Insertion of CO and CNR into tantalum-methyl bonds of imido(pentamethylcyclopentadienyl)tantalum complexes. X-ray crystal structures of [TaCp*(NR)-Me{η2-C(Me)=NR}] and [TaCp*Cl(O){η2-C(Me)=NR}] (R = 2,6-Me2C6H3)†

Organometallics

Volumn 15, Issue 16, 1996, Pages 3579-3587

  Gómez, Manuel ^a   Gómez Sal, Pilar ^a   Jiménez, Gerardo ^a   Martín, Avelino ^a   Royo, Pascual ^a   Sánchez Nieves, Javier ^a  

^a UNIVERSITY OF ALCALÁ   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0038783774     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om9602015     Document Type: Article

References (49)

1. (a) Calderazzo, F. Angew. Chem., Int. Ed. Engl. 1977, 16, 299.
2. (b) Wood, C. D.; Schrock, R. R. J. Am. Chem. Soc. 1979, 101, 5421.
3. (c) Kulhmann, E. J.; Alexander, J. J. Coord. Chem. Rev. 1980, 33, 195.
4. (a) Treitchel, P. M. Adv. Organomet. Chem. 1973, 11, 21.
5. (b) Andersen, R. A. Inorg. Chem. 1979, 18, 2928.
6. (a) Takahashi, Y.; Onoyama, N.; Ishikawa, Y.; Motojima, S.; Sugiyama, K. Chem. Lett. 1978, 525.
7. (b) Wolczanski, P. T.; Bercaw, J. E. J. Am. Chem. Soc. 1979, 101, 6450.
8. (c) Wolczanski, P. T.; Bercaw, J. E. Acc. Chem. Res. 1980, 13, 121.
9. (d) Chiu, K. W.; Jones, R. A.; Wilkinson, G.; Galas, A. M. R.; Hursthouse, M. B. J. Am. Chem. Soc. 1980, 102, 7978.
10. (e) Chiu, K. W.; Jones, R. A.; Wilkinson, G.; Galas, A. M. R.; Hursthouse, M. B. J. Chem. Soc., Dalton Trans. 1981, 2088.
11. (f) Mayer, J. M.; Curtis, C. J.; Bercaw, J. E. J. Am. Chem. Soc. 1983, 105, 2651.
12. (g) Nugent, W. A.; Overall, D. W.; Holmes, S. J. Organometallics 1983, 2, 161.
13. (h) Chamberlain, L. R.; Rothwell, I. P.; Huffman, J. C. J. Chem. Soc., Chem. Commun. 1986, 1203.
14. (i) Sielisch, T.; Behrens, U. J. Organomet. Chem. 1986, 310, 179.
15. (j) Brunner, H.; Wachter, J.; Schmidbauer, J. Organometallics 1986, 5, 2212.
16. (k) Durfee, L. D.; Fanwick, P. E.; Rothwell, I. P. J. Am. Chem. Soc. 1987, 109, 4720.
17. (l) Chamberlain, L. R.; Steffey, B. D.; Rothwell, I. P.; Huffman, J. D. Polyhedron 1989, 8, 341.
18. (m) Durfee, L. D.; Hill, J. E.; Fanwick, P. E.; Rothwell, I. P. Organometallics 1990, 9, 75.
19. (a) Galakhov, M. V.; Gómez, M.; Jiménez, G.; Royo, P.; Pellinghelli, M. A.; Tiripicchio, A. Organometallics 1995, 14, 1901.
20. (b) Galakhov, M. V.; Gómez, M.; Jiménez, G.; Royo, P.; Pellinghelli, M. A.; Tiripicchio, A. Organometallics 1995, 14, 2843.
21. (a) Curtis, M. D.; Real, J.; Hirpo, W.; Butler, W. M. Organometallics 1990, 9, 66.
22. (b) Gómez, M.; Jiménez, G.; Royo, P.; Pellinghelli, M. A.; Tiripicchio, A. J. Organomet. Chem. 1992, 439, 309.
23. (a) Schrock, R. R. J. Am. Chem. Soc. 1974, 96, 6796.
24. (b) Andersen, R. A. Inorg. Chem. 1979, 18, 3622.
25. (c) Chamberlain, L. R.; Rothwell, I. P.; Folting, K.; Huffman, J. C. J. Chem. Soc., Dalton Trans. 1987, 155.
26. (a) Bradley, D. C.; Hursthouse, M. B.; Howes, A. J.; Jelfs, A. N. de M.; Runnacles, J. D.; Thornton-Pett, M. J. Chem. Soc., Dalton Trans. 1991, 841.
27. (b) Williams, D. N.; Mitchell, J. P.; Poole, A. D.; Siemeling, U.; Clegg, W.; Hockless, D. C. R.; O'Neil, P. A.; Gibson, V. C. J. Chem. Soc., Dalton Trans. 1992, 739.
28. (a) Gibson, V. C.; Poole, A. D.; Siemeling, U.; Williams, D. N.; Clegg, W.; Hockless, D. C. R. J. Organomet. Chem. 1993, 462, C12.
29. (b) Galakhov, M. V.; Gómez, M.; Jiménez, G.; Pellinghelli, M. A.; Royo, P.; Tiripicchio, A. Organometallics 1994, 13, 1564.
30. Durfee, L. D.; Rothwell, I. P. Chem. Rev. 1988, 88, 1059.
31. (a) Curtis, M. D.; Thanedar, S.; Butler, W. M. Organometallics 1984, 3, 1855.
32. (b) Meyer, T. Y.; Garner, L. R.; Baenzinger, N. C.; Messerle, L. W. Inorg. Chem. 1990, 29, 4045.
33. Nakamoto, K. Infrared and Raman Spectra of Inorganic and Coordination Compounds; Wiley: New York, 1978.
34. (a) Planalp, R. P.; Andersen, R. A. J. Am.Chem. Soc. 1983, 105, 7774.
35. (b) Arnold, J.; Tilley, T. D.; Rheingold, A. L.; Geib, S. J.; Arif, A. M. J. Am. Chem. Soc. 1989, 111, 149.
36. (c) Veya, P.; Floriani, C.; Chiesi-Villa, A.; Guastini, C. Organometallics 1994, 13, 208.
37. (a) Nugent, W. A.; Mayer, J. M. Metal-Ligand Multiple Bonds; Wiley: New York, 1988.
38. (b) Parkin, G.; Van Asselt, A.; Leahy, D. J.; Whinnery, L.-R.; Hua, N. G.; Quan, R. W.; Henling, L. M.; Schaefer, W. P.; Santarsiero, B. D.; Bercaw, J. E. Inorg. Chem. 1992, 31, 82.
39. Bradley, D. C. Private communication (cited in: Nugent, W. A.; Mayer, J. M. Metal-Ligand Multiple Bonds; Wiley: New York, 1988; p 163).
40. Bradley, D. C. Private communication (cited in: Nugent, W. A.; Mayer, J. M. Metal-Ligand Multiple Bonds; Wiley: New York, 1988; p 163).
41. Schaefer, W. P.; Quan, R. W.; Bercaw, J. E. Acta Crystallogr., Sect. C 1993, 49, 878.
42. Hirpo, W.; Curtis, M. D. Organometallics 1994, 13, 2706.
43. (a) Carmona, E.; Marín, J. M.; Palma, P.; Poveda, P. L. J. Organomet. Chem. 1989, 377, 157.
44. (b) Filippou, A. C.; Grünleitner, W.; Völk, C.; Kiprof, P. J. Organomet.Chem. 1991, 413, 181.
45. Filippou, A. C.; Völk, C.; Kiprof, P. J. Organomet. Chem. 1991, 415, 375.
46. Weber, W. P.; Gökel, G. W.; Ugi, I. K. Angew. Chem., Int. Ed. Engl. 1972, 11, 530.
47. Gómez, M.; Jiménez, G.; Royo, P.; Selas, J. M.; Raithby, P. R. J. Organomet. Chem. 1992, 439, 147.
48. Sheldrick, G. M. Acta Crystallogr., Sect. A 1990, 46, 467.
49. Sheldrick, G. M. SHELXL 93; University of Göttingen, Göttingen, Germany, 1993.