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Acta Polymerica
Volumn 49, Issue 4, 1998, Pages 133-144
Anionic living polymerization of functionalized monomers
Author keywords

[No Author keywords available]
Indexed keywords

ANIONIC POLYMERIZATION; BLOCK COPOLYMERS; DERIVATIVES; MACROMOLECULES; MOLECULAR STRUCTURE; MOLECULAR WEIGHT DISTRIBUTION; MONOMERS;
EID: 0032049838     PISSN: 03237648     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-4044(199804)49:4<133::AID-APOL133>3.0.CO;2-P     Document Type: Article
Times cited : (52)
References (106)
  • 7
    • 85034200267 scopus 로고    scopus 로고
    • Both 1,3-butadiene and isoprene undergo anionic polymerization to afford living polymers that have nearly the same grade of living polystyrene with regard to molecular weight control and reactivity and stability of the propagating carbanions.
    • Both 1,3-butadiene and isoprene undergo anionic polymerization to afford living polymers that have nearly the same grade of living polystyrene with regard to molecular weight control and reactivity and stability of the propagating carbanions.
  • 17
    • 85034183377 scopus 로고    scopus 로고
    • In the anionic polymerization of 2-methoxystyrene in toluene at 20 °C, side reactions were suggested to occur by Smets et al. (J. Polym. Sci. A-1, 1969, 7, 2859). However, we found that the polymerizations of this monomer in THF at -78 °C with secBuLi gave good molecular weight control with narrow molecular weight distributions (Afw/Mn < 1.05).
    • In the anionic polymerization of 2-methoxystyrene in toluene at 20 °C, side reactions were suggested to occur by Smets et al. (J. Polym. Sci. A-1, 1969, 7, 2859). However, we found that the polymerizations of this monomer in THF at -78 °C with secBuLi gave good molecular weight control with narrow molecular weight distributions (Afw/Mn < 1.05).
  • 35
    • 85034188367 scopus 로고    scopus 로고
    • A. Hirao, unpublished results. The anionic polymerization of 8 proceeded quantitatively in THF at -78 °C for 0.5 h with secBuLi capped with a-methylstyrene. The Mn values calculated and observed and A/w/A/n of the resulting polymer were 21000 g/ mol, 21000 g/mol, and 1.02. . '
    • A. Hirao, unpublished results. The anionic polymerization of 8 proceeded quantitatively in THF at -78 °C for 0.5 h with secBuLi capped with a-methylstyrene. The Mn values calculated and observed and A/w/A/n of the resulting polymer were 21000 g/ mol, 21000 g/mol, and 1.02. . '
  • 52
    • 85034190381 scopus 로고    scopus 로고
    • A. Hirao, unpublished results. 31 a and 31 b underwent anionic polymerization quantitatively in THF at -78 °C with cumylpotassium for 1 h. The A/n values of the resulting polymers of 31 a and 31 b were observed to be controlled in the range of 1000050000 g/mol. These polymers possessed narrow molecular weight distributions, A/w/A/n values being less than 1.05.
    • A. Hirao, unpublished results. 31 a and 31 b underwent anionic polymerization quantitatively in THF at -78 °C with cumylpotassium for 1 h. The A/n values of the resulting polymers of 31 a and 31 b were observed to be controlled in the range of 1000050000 g/mol. These polymers possessed narrow molecular weight distributions, A/w/A/n values being less than 1.05.
  • 69
    • 0001391988 scopus 로고
    • Organic Silicon Compounds
    • Ed: D.N. Jones, Pergamon, Oxford
    • I. Fleming, "Organic Silicon Compounds", in Comprehensive Organic Chemistry, Vol. 3 (Ed: D.N. Jones), Pergamon, Oxford 1979, pp. 541-686.
    • (1979) Comprehensive Organic Chemistry , vol.3 , pp. 541-686
    • Fleming, I.1
  • 75
    • 85034161275 scopus 로고    scopus 로고
    • A. Hirao, unpublished results. The anionic polymerization of 43 was carried out with potassium naphthalenide in THF at -78 CC for 0.5 h. The polymer yield was 100%. The A/n values calculated and observed were 14000 g/mol and 13000 g/mol, respectively.
    • A. Hirao, unpublished results. The anionic polymerization of 43 was carried out with potassium naphthalenide in THF at -78 CC for 0.5 h. The polymer yield was 100%. The A/n values calculated and observed were 14000 g/mol and 13000 g/mol, respectively.
  • 102
    • 85034158762 scopus 로고    scopus 로고
    • A. Hirao, unpublished results. The anionic polymerization of 51 h was carried out in THF at -78 for 0.5 h with 1,1-diphenylhexyllithium in the presence of 5 equivalents of LiCl. Yields of polymers were always quantitative. The value of Mn calculated and observed were, for example, 11000 g/mol, 25000 g/mol, and 11000 g/mol, 26000 g/mol, respectively. The A/w/A/n values of these polymer samples were 1.05 and 1.06, respectively
    • A. Hirao, unpublished results. The anionic polymerization of 51 h was carried out in THF at -78 for 0.5 h with 1,1-diphenylhexyllithium in the presence of 5 equivalents of LiCl. Yields of polymers were always quantitative. The value of Mn calculated and observed were, for example, 11000 g/mol, 25000 g/mol, and 11000 g/mol, 26000 g/mol, respectively. The A/w/A/n values of these polymer samples were 1.05 and 1.06, respectively.

* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.