Effect on kinetics by deuterium in the 1,5-hydrogen shift of a cisoid-locked 1,3(Z)-pentadiene, 2-methyl-10-methylenebicyclo[4.4.0]dec-1-ene: Evidence for tunneling?

Journal of the American Chemical Society

Volumn 128, Issue 28, 2006, Pages 9080-9085

  Von E Doering, William ^a   Zhao, Xin ^a  

^a HARVARD UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

DEUTERIUM; ELECTRON TUNNELING; EXTRAPOLATION; REACTION KINETICS; TEMPERATURE DISTRIBUTION; THERMAL EFFECTS;

2-METHYL-10-METHYLENEBICYCLO[4.4.0]DEC-1-ENE; ARRHENIUS PLOTS; CISOID VERSION; PENTADIENE;

OLEFINS;

1 PHENYL 5 TOLYL 1,3 PENTADIENE; 2 METHYL 10 METHYLENEBICYCLO[4.4.0]DEC 1 ENE; ALKADIENE; BICYCLO COMPOUND; DEUTERIUM; HYDROGEN; UNCLASSIFIED DRUG;

ACCURACY; ARTICLE; CALCULATION; CHEMICAL REACTION KINETICS; CONFORMATION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; QUANTITATIVE ANALYSIS; REACTION ANALYSIS; ROOM TEMPERATURE; STEREOCHEMISTRY; TEMPERATURE DEPENDENCE;

EID: 33746035683     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja057377v     Document Type: Article

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