Zinc thiolate complexes [ZnLn(SR)]+ with azamacrocyclic ligands, part II: Mechanism of the reaction with CS2

European Journal of Inorganic Chemistry

Volumn , Issue 14, 2006, Pages 2783-2791

  Notni, Johannes ^a   Schenk, Stephan ^a   Roth, Arne ^a   Plass, Winfried ^a   Görls, Helmar ^a   Uhlemann, Ute ^a   Walter, Angela ^a   Schmitt, Michael ^a   Popp, Jürgen ^a   Chatzipapadopoulos, Susana ^a   Emmler, Thomas ^b   Breitzke, Hergen ^a   Leppert, Jörg ^c   Buntkowsky, Gerd ^a   Kempe, Kristian ^a   Anders, Ernst ^a  

^a FRIEDRICH SCHILLER UNIVERSITY JENA   (Germany)

^b FREIE UNIVERSITÄT BERLIN   (Germany)

^c FRITZ LIPMANN INSTITUTE   (Germany)

Author keywords

Density functional calculations; Enzyme models; Heterocumulenes; Macrocyclic ligands; Zinc

Indexed keywords

ACTIVATION ENERGY; CARBON DISULFIDE; CHLORINE COMPOUNDS; DISSOCIATION; ENZYMES; FREE ENERGY; LIGANDS; RATE CONSTANTS; ZINC COMPOUNDS;

AZAMACROCYCLIC; DENSITY-FUNCTIONAL CALCULATIONS; ENZYME MODELS; FREE ENERGY OF ACTIVATIONS; HETEROCUMULENES; MACRO-CYCLIC LIGANDS; TRITHIOCARBONATE; ZINC; ZINC THIOLATES;

DENSITY FUNCTIONAL THEORY;

EID: 33746210206     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.200500948     Document Type: Article

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