Gradual H/D substitution in synthetic germanium bearing talcs: A method for infrared band assignment

Clay Minerals

Volumn 34, Issue 2, 1999, Pages 365-374

  Martin, F ^a,b,c,d   Petit, S ^a,b,c   Grauby, O ^a,b,c   Lavie, M P ^a,b,c  

^a UNIVERSITÉ DE TOULOUSE   (France)

^b Environmental Research Observatory (ORE) HYBAM Centre IRD d'Ile de France   (France)

^c CNRS   (France)

^d CAMPUS DE LUMINY   (France)

Author keywords

[No Author keywords available]

Indexed keywords

CLAY MINERALS; COBALT; DEUTERIUM; GERMANIUM; INFRARED SPECTROSCOPY; MAGNESIUM; NICKEL; SYNTHESIS (CHEMICAL);

DEUTERATION; HYDROTHERMAL SYNTHESIS;

TALC;

GERMANIUM; INFRARED SPECTROSCOPY; TALC;

EID: 0033400340     PISSN: 00098558     EISSN: None     Source Type: Journal    
DOI: 10.1180/000985599546154     Document Type: Article

References (20)

1. Decarreau A. (1983) Etude expérimentale de la cristallogénèse des smectites. Mesure des coefficients de partage smectite-solutions aqueuses pour les métaux M2<" de la première série de transition. Afein. Sei. Géol. 74, Strasbourg, France.
2. Decarreau A, Grauby O. & Petit S. (1992) The actual distribution of octahedral cations in 2:1 clay minerals: results from clay synthesis. Appl. Clay Sei. 7, 147-167.
3. Delia Ventura G., Robert J.-L., Bény J.M., Raudsepp M. & Hawthorne F.C. (1993) The OH-F substitution in Ti-rich potassium richterite: Rietveld structure refinement and FTIR and micro-Raman spectroscopic studies of synthetic amphiboles in the system K2O-Na2-CaO-MgO-SiO2-TiO2-H2O-HF. Am. Miner. 78, 980-987.
4. Farmer V.C. (1958) The infrared spectra of talc, saponite and hectorite. Mineral. Mag. 31, 829-845.
5. Farmer V.C. & Russell J.D. (1967) Infrared absorption spcctrometry in clay studies. Clays Clay Miner. 15, 121-142.
6. Farmer V.C., Russell J.D. & Ahlrichs J.L. (1968) Characterization of clay minerals by infrared spectroscopy. Trans. 9th Int. Congr. Soil. Sei. 3, 101-110.
7. Grauby O., Petit S., Enguehard F., Martin F. & Decarreau A. (1991) XRD, EXAFS and FTIR octahedral cation distribution in synthetic Ni-Co kerolites. Proc. 7th Euroclay Conf. Dresden, 2, 447-452.
8. Ishida K. (1990) Identification of infrared OH librational bands of talc-willemseite solid solutions and Al(lvr>frce amphiboles through dcuteration. Mineral. J. 15(3), 93-104.
9. Ishii M., Shimanouchi T. & Nakahira M. (1967) Far infrared absorption spectra of layer silicates. Inorg. Chim. Ada, 1, 387-392.
10. Langer K. & Lattard D. (1980) Identification of a low energy OH valence vibration in zoisite. Am. Miner. 50, 779-783.
11. Luth W.C. & Ingamells C.O. (1965) Gel preparation of starting materials for hydrothermal experimentation. Am. Miner. 50, 255-258.
12. Martin F., Ildefonse Ph., Hazemann J.L., Petit S., Grauby O. & Decarreau A. (1996) X-ray absorption fine structure and Fourier transform Infrared studies of the Ge-Si-solid solution in talcs. Eur. J. Miner. 8, 289-299.
13. Martin F., Petit S., Decarreau A., Grauby O., Hazemann J.L. & Noack Y. (1992) Experimental study of Si-Ge tetrahedral solid solution in Ni-Co-Mg talcs. Thin Solid Films, 222, 189-195.
14. Petit S., Robert J.-L., Dccarreau A., Besson G., Grauby O. & Martin F. (1995) Contribution of spectroscopic methods to 2:1 clay characterization. Bull. Centres Rech. Explor.-Prod. Elf Aquitaine, 19, 119-148.
15. Robert J.-L., Deny J.M., Delia Ventura G. & Hardy M. (1993) Fluorine in micas: crystal-chemical control of the OH-F distribution between trioctahedral and dioctahedral sites. Eur. J. Miner. 5, 7-18.
16. Roy D.M. & Roy R. (1955) Synthesis and stability of minerals in the system MgO-A-Oj-SiC HjO. Am. Miner. 40, 147-178.
17. Russell J.D., Farmer V.C. & Velde B. (1970) Replacement of OH by OD in layer silicates and identification of the vibrations of these groups in infrared spectra. Mineral. Mag. 37, 292, 869.
18. Shirozu H. & Ishida K. (1982) Infrared study of some 7 A and 14 A layer silicates by deuteration. Mineral. J. 11(4), 161-171.
19. Stubican V. & Roy R. (1961) A new approach to assignment of infrared absorption bands in layerstructure silicates. Zeils. Kristallogr. 115, 200-214.
20. Vedder W. (1964) Correlations between infrared spectrum and chemical compositions of micas. Am. Miner. 49, 736-767.