Dehydroxylation, proton migration, and structural changes in heated talc: An infrared spectroscopic study

American Mineralogist

Volumn 91, Issue 5-6, 2006, Pages 816-825

  Zhang, Ming ^a   Hui, Qun ^a   Lou, Xiao Jie ^a   Redfern, Simon A T ^a   Salje, Ekhard K H ^a   Tarantino, Serena C ^b  

^a UNIVERSITY OF CAMBRIDGE   (United Kingdom)

^b UNIVERSITY OF PAVIA   (Italy)

Author keywords

CO2; Dehydroxylation; Enstatite; Infrared spectroscopy; NH4; OD; OH; Talc

Indexed keywords

CARBON DIOXIDE; INFRARED SPECTROSCOPY; PHONONS; SILICA; SILICON; SPECTROSCOPIC ANALYSIS; TALC; TEMPERATURE DISTRIBUTION;

CHARACTERISTIC BANDS; COMPLEX PROCESSES; DEHYDROXYLATIONS; ENSTATITE; IN-SITU MEASUREMENT; INFRARED SPECTROSCOPIC STUDIES; RELATED SUBSTANCES; TEMPERATURE DEPENDENCE;

MAGNESIUM COMPOUNDS;

DEHYDROXYLATION; ENSTATITE; HIGH TEMPERATURE; INFRARED SPECTROSCOPY; MAGNESIUM; TALC;

EID: 33745493139     PISSN: 0003004X     EISSN: None     Source Type: Journal    
DOI: 10.2138/am.2006.1945     Document Type: Article

References (36)

1. Avgustinik, A.I. and Vigdergauz, V.S. (1948) Properties of talc during Heating. Ogneupory, 13, 218-227.
2. + in clay minerals by DTA and IR reflectance spectroscopy: a potential tool for for planetary surface exploration. Planetary and Space Science, 50, 11-19.
3. Boffa Ballaran, T., Carpenter, M.A., and Ross, N.L. (2001) Infrared powder-absorption spectroscopy of Ca-free P21/c clinopyroxenes. Mineralogical Magazine, 65, 339-350.
4. Bošković, S.B., Gašić, M.Č., Nikolić, V.S., and Ristić, M.M. (1968) The structural changes of talc during heating. Proceedings of the British Ceramic Society, 10, 1-12.
5. Bray, H.J. and Redfern, S.A.T. (1999) Kinetics of dehydration of Ca-montmorillonite. Physics and Chemistry of Minerals, 26, 591-600.
6. Busigny, V., Cartigny, P., Philippot, P., and Javoy, M. (2003) Ammonium quantification in muscovite by infrared spectroscopy. Chemical Geology, 198, 21-31.
7. Chihara, H., Koike, C., Tsuchiyama, A., Tachibana, S. and Sakamoto, D. (2002) Compositional dependence of infrared absorption spectra of crystalline silicates. Astronomy and Astrophysics, 391, 267-273.
8. Drits, V.A., Besson, G., and Muller, F. (1995) An improved model for structural transformations of heat-treated aluminous dioctahedral 2:1 layer silicates. Clays and Clay Minerals, 43, 718-731.
9. Farmer, V.C. (1974) The layer silicates. In V.C. Farmer, Ed., The Infrared Spectra of Minerals, p. 331-364. Mineralogical Society, London.
10. Farmer, V.C. and Russell, J.D. (1964) The infra-red spectra of layer silicates. Spectrochimica Acta, 20, 1149-1179.
11. Ferrage, E., Martin, F., Petit, S., Pejo-Soucaille, S., Micoud, P., Fourty, G., Ferret, J., Salvi, S., de Parseval, P. and Fortune, J.P. (2003) Evaluation of talc morphology using FTIR and H/D substitution. Clay Minerals, 38, 141-150.
12. 1H CRAMPS studies of the 2:1 phyllosilicate pyrophyllite. Journal of Physical Chemistry, 100, 17351-17360.
13. Guggenheim, S., Chang, Y.-H., and Koster van Groos, A.F. (1987) Muscovite dehydroxylation: High-temperature studies. American Mineralogist, 72, 537-550.
14. Ishii, M., Shimanouchi, T., and Nakahirea, M. (1967) Far infrared absorption spectra of layer silicates. Inorganica Chimica Acta, 1, 387-392.
15. Ishii, T., Furuichi, R., and Kobayashi, Y. (1974) Thermoanalytical study on the chlorination of magnesium-containing ores: An application of a simple gas-flow differential thermal analysis technique. Thermochimica Acta, 9, 39-53.
16. Krönert, W., Schwiete, H.E., and Suchow, A. (1964a) Das thermische Verhalten von Speckstein und die Stabilität der Magnesiummetasilikat-Modifikationen. Ziegelindustrie, 17, 364-369.
17. 3-Modifikationen. Naturwissenschaften, 51, 85-86.
18. 4-analcime. Physics and Chemistry in Minerals, 31, 306-312.
19. 29Si nuclear magnetic resonance spectroscopy. Journal of the American Ceramic Society, 68, 266-272.
20. Martin, F., Petit, S. Granby, O., and Lavie, M.P. (1999) Gradual H/D substitution in synthetic germanium bearing tales: a method for infrared band assignment. Clay Minerals, 34, 365-374.
21. Muller, F., Drits, V., Plancon, A., and Robert, J.L. (2000) Structural Transformation of 2:1 dioctahedral layer silicates during dehydroxylation-rehydroxylation reactions. Clays and Clay Minerals, 48, 572-585.
22. +-vermiculite from Santa Olalla (Huelva, Span) and its relation to the metal ion distribution in the octahedral sheet. Physics and Chemistry in Minerals, 31, 415-420.
23. Petit, S., Martin, F., Weiqiora, A., de Parseval, P. and Decarreau, A. (2004) Crystal-chemistry of talc: A near infrared (NIR) spectroscopy study. American Mineralogist, 89, 319-326.
24. + cations. Clay Minerals, 38, 201-211.
25. Robert J.-L., Volfinger, M., Barrandon, J.-N., and Basuteu M. (1983) Lithium in the interlayer space of synthetic trioctahedral micas. Chemical Geology, 40, 337-351.
26. Russell, J.D., Farmer, V.C. and Velde, B. (1970) Replacement of OH by OD in layer silicates and identification of the vibrations of these groups in infrared spectra. Mineralogical Magazine, 37, 869-879.
27. Sainz-Díaz, C.I., Escamilla-Roa, E., and Hernández-Laguna, A. (2004) Pyrophyllite dehydroxylation process by First Principle calculations. American Mineralogist, 89, 1092-1100.
28. Tarantino, S.C., Domeneghetti, M.C., Carpenter, M.A., Shaw, C.J.S., and Tazzoli, V. (2002a) Mixing properties of the enstatite-ferrositite solid solution: I. A macroscopic perspective. European Journal of Mineralogy, 14, 525-536.
29. Tarantino, S.C., Boffa Ballaran, T., Carpenter, M.A., Domeneghetti, M.C., and Tazzoli, V. (2002b) Mixing properties of the enstatite-ferrosilite solid solution: II A microscopic perspective. European Journal of Mineralogy, 14, 537-547.
30. Wang, L., Zhang, M., Redfern, S.A.T., and Zhang, Z.Y. (2002) Dehydroxylation and transformations ofthe 2:1 phyllosilicate pyrophyllite at elevated temperatures: An infrared spectroscopic study. Clays and Clay Minerals, 50, 272-283.
31. 2] during dehydroxylation. Clays and Clay Minerals, 51, 439-444.
32. Ward, J.R. (1975) Kinetics of talc dehydroxylation. Thermochimica Acta, 13, 7-14.
33. Wesolowski, M. (1984) Thermal decomposition of talc: a review. Thermochimica Acta, 78, 395-421.
34. Wilkins, R.W.T. and Ito, J. (1967) Infrared spectra of some synthetic talc. American Mineralogist, 52, 1649-1661.
35. Zhang, M., Wruck, B., Graeme-Barber, A., Salje, E.K.H., and Carpenter, M.A. (1996) Phonon spectra of alkali-fieldspars: phase transitions and solid solutions. American Mineralogist, 81, 92-104.
36. 2 incorporation in annealed mica (sericite): An infrared spectroscopic study. American Mineralogist, 90, 173-180.