery, L.; Hua, N. G.; Quan, R. W.; Henling, L. M.; Schaefer, W. P.; Santarsiero, B. D.; Bercaw, J. E. Inorg. Chem. 1992, 31, 82.
38. Danopoulos, A. A.; Galsworthy, J. R.; Green, M. L. H.; Cafferkey, S.; Doerrer, L. H.; Hursthouse, M. B. Chem. Commun. 1998, 2529.
39. (a) Barrado, G.; Doerrer, L.; Green, M. L. H.; Leech, M. A. J. Chem. Soc., Dalton Trans. 1999, 1061.
40. (b) Sarsfield, M. J.; Helliwell, M. J. Am. Chem. Soc. 2004, 126, 1036.
41. Doerrer, L. H.; Green, M. L. H. J. Chem. Soc., Dalton Trans. 1999, 4325.
42. Galakov, M. V.; Gómez, M.; Jiménez, G.; Royo, P.; Pellinghelli, M. A.; Tiripichio, A. Organometallics 1995, 14, 1901.
43. Acho, J. A.; Doerrer, L. H.; Lippard, S. J. Inorg. Chem. 1995, 34, 2542.
44. Canac, Y.; Conejero, S.; Donnadieu, B.; Schoeller, W. W.; Bertrand, G. J. Am. Chem. Soc. 2005, 127, 7312.
45. Burt, R. J.; Chatt, J.; Leigh, G. J.; Teuben, J. H.; Westerhof A. J. Organomet. Chem. 1977, 729, C33.
46. Sanner, R. D.; Carter, S. T.; Burton, W. J. J. Organomet. Chem. 1982, 240, 157.
47. (a) Baerends, E. J.; Ellis, D. E.; Ros, P. Chem. Phys. 1973, 2, 41.
48. (b) Baerends, E. J.; Ros, P. Chem. Phys. 1973, 2, 52.
49. Ravenek, W. In Algorithms and Applications on Vector and Parallel Computers; te Riele, H. J. J., Deckker, T. J., van de Horst, H. A., Eds.; Elsevier: Amsterdam, The Netherlands, 1987.
50. (a) Boerrigter, P. M.; te Velde, G.; Baerends, E. J. Int. J. Quantum Chem. 1988, 33, 87.
51. (b) te Velde, G.; Baerends, E. J. J. Comput. Chem. 1992, 99, 84.
52. Versluis, L.; Ziegler, T. J. Chem. Phys. 1988, 88, 322.
53. Becke, A. D. Phys. Rev. A 1988, 38, 3098.
54. Perdew, J. P. Phys. Rev. B 1986, 34, 7406.
55. Perdew, J. P. Phys. Rev. B 1986, 33, 8822.
56. (a) van Lenthe, E.; Baerends, E. J.; Snijders, J. G. J. Chem. Phys. 1993, 99, 4597.
57. (b) van Lenthe, E.; Baerends, E. J.; Snijders, J. G. J. Chem. Phys. 1994, 101, 9783.
58. (c) van Lenthe E.; Ehlers, A.; Baerends, E. J. J. Chem. Phys. 1999, 110, 8943.
59. Ortiz Alba, J. C.; Bo, C. Xaim-1.0; Universitat Rovira I Virgili: Tarragona, Spain. http://www.quimica.urv.es/XAIM.
60. Sheldrick, G. M. SADABS version 2.03, A Program for Empirical Absorption Correction; Universität Göttingen, 1997-2001.
61. SAINT+ NT ver. 6.04, SAX Area-Detector Integration Program; Bruker AXS: Madison, WI, 1997-2001.
62. Bruker AXS SHELXTL version 6.10, Structure Determination Package; Bruker AXS: Madison, WI, 2000.
63. Sheldrick, G. M. SHELXS-97, Program for Structure Solution: Acta Crystallogr. Sect. A 1990, 46, 467.
64. (a) Sheldrick, G. M. SHELXL-97, Program for Crystal Structure Refinement; Universität Göttingen, 1997.
65. (b) SMART v. 5.625, Area-Detector Software Package; Bruker AXS: Madison, WI, 1997-2001.