On the glassy state of multiphase and pure polymer materials

Polymer

Volumn 47, Issue 17, 2006, Pages 6243-6253

  Baeurle, Stephan A ^a,b,c   Hotta, Atsushi ^b,c   Gusev, Andrei A ^d  

^a UNIVERSITY OF REGENSBURG   (Germany)

^b University of California   (United States)

^c UNIVERSITY OF CALIFORNIA   (United States)

^d ETH ZURICH   (Switzerland)

Author keywords

Glass transition; Nanophase separated block copolymers; Pure polymers

Indexed keywords

BLOCK COPOLYMERS; CROSSLINKING; GLASS TRANSITION; POLYSTYRENES; STRESS RELAXATION; THERMODYNAMICS;

GLASS THEORY; NANOPHASE-SEPARATED BLOCK COPOLYMERS; PURE POLYMERS; SIGNIFICANT-STRUCTURE THEORY;

THERMOPLASTIC ELASTOMERS;

BLOCK COPOLYMER; ELASTOMER; GLASS TRANSITION TEMPERATURE; NATURAL POLYISOPRENE; POLYBUTADIENE; POLYSTYRENE; THERMODYNAMICS; THERMOPLASTIC POLYMER;

EID: 33746336958     PISSN: 00323861     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.polymer.2006.05.076     Document Type: Article

References (55)

1. Priestley R.D., Ellison C.J., Broadbelt L.J., and Torkelson J.M. Science 309 (2005) 456-459
2. Miracle D.B. Nat Mater 3 (2004) 697-702
3. Yue Y.-Z., and Angell C.A. Nature 427 (2004) 717-720
4. Lundquist P.M., Wortmann R., Geletneky C., Twieg R.J., Jurich M., Lee V.Y., et al. Science 274 (1996) 1182-1185
5. Macfarlane A., and Martin G. Science 305 (2004) 1407-1408
6. Sperling L.H. Introduction to physical polymer science (2001), Wiley, New York
7. Fredrickson G.H. Annu Rev Phys Chem 39 (1988) 149-180
8. Santen L., and Krauth W. Nature 405 (2000) 550-551
9. Merabia S., Sotta P., and Long D. Eur Phys J E 15 (2004) 189-210 and references therein
10. Gibbs J.H., and Di Marzio E.A. J Chem Phys 28 (1958) 373-383
11. Angell C.A. J Non-Cryst Solids 131-133 (1991) 13-31
12. Kauzmann W. Chem Rev 43 (1948) 219-256
13. Gibbs J.H. J Chem Phys 25 (1956) 185-186
14. Di Marzio E.A., and Gibbs J.H. J Chem Phys 28 (1958) 807-813
15. Di Marzio E.A., and Yang A.J.M. J Res Natl Inst Stand Technol 102 (1997) 135-157 and references therein
16. O'Connel P.A., and McKenna G.B. J Chem Phys 110 (1999) 11054-11060
17. Simon S.L., Sobieski J.W., and Plazek D.J. Polymer 42 (2001) 2555-2567
18. Torquato S. Nature 405 (2000) 521-522
19. Kurchan J. Nature 433 (2005) 222-225
20. Spontak R.J., and Patel N.P. Curr Opin Coll 5 (2000) 334-341
21. Baeurle S.A., Fredrickson G.H., and Gusev A.A. Macromolecules 37 (2004) 5784-5791 and references therein
22. Cicerone M.T., Blackburn F.R., and Ediger M.D. Macromolecules 28 (1995) 8224-8232
23. Luchinsky D.G. Contemp Phys 43 (2002) 379-395
24. Wunderlich B. J Chem Phys 64 (1960) 1052-1056
25. Hsu C.C., and Eyring H. Proc Natl Acad Sci 69 (1972) 1342-1345
26. Eyring H., and Ree T. Proc Natl Acad Sci 47 (1961) 526-537
27. Eyring H. J Chem Phys 4 (1936) 283-289
28. Ree T., and Jhon M.S. J Korean Chem Soc 14 (1970) 45-48
29. Fox T.G., and Flory P.J. J Appl Phys 21 (1950) 581-591
30. Adam G., and Gibbs J.H. J Chem Phys 43 (1965) 139-146
31. Miller A.A. J Polym Sci Part A-2 6 (1968) 1161-1175
32. Tammann G., and Pape A. Z Anorg Allg Chem 200 (1931) 113-132
33. Boumiz A., Vernet C., and Cohen Tenoudji C. Adv Cem Based Mater 3 (1996) 94-106
34. Williams M.L., Landel R.F., and Ferry J.D. J Am Chem Soc 77 (1955) 3701-3707
35. n = 76,000. Measurements were performed at temperatures from -40 to 60 °C by applying strains of 1.2 and 5.0 on the samples.
36. In Ref. [41] Hotta et al. performed tensile stress relaxation experiments at different temperatures using SIS copolymers with styrene contents of 14% and 17%. The samples were extended to 125% of their original length at temperatures between 4 °C and 90 °C.
37. n = 200,000. The styrene content of Kraton 102 and SB 40/160 was determined to be about 33% and 20%, respectively. The dynamical mechanical properties of the two block copolymers were measured on twin specimens of different sizes in different temperature regions, to obtain best results. Measurements with specimens A and C were made at temperatures between -60 °C and 30 °C with frequencies from 25 to 798 Hz, while measurements with specimens B were made for temperatures between 30 °C and 130 °C at frequencies from 25 to 1260 Hz. The dynamic measurements on SB 40/160 were made on twin specimens S at temperatures between -9.9 °C and 5.5 °C and at frequencies between 250 and 2500 Hz, as well as on specimens M at temperatures between 9.1 °C and 78.5 °C at the same frequencies.
38. In Ref. [43] Beecher et al. performed dynamic mechanical experiments on SIS copolymers with a molecular weight of 130,000 and a styrene content of 22%. Measurements were made by subjecting the samples to a sinusoidal tensile strain with a constant strain amplitude of 2.5%. The stress on the sample and the phase angle between stress and strain were measured at frequencies from 0.001 Hz to 10 Hz and at temperatures from -50 to 80 °C.
39. Smith T.L., and Dickie R.A. J Polym Sci Part C 26 (1969) 163-187
40. Hotta A., Clarke S.M., and Terentjev E.M. Macromolecules 35 (2002) 271-277
41. Morton M, Tschoegl NW, Froelich D. Technical Report AFML (Air Force Materials Laboratory)-TR-67-408 1969; 2. p. 1-33.
42. Beecher J.F., Marker L., Bradford R.D., and Aggarwal S.L. J Polym Sci Part C 26 (1969) 117-134
43. Curro J.G., and Pincus P. Macromolecules 16 (1983) 559-562
44. Smith T.L. Time-dependent mechanical properties of elastomeric block polymers in large tensile deformations. In: Aggarwal S.L. (Ed). Block polymers (1970), Plenum Press, New York 137-151
45. Dair B.J., Avgeropoulos A., Hadjichristidis N., and Thomas E.L. J Mater Sci 35 (2000) 5207-5213
46. Wang Y., Wang B., and Shen J. J Appl Polym Sci 92 (2004) 2593-2598 and references therein
47. Baeurle S.A., Hotta A., and Gusev A.A. Polymer 46 (2005) 4344-4354
48. Gurtovenko A.A., and Gotlib Y.Y. J Chem Phys 115 (2001) 6785-6793
49. Wunderlich B., and Bodily D.M. J Appl Phys 35 (1964) 103-104
50. Bares J. Macromolecules 8 (1975) 244-246
51. Shen M., and Kaelble D.H. J Polym Sci Part B Polym Lett 8 (1970) 149-153
52. Fredrickson G.H., Ganesan V., and Drolet F. Macromolecules 35 (2002) 16-39
53. Baeurle S.A., Martonak R., and Parrinello M. J Chem Phys 117 (2002) 3027-3039
54. Baeurle S.A. J Comput Phys 184 (2003) 540-558
55. Baeurle S.A. Comput Phys Commun 157 (2004) 201-206