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Volumn 50, Issue 7, 1999, Pages 219-231

Recent advance in syntheses and applications of well-defined endfunctionalized polymers by means of anionic living polymerization

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EID: 33746072579     PISSN: 03237648     EISSN: None     Source Type: Journal    
DOI: 10.1002/(sici)1521-4044(19990701)50:7<219::aid-apol219>3.3.co;2-l     Document Type: Article
Times cited : (119)

References (114)
  • 1
    • 33746061489 scopus 로고
    • Reactive Oligomers, ACS Symposium Series, No. 282
    • Washington, D.C.
    • a) F.W. Harris, H.J. Spinelli, Reactive Oligomers, ACS Symposium Series, No. 282, Am. Chem. Soc., Washington, D.C. 1985;
    • (1985) Am. Chem. Soc.
    • Harris, F.W.1    Spinelli, H.J.2
  • 25
    • 33746051908 scopus 로고    scopus 로고
    • unpublished results. End-functionalized polystyrenes with aldehyde, ketone, and ethynyl groups were obtained by reacting of polystyryllithium with the terminators followed by deprotection (see Fig. 2). Degrees of end-functionalities were 93-100% in all cases.
    • A. Hirao, unpublished results. End-functionalized polystyrenes with aldehyde, ketone, and ethynyl groups were obtained by reacting of polystyryllithium with the terminators followed by deprotection (see Fig. 2). Degrees of end-functionalities were 93-100% in all cases.
    • Hirao, A.1
  • 30
    • 33746080627 scopus 로고    scopus 로고
    • A. Hirao, unpublished results. End-functionalized polystyrenes and polyisoprenes with two or three hydroxy groups were obtained by reacting with either acetal- or orthoester-protected cu-bromoalkanes. Yields of functionalizations were more than 95% in both cases.
    • A. Hirao, unpublished results. End-functionalized polystyrenes and polyisoprenes with two or three hydroxy groups were obtained by reacting with either acetal- or orthoester-protected cu-bromoalkanes. Yields of functionalizations were more than 95% in both cases.
  • 38
    • 33746092710 scopus 로고    scopus 로고
    • It was clearly observed that characteristic orange-red and yellow colors of anionic living polymers of styrène and isoprene disappeared within a second on mixing of the reagent.
    • It was clearly observed that characteristic orange-red and yellow colors of anionic living polymers of styrène and isoprene disappeared within a second on mixing of the reagent.
  • 49
    • 33746056709 scopus 로고    scopus 로고
    • A. Hirao and C.W. Macosko, unpublished results.
    • A. Hirao and C.W. Macosko, unpublished results.
  • 52
    • 85087245067 scopus 로고    scopus 로고
    • n = 1.05). The degree of terminal hydroxy functionality was found to be 98%.
    • n = 1.05). The degree of terminal hydroxy functionality was found to be 98%.


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