Which sites are the active sites in TiO2-SiO2 mixed oxides?

Catalysis Today

Volumn 116, Issue 2 SPEC. ISS., 2006, Pages 99-110

  Notari, Bruno ^a   Willey, Ronald J ^a   Panizza, Marta ^b   Busca, Guido ^b  

^a Northeastern University   (United States)

^b UNIVERSITY OF GENOA   (Italy)

Author keywords

1 Butene; Acidity; Isomerization; Silica; Titanium dioxide

Indexed keywords

ACIDITY; BUTENES; CATALYSIS; CATALYSTS; INDUSTRIAL APPLICATIONS; INDUSTRIAL RESEARCH; ISOMERIZATION; SILICA; THERMAL EFFECTS; TITANIUM DIOXIDE;

1-BUTENETY; ACID-INDUCING IMPURITIES; CATALYTIC ACTIVITY; INDUSTRIAL MATERIALS;

TITANIUM OXIDES;

EID: 33745924106     PISSN: 09205861     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cattod.2006.02.086     Document Type: Article

References (44)

1. 2 and its catalytic activities for the amination of phenol, the hydration of ethylene and the isomerization of butene. J. Catal. 35 (1974) 225
2. H.P. Wulff, Expoxidation process with improved heterogeneous catalyst, 1975, U.S. Patent 3,923,843.
3. B. Notari, Microporous crystalline titanium silicates, Adv. Catal. 41 (1996) 253-334. Academic Press.
4. Tanabe K. Solid acid and base catalysts. In: Anderson J.R., and Boudart M. (Eds). Catalysis Science and Technology vol. 2 (1981), Springer, Verlag 255
5. G. Bellussi, M.S. Rigutto, Metal ions associated to the molecular sieve framework: possible catalytic oxidation sites, Stud. Surf. Sci. Catal. 85 (1994) 177. Elsevier.
6. Vayssilov G.N. Structural and physico-chemical features of titanium silicalites. Catal. Rev. Sci. Eng. 39 (1997) 209
7. Saxton R.J. Crystalline microporous titanium silicates. Top. Catal. 9 1 (1999) 43-57
8. Sheldon R.A., Arends I.W., and Dijksman A. New developments in catalytic alcohol oxidations for fine chemicals synthesis. Catal. Today 57 (2000) 157-166
9. Dusi M., Mallat T., and Baiker A. Epoxidation of functionalized olefins over solid catalysts. Catal. Rev. 42 (2000) 15
10. Ratnasamy P., Srinivas D., and Knozinger H. Active sites and reactive intermediates in titanium silicate molecular sieves. Adv. Catal. 48 (2004) 1-169
11. M. Taramasso, G. Perego, B. Notari, Preparation of porous crystalline synthetic material comprised of silicon and titanium oxides, 1983, U.S. Patent 4,410,501.
12. T. Suzuki, Active site model of a high silica MFI zeolite for the vapor phase rearrangement of cyclohexanone oxime to caprolactam, in: Proceedings of the Fifth International Symposium on Acid Base Catalysis, July 1, Puerta Vallarte, Mexico, 2005, Paper O-14.
13. McCoy M. New routes to propylene oxide. C&EN 79 (2001) 19-20
14. Tullo A. Chem. Eng. News 82 36 (2004) 15
15. B. Notari, Synthesis and catalytic properties of Ti-containing zeolites, in: Innovation in Zeolites, Stud. Surf. Sci. Catal. 37 (1987) 413. Elsevier.
16. Tanabe K., Sumiyoshi T., Shibata K., Kiyoura T., and Kitagawa J. A new hypothesis regarding the surface acidity of binary metal oxides. Bull. Chem. Soc. Jpn. 47 (1974) 1064
17. Tanabe K., Itoh M., and Sato M. Chem. Commun. (1973) 676
18. Seiyama T. Metal Oxides and Their Catalytic Actions (1978), Kodansha, Toyko
19. Ko E.I., Chen J.P., and Weissman J.G. A Study of acidic titania/silica mixed oxides and their use as supports for nickel catalysts. J. Catal. 105 (1987) 511
20. Connell G., and Dumesic J.A. The generation of Brønsted and Lewis acid sites on the surface of silica by addition of dopant cations. J. Catal. 105 (1987) 285-298
21. Kataoka T., and Dumesic J.A. Acidity of unsupported and silica-supported vanadia, molybdena and titania as studied by pyridine adsorption. J. Catal. 112 (1988) 66
22. 2 catalysts and activity for acid catalysis. J. Catal. 132 (1991) 563
23. Liu Z., Tabora J., and Davis R.J. Relationship between microstructure and surface acidity of Ti-Si mixed oxide catalysts. J. Catal. 149 (1994) 117-126
24. Doolin P.K., Alerasool S., Zalewski D.J., and Hoffman J.F. Acidity studies of titania-silica mixed oxides. Catal. Lett. 25 (1994) 209-223
25. Miller J.B., Johnston S.T., and Ko E.I. Effect of prehydrolysis on the textural and catalytic properties of titania-silica aerogels. J. Catal. 150 2 (1994) 311
26. 2 mixed oxides and their relationship to catalyst activities for 1-butene isomerization. J. Catal. 157 (1995) 244
27. Gao X., and Wachs I.E. Titania-silica as catalysts: molecular structural characteristics and physico-chemical properties. Catal. Today 51 (1999) 233-254
28. Liu Z., and Davis R.J. Investigation of the structure of microporous Ti-Si mixed oxides by X-ray, UV reflectance, FT-Raman, and FT-IR spectroscopies. J. Phys. Chem. 98 4 (1994) 1253
29. West J., Haller G., and Burwell R.L. J. Catal. 29 (1973) 486
30. Hu S., Willey R., and Notari B. An investigation on the catalytic properties of titania-silica materials. J. Catal. 220 (2003) 240
31. Armaroli T., Milella F., Notari B., Willey R.J., and Busca G. A spectroscopic study of amorphous and crystalline Ti-containing silicas and their surface acidity. Top. Catal. 15 (2001) 63-71
32. Armaroli T., Bevilacqua M., Trombetta M., Milella F., Alejandre A.G., Ramirez J., Notari B., Willey R.J., and Busca G. A study of the external and internal sites of MFI-type zeolitic materials through the FT-IR investigation of the adsorption of nitriles. Appl. Catal. A 216 (2001) 59
33. Gorte R.J. Catal. Today 28 (1996) 405
34. Juskelis M.V., Slanga J.P., Roberie T.G., and Peters A.W. J. Catal. 138 (1992) 391
35. Gorte R.J. Catal. Lett. 62 (1999) 1
36. Nakabayashi H., Kakuta N., and Ueno A. Bull. Chem. Soc. Jpn. 64 (1991) 2428
37. Niwa M., Katada N., and Murakami Y. J. Catal. 70 (1981) 275
38. Xu M., Lunsford J.H., Goodman D.W., and Bhattacharyya A. Appl. Catal. A: Gen. 149 (1977) 289
39. Gervasini A., and Auroux A. J. Catal. 131 (1991) 190
40. Rekoske J.E., and Barteau M.A. J. Catal. 165 (1997) 57
41. Che M., Naccache C., Imelik R., and Prettre M. Comptes Rendus 264C (1967) 1901
42. 2 for the isomerization of butenes. J. Catal. 38 (1975) 172
43. Fernandez A., Leyrer J., Gonzalez-Felipe A.R., Munuera G., and Knozinger H. J. Catal. 112 (1988) 489
44. Haerudin H., Bertel S., and Kramer R. JCS Faraday Trans. 94 10 (1988) 1481