Synthesis, characterization of [{(N-methyl-N-benzyl)amino}methyl]ferrocenes and their cyclopalladated complexes: Crystal structure of σ-Pd[(η5-C5H5)Fe(η5-C5H3CH2N(CH3)CH2C6H4NO2-4)]Cl(PPh3)

Inorganica Chimica Acta

Volumn 359, Issue 12, 2006, Pages 4114-4120

  Wang, Hong Xing ^a   Wu, Hong Fei ^a   Zhou, Hui Chao ^a   Geng, Feng Ying ^a   Gao, Ren Qing ^a   Yang, Xiao Li ^a   Wan, Li ^a   Zhang, Wen Qin ^a   Jin, Rong ^b  

^a TIANJIN UNIVERSITY   (China)

^b TIANJIN FIRST CENTRAL HOSPITAL   (China)

Author keywords

Crystal; Cyclopalladation; Ferrocenylamines; N methylation; Stereoselectivity

Indexed keywords

ALKYLATION; CRYSTAL STRUCTURE; CRYSTALS; METHYLATION; ORGANOMETALLICS; SINGLE CRYSTALS; SODIUM BOROHYDRIDE; STEREOSELECTIVITY; SYNTHESIS (CHEMICAL);

CYCLOPALLADATED COMPLEXES; CYCLOPALLADATION; FERROCENYLAMINES; N-METHYLATION; POSSIBLE MECHANISMS; SINGLE CRYSTAL X-RAY DIFFRACTION; SODIUM ACETATE; SUBSTITUTED BENZALDEHYDES;

PALLADIUM COMPOUNDS;

EID: 33746209332     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ica.2006.05.019     Document Type: Article

References (38)

1. Dupont J., Consorti C.S., and Spencer J. Chem. Rev. 105 (2005) 2527
2. Vicente J., and Arcas A. Coordin. Chem. Rev. 249 (2005) 1135
3. Togni A., and Venanzi L.M. Angew. Chem., Int. Ed. Engl. 33 (1994) 497
4. Ryabov A.D. Chem. Rev. 90 (1990) 403
5. Dunina V.V., Zalevskaya O.A., and Potatov V.M. Russ. Chem. Rev. 57 (1988) 250
6. Omae I. Coordin. Chem. Rev. 83 (1988) 137
7. Newkome G.R., Puckett W.E., Gupta V.K., and Kiefer G.E. Chem. Rev. 86 (1986) 451
8. Omae I. Chem. Rev. 79 (1979) 287
9. Brice M.I. Angew. Chem., Int. Ed. Engl. 10 (1977) 73
10. Iyer S., and Ramesh C. Tetrahedron Lett. 41 (2000) 8981
11. Weissmann H., and Milstein D. Chem. Commun. (1999) 1901
12. Sokolov V.I., Bashilova T.A., Musaev A.A., and Reutov O.A. J. Organomet. Chem. 182 (1979) 537
13. Bosque R., Lopez C., and Sales J. J. Organomet. Chem. 498 (1995) 147
14. Examples of cyclopalladation on tertiary amines:. Tollari F., Demartin S., Cenini S., Palmisano G., and Raimondi P. J. Organomet. Chem. 527 (1997) 93
15. Widenhoefer R.A., Zhong H.A., and Buchwald S.L. Organometallics 15 (1996) 2745
16. Pfeffer M., Beydoun N.S., Cian A.D., and Fischer J. J. Organomet. Chem. 453 (1993) 139
17. Alsters P.L., Engel P.F., Hogerheide M.P., Copijn M., Spek A.L., and van Koten G. Organometallics 12 (1993) 1831
18. Grellier M., and Pfeffer M. J. Organomet. Chem. 548 (1997) 301
19. Chakladar P., Paul S., Mukherjee A.K., Dutta S.K., Nanda K.K., Podder D., and Nag K. J. Chem. Soc., Dalton Trans. (1992) 3119
20. Vicente J., Liamas I.S., and Jones P.G. J. Chem. Soc., Dalton Trans. (1993) 3619
21. Lopez C., Bosque R., Solans X., and Font-Bardia M. New J. Chem. (1998) 977
22. Examples of cyclopalladation on secondary amines:. Fuchita Y., and Tsuchiya H. Inorg. Chim. Acta. 209 (1993) 229
23. Clark P.W., and Dyke S.F. J. Organomet. Chem. 281 (1985) 389
24. Examples of cyclopalladation on primary amines:. Albert J., Cadena M., and Granell J. Tertrahedron, Asymm. 8 (1997) 991
25. Albert J., Granell J., Zafrilla J., Font-Bardia M., and Solans X. J. Organomet. Chem. 690 (2005) 422
26. Lopez C., Sales J., Solans X., and Zquiak R. J. Chem. Soc., Dalton Trans. 2321 (1992)
27. Bosque R., Lopez C., Sales J., Solans X., and Font-Bardia M. J. Chem. Soc., Dalton Trans. 735 (1994)
28. Wang H.X., Ding L., and Wu Y.J. J. Organomet. Chem. 679 (2003) 130
29. Wang H.X., Li Y.J., Jin R., Niu J.R., Wu H.F., Zhou H.C., Xu J., Gao R.Q., and Geng F.Y. J. Organomet. Chem. 691 (2006) 987
30. Wang H.X., Li Y.J., Gao R.Q., Wu H.F., Geng F.Y., and Jin R. Inorg. Chem. Commun. 9 (2006) 658
31. H.X. Wang, H.F. Wu, H.C. Zhou, R. Jin, R.Q. Gao, F.Y. Geng, J. Xu, Y.J. Li, W.Q. Zhang, Polyhedron 9 (2006) in press.
32. Borch R.F., and Hassid A.I. J. Org. Chem. 37 (1972) 1673
33. Allen T.H., and Kennard O. Chem. Design Automation News 8 (1993) 146
34. Ranatunge-Bandarage P.R.R., Robinson B.H., and Simpson J. Organometallics 13 (1994) 500
35. Wang H.X., Wu H.F., Geng F.Y., Gao R.Q., and Zhou H.C. Acta Crystallogr. E62 (2006) m14
36. Sun H., Wang Q., Huang R., Li H., and Li Y. J. Organomet. Chem. 655 (2002) 182
37. G.M. Sheldrick, sadabs, University of Göttingen, 1996.
38. G.M. Sheldrick, shelxs-97 and shelxl-97, Programs for Crystal Structure Solution and Refinement, University of Göttingen, 1997.