Largest discrete supramolecular architecture based on a lanthanide ion: [Lanthanum(III)18{N,N′-bis(2-pyridylmethyl)-N,N′-1,2- ethanediylbis(D-alaninate)}18(H2O)36] 18+

Inorganic Chemistry

Volumn 45, Issue 14, 2006, Pages 5263-5265

  Omata, Kenji ^a   Hoshi, Nagayasu ^a   Kabuto, Kuninobu ^a   Kabuto, Chizuko ^a   Sasaki, Yoichi ^b  

^a TOHOKU UNIVERSITY   (Japan)

^b HOKKAIDO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 33746542135     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic0605625     Document Type: Article

References (25)

1. For recent reviews, see: (a) Uemura, T.; Kitagawa, S. Chem. Lett. 2005, 34, 132-137.
2. (b) Rao, C. N. R.; Natarajan, S.; Vaidhyanathan, R. Angew. Chem., Int. Ed. 2004, 43, 1466-1496.
3. (c) Janiak, C. Dalton Trans. 2003, 2781-2804.
4. (d) Holliday, B. J.; Mirkin, C. A. Angew. Chem., Int. Ed. 2001, 40, 2022-2043.
5. (e) Fujita, M.; Umemoto, K.; Yoshizawa, M.; Fujita, N.; Kusukawa, T.; Biradha, K. Chem. Commun. 2001, 509-518 and references cited therein.
6. For a recent paper, see: Comby, S.; Scopelliti, R.; Imbert, D.; Charbonnière, D.; Ziessel, R.; Bünzli, J.-C. G. Inorg. Chem. 2006, 45, 3158-3160.
7. For reviews, see: (a) Bünzli, J.-C. G.; Piguet, C. Chem. Rev. 2002, 102, 1897-1928.
8. (b) Anwander, R. Angew. Chem., Int. Ed. 1998, 37, 599-602.
9. Also see: Long, D.-L.; Blake, A. J.; Champness, N. R.; Wilson, C.; Schröder, M. Angew. Chem., Int. Ed. 2001, 40, 2443-2447.
10. For a review, see: (a) Müller, A.; Peters, F. Chem. Rev. 1998, 98, 239-271.
11. For recent papers, see: (b) Daniel, C.; Hartl, H. J. Am. Chem. Soc. 2005, 127, 13978-13987.
12. (c) Kurata, T.; Uehara, A.; Hayashi, Y.; Isobe, K. Inorg. Chem. 2005, 44, 2524-2530.
13. (d) Saalfrank, R. W.; Nakajima, T.; Mooren, N.; Scheurer, A.; Maid, H.; Hampel, F.; Trieflinger, C.; Daub, J. Eur. J. Inorg. Chem. 2005, 1149-1153.
14. Wang, R.; Selby, H. D.; Liu, H. D.; Carducci, M. D.; Jin, T.; Zheng, Z.; Anthis, J. W.; Staples, R. J. Inorg. Chem. 2002, 41, 278-286 and references cited therein.
15. For the latest references for a hydroxolanthanide cluster, see: (a) Addamo, M.; Bombieri, G.; Foresti, E.; Grillone, M. D.; Volpe, M. Inorg. Chem. 2004, 43, 1603-1605.
16. (b) Zheng, X. J.; Jin, L. P.; Gao, S. Inorg. Chem. 2004, 43, 1600-1602 and references cited therein.
17. Kajiwara, T.; Wu, H.; Ito, T.; Iki, N.; Miyano, S. Angew. Chem., Int. Ed. 2004, 43, 1832-1835.
18. Kretschmer, W. P.; Teuben, J. H.; Troyanov, S. I. Angew. Chem., Int. Ed. 1998, 37, 88-90.
19. int = 0.076), wR2 (all reflections) = 0.1501.
20. We have been studying the properties of lanthanide-bpba complexes as chiral shift reagents for an aqueous solution. La- and Ce(bpba) complexes resolve the enantiomer signals of α-amino acids and their N-acetyl derivatives. Ce(bpba) differentiates the chirality of the peptide C terminus. These results will be published elswhere.
21. (a) The CH/π interaction: evidence, nature, and consequenses; Nishio, M., Hirota, M., Umezawa, Y., Eds.; Wiley-VCH: New York, 1998.
22. (b) Umezawa, Y.; Tsuboyama, S.; Honda, K.; Uzawa, J.; Nishio, M. Bull. Chem. Soc. Jpn. 1998, 71, 1207-1213.
23. Kabuto, C.; Kabuto, K.; Sasaki, Y.; Nishiyama, T.; Umakoshi, K. J. Chem. Soc., Chem. Commun. 1993, 381-383.
24. (a) Sakagami, N.; Yamada, Y.; Konno, T.; Okamoto, K. Inorg. Chim. Acta 1999, 288, 7-16 and references cited therein.
25. (b) Zheng, Z. Chem. Commun. 2001, 2521-2529.