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note
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We have tried to synthesize a β-diketone with a structure more similar to HCBDK in which the carbazole group is substituted by a fluorene group, thus we got ethyl 2-(9H-fluoren-9-yl)acetate first. However, the active hydrogen of the fluorene ring and methylene may influence the Claisen condensation reaction in some extent, so we switched tactics to synthesize HFBDK.
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note
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CCDC 254344 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/ data_request/cif, by emailing data_request@ccdc.cam.ac.uk, or by contacting The Cambridge Crystallographic Data Centre, 12, Union Road, Cambridge CB2 1EZ, UK; fax: +44 1223 336033.
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