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Volumn 15, Issue 12, 1996, Pages 2745-2754

Synthesis and solution structure of palladium tris(o-tolyl)phosphine mono(amine) complexes

Author keywords

[No Author keywords available]

Indexed keywords


EID: 0001066461     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om9509599     Document Type: Article
Times cited : (69)

References (88)
  • 15
    • 0000618599 scopus 로고
    • While this work was in progress, Hartwig and co-workers reported the syntheses of some palladium tris(o-tolyl)phosphine amine adducts: Paul, F.; Patt, J.; Hartwig, J. F. Organometallics 1995, 14, 3030.
    • (1995) Organometallics , vol.14 , pp. 3030
    • Paul, F.1    Patt, J.2    Hartwig, J.F.3
  • 17
    • 5844287005 scopus 로고    scopus 로고
    • note
    • 2 and none of the corresponding bis(phosphine) monomer (see Experimental Section).
  • 21
    • 0001279423 scopus 로고    scopus 로고
    • The equilibrium constant for the formation of palladium amine adducts from the corresponding halide dimers is dependent on both the halide ligand and the amine: Widenhoefer, R. A.; Buchwald, S. L. Organometallics 1996, 15, 2755.
    • (1996) Organometallics , vol.15 , pp. 2755
    • Widenhoefer, R.A.1    Buchwald, S.L.2
  • 22
    • 5844287006 scopus 로고    scopus 로고
    • note
    • The rate and extent of formation of bis(amine) complexes was dependent on both the amine and the halide ligand. We are currently investigating the formation of palladium bis(amine) complexes in detail as a potential chain-limiting step in the catalytic cross-coupling of aryl bromides and primary amines.
  • 61
    • 85087247612 scopus 로고    scopus 로고
    • note
    • 3.
  • 87
    • 85087251005 scopus 로고    scopus 로고
    • note
    • 3Pd: C, 66.9 (67.16); H, 4.6 (4.75); Pd, 23.2 (23.08).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.