Separation and preconcentration of cesium from acidic media by extraction chromatography

Separation Science and Technology

Volumn 41, Issue 10, 2006, Pages 2183-2204

  Dietz, Mark L ^a   Ensor, Dale D ^b   Harmon, Ben ^b   Seekamp, Stefan ^a  

^a ARGONNE NATIONAL LABORATORY   (United States)

^b TENNESSEE TECHNOLOGICAL UNIVERSITY   (United States)

Author keywords

Calixarene; Cesium; Extraction chromatography; Preconcentration; Separation

Indexed keywords

CHROMATOGRAPHIC ANALYSIS; EXTRACTION; OLEFINS; POLYMERS; RADIOISOTOPES; SUBSTRATES;

CALIXARENE; EXTRACTION CHROMATOGRAPHY; PRECONCENTRATION;

CESIUM;

CESIUM; CHROMATOGRAPHIC ANALYSIS; EXTRACTION; OLEFINS; POLYMERS; RADIOISOTOPES; SUBSTRATES;

CHLORINATION; CHROMATOGRAPHY; CONCENTRATION; EXTRACTION METHOD; NITRIC ACID; POLYMER; SEPARATION; SYNTHETIC RESIN;

EID: 33746198058     PISSN: 01496395     EISSN: 15205754     Source Type: Journal    
DOI: 10.1080/01496390600744480     Document Type: Conference Paper

References (50)

1. Schulz, W.W. and Bray, L.A. (1987) Solvent extraction recovery of byproduct cesium-137 and strontium-90 from nitric acid solutions. A technology review and assessment Sep. Sci. Technol., 22 (2-3): 191-214.
2. Horwitz, E.P. and Schulz, W.W. (1999) Solvent extraction in the treatment of acidic high-level liquid waste: Where do we stand? Metal Ion Separation and Preconcentration: Progress and Opportunities, Bond, A.M., Dietz, M.L. and Rogers, R.D. (eds.); American Chemical Society: Washington, DC, 20-50.
3. Bonnesen, P.V., Haverlock, T.J., Engle, N.L., Sachleben, R.A., and Moyer, B.A. (2000) Development of process chemistry for the removal of cesium from acidic nuclear waste by calix[4]arene-crown-6 ethers. In Calixarenes for Separations, Lumetta, G.J., Rogers, R.D. and Gopalan, A.S. (eds.); American Chemical Society: Washington, DC, 26-44.
4. Vandervell, H.D. and Morgan, A. (1965) The determination of caesium-137 in herbage and soil. Analyst, 90: 283-289.
5. 137Cs in environmental samples. Anal. Chim. Acta, 294: 221-226.
6. 137Cs. J. Radioanal. Nucl. Chem., 121: 415-428.
7. Dozol, J.F., Asfari, Z., Arnaud-Neu, F., Vicens, J., and Thuery, P. (2004) Extraction of rubidium and caesium from strongly alkaline media. Radiochim. Acta, 92: 175-182.
8. Boni, A.L. (1966) Rapid ion exchange analysis of radiocesium in milk, urine, sea water, and environmental samples. Anal. Chem., 38: 89-92.
9. Fardy, J.J. (1992) Preconcentration of trace elements by ion exchangers. In Preconcentration Techniques for Trace Elements, Alfassi, Z.B. and Wai, C.M. (eds.); CRC Press: Boca Raton, FL, 181-210.
10. Zouad, S., Loos-Neskovic, C., Gamier, E., Jeanjean, J., and Fedoroff, M. (1990) Recovery of fission products by fixation on inorganic sorbents. In Recent Developments in Ion Exchange, Williams, P.A. and Hudson, M.J. (eds.); Elsevier, New York; Vol. 2, 151-159.
11. Haas, P.A. (1993) A review of information on ferrocyanide solids for removal of cesium from solutions. Sep. Sci. Technol., 28 (17-18): 2479-2506.
12. Clearfield, A., Poojary, D.M., Behrens, E.A., Cahill, R.A., Bortun, A.I., and Bortun, L.N. (1999) Structural Basis of Selectivity in Tunnel Type Inorganic Ion Exchangers. In Metal Ion Separation and Preconcentration: Progress and Opportunities, Bond, A.H., Dietz, M.L. and Rogers, R.D. (eds.); American Chemical Society: Washington, DC, 168-182.
13. Andao, D. (1992) Radiochemical neutron activation analysis of Cs and Rb in geological samples using zeolite (Clinoptilite) chromatography and sodium tetraphenylborate precipitation. J. Radioanal. Nucl. Chem., 159: 293-299.
14. Roane, J.E., DeVol, T.A., Leyba, J.D., and Fjeld, R.A. (1999) Effects of ionic radiological and chemical interferences on the chromatographic separation of a radionuclide standard solution. J. Radioanal. Nucl. Chem., 240: 197-208.
15. 137Cs in urine by the AMP-chlorostannate method. J. Radioanal. Nucl. Chem., 125: 431-437.
16. LaRosa, J.J., Burnett, W., Lee, S.H., Levy, I., Gastaud, J., and Povinec, P.P. (2001) Separation of actinides, cesium, and strontium from marine samples using extraction chromatography and sorbents. J. Radioanal. Nucl. Chem., 248: 765-770.
17. Güçlü, K., Apak, R., Tütem, E., and Atun, G. (2004) Determination and preconcentration of natural and radio-cesium from aqueous solution. J. Radioanal. Nucl. Chem., 259: 209-211.
18. Petrow, H.G. and Levine, H. (1967) Ammonium hexacyanocobalt ferrate as an improved inorganic exchange material for determination of cesium-137. Anal. Chem., 39: 360-362.
19. Onodera, Y., Mimura, H., Iwasaki, T., Hayashi, H., Ebina, T., and Chatterjee, M. (1999) A new granular composite with high selectivity for cesium ion prepared from phosphomolybdic acid hydrate and inorganic porous material. Sep. Sci. Technol., 34: 2347-2354.
20. 137Cs in milk by sorption on freshly prepared precipitate of Cu(II) hexacyanoferrate in combination with gamma spectrometry. Coll. Czech. Chem. Commun., 53: 3058-3066.
21. Cesarano, C., Pugnetti, G., and Testa, C. (1965) Separation of Cesium-137 from fission products by means of a Kel-F column supporting tetraphenylboron. J. Chrom., 19: 589-593.
22. Testa, C. and Cesarano, C. (1965) Separation of Cs-137 from fission products by means of a Kel-F column supporting dipicrylamine. J. Chrom., 19: 594-598.
23. Kyrs, M. and Kadlecová, L. (1968) Separation of alkali metals by extraction chromatography with dipicrylamine and nitrobenzene. J. Radioanal. Nucl. Chem., 1: 103-112.
24. Smulek, W. and Lada, W. (1977) Separation of alkali metals by extraction chromatography using polyethers. Radiochem. Radioanal. Lett., 30: 199-208.
25. Smulek, W. and Lada, W. (1979) Separation of alkali and alkaline earth metals by polyethers using extraction chromatography. Effect of diluent. J. Radioanal. Chem., 50: 169-178.
26. 137Cs from a mixture of radionuclides. Radiochem. Radioanal. Lett., 50: 333-343.
27. Peimli, E. (1990) Extraction chromatography of Cs and Na using crown ethers loaded on a solid support. J. Radioanal. Nucl. Chem., Lett., 144: 9-15.
28. Kremliakova, N.Y., Novikov, A.P., and Myasoedov, B.F. (1990) Extraction chromatographic separation of radionuclides of strontium, cesium, and barium with the use of TVEK-DCH18C6. J. Radioanal. Nucl. Chem., Lett., 145: 23-28.
29. + coupled transport of cations through a liquid membrane by macrocyclic calixarene ligands. J. Am. Chem., Soc., 105: 1782-1785.
30. Dozol, J.F., Dozol, M., and Macias, R.M. (2000) Extraction of strontium and cesium by dicarbollides, crown ethers and functionalized calixarenes. J. Incl. Phenom., 38: 1-22.
31. Alfieri, C., Dradi, E., Pochini, A., Ungaro, R., and Andreetti, G.D. (1983) Synthesis, and X-ray Crystal and Molecular Structure of a Novel Macrobicyclic Ligand: Crowned p-t-Butyl-calix[4]arene. J. Chem. Soc. Chem., Commun., 1075-1076.
32. Ungaro, R., Casnati, A., Ugozzoli, Pochini, A., Dozol, J.F., Hill, C., and Rouquette, H. (1994) 1,3-Dialkoxycalix[4]arenecrowns-6 in 1,3-alternate conformation: Cesium-selective ligands that exploit cation-arene interactions. Angew. Chem. Int. Ed. Engl., 33: 1506-1509.
33. Asfari, Z., Bressot, C., Vicans, J., Hill, C., Dozol, J.-F., Rouquette, H., Eymard, S., Lamare, V., and Tournois, B. (1995) Doubly crowned calix[4]arenes in the 1,3-alternate conformation as cesium-selective carriers in supported liquid Membranes. Anal. Chem., 67: 3133-3139.
34. Shama, K.R. and Agrawal, Y.K. (2004) Analytical potentialities of Calix-crown ethers. Rev. Anal. Chem., 23: 133-158.
35. Dietz, M.L. (2004) Recent Progress in the Development of Extraction Chromatographic methods for radionuclide separation and preconcentration. In Radioanalytical Methods in Interdisciplinary Research: Fundamentals in Cutting-Edge Applications, Laue, C.A. and Nash, K.L. (eds.); American Chemical Society: Washington, DC, 161-176.
36. Horwitz, E.P., Dietz, M.L., Nelson, D.M., LaRosa, J.J., and Fairman, W.D. (1990) Concentration and separation of actinides from urine using a supported bifunctional organophosphorus extractant. Anal. Chim. Acta, 238: 263-271.
37. Horwitz, E.P., Dietz, M.L., and Fisher, D.E. (1991) Separation and preconcentration of strontium from biological, environmental, and nuclear waste samples by extraction chromatography using a crown ether. Anal. Chem., 63: 522-525.
38. Horwitz, E.P., Chiarizia, R., and Dietz, M.L. (1992) A novel strontium-selective extraction chromatographic resin. Solv. Extr. Ion Exch., 10: 313-336.
39. Dietz, M.L., Horwitz, E.P., and Bond, A.H. (1999) Extraction chromatography: progress and opportunities. In Metal Ion Separation and Preconcentration: Progress and Opportunities, Bond, A.H., Dietz, M.L. and Rogers, R.D. (eds.); American Chemical Society: Washington, DC, 234-250.
40. Cortina, J.L., Miralles, N., Aguilar, M., and Sastre, A.M. (1994) Solvent impregnated resins containing Di(2-ethylhexyl)phosphoric acid. II. study of the distribution equilibria of Zn(II), Cu(II), and Cd(II). Solv. Extr. Ion Exch., 12: 371-391.
41. Gonzalo, A., Muraviev, D., and Valiente, M. (2001) Influence of polymeric support on selectivity of extractant in solvent impregnated resins. In Solvent Extraction for the 21st Century (Proceedings of ISEC'99). Cox, M., Hidalgo, M. and Valiente, M. (eds.), Society of the Chemical Industry: London; Vol. 1, 1273-1277.
42. Strikovsky, A.G., Jerabek, K., Cortina, J.L., Sastre, A.M., and Warshawsky, A. (1996) Solvent impregnated resin (SIR) containing dialkyl dithiophosphoric acid on amberlite XAD-2: Extraction of copper and comparison to the liquid-liquid extraction. React. Funct. Polym., 28: 149-158.
43. Horwitz, E.P., Dietz, M.L., Chiarizia, R., Diamond, H., Maxwell, S.L., III, and Nelson, M.R. (1995) Separation and preconcentration of actinides by extraction chromatography using a supported liquid anion exchanger: Application to the characterization of high-level nuclear waste solutions. Anal. Chim. Acta, 310: 63-78.
44. Izatt, R.M., Bradshaw, J.S., Nielsen, S.A., Lamb, J.D., and Christensen, J.J. (1985) Thermodynamic and Kinetic Data for Cation-Macrocycle Interaction. Chem. Rev., 85: 271-339.
45. Izatt, R.M., Pawlak, K., Bradshaw, J.S., and Bruening, R.L. (1991) Thermodynamic and kinetic data for macrocycle interaction with cations and anions. Chem. Rev., 91: 1721-2085.
46. Instructions for Use, Empore™ Cesium Rad Disks, 3M Filtration Products. St. Paul, MN, 2004, 2.
47. Horwitz, E.P., Chiarizia, R., Dietz, M.L., and Diamond, H. (1993) Separation and preconcentration of actinides from acidic media by extraction chromatography. Anal. Chim. Acta, 281: 361-372.
48. Dietz, M.L., Yaeger, J., Sajdak, L.R., Jr., and Jensen, M.P. (2005) Characterization of an improved extraction chromatographic material for the separation and preconcentration of strontium from acidic media. Sep. Sci. Technol., 40: 349-366.
49. Bonnesen, P.V., Haverlock, T.J., Engle, N.L., Sachleben, R.A., and Moyer, B.A. (2000) Development of process chemistry for the removal of cesium from acidic nuclear waste by calix[4]arene-crown-6 ethers. In Calixarenes for Separations, Lumetta, G.J., Rogers, R.D. and Gopalan, A.S. (eds.); American Chemical Society: Washington, DC, 26-44.
50. Dewberry, R.A., Boyce, W.T., Bibler, N.E., Ekechukwu, A.E., and Ferrara, D.M. (2002) Separation and purification and beta liquid scintillation analysis of 151 Sm in savannah river site and hanford site DOE high level waste. J. Radioanal. Nucl. Chem., 252: 503-513.