Regioselectivity in the 1,3-dipolar cycloaddition of adamantylidenefulvene and its modification by inclusion in cyclodextrins' solutions

Tetrahedron

Volumn 62, Issue 31, 2006, Pages 7380-7389

  Chu, Jean Ho ^a   Li, Wan Sheung ^b   Chao, Ito ^b   Lee, Gene Hsiang ^c   Chung, Wen Sheng ^c  

^a NATIONAL CHIAO TUNG UNIVERSITY   (Taiwan)

^b INSTITUTE OF CHEMISTRY   (Taiwan)

^c NATIONAL TAIWAN UNIVERSITY   (Taiwan)

Author keywords

1,3 Dipolar cycloaddition; Chiral shift reagent; Fulvene; Inclusion complex; Molecular reactor; Regioselectivity; Steric effect

Indexed keywords

3 (4 TERT BUTYLPHENYL) 4 METHYL 4,5 DIHYDROISOXAZOLE 5 CARBOXYLIC ACID METHYL ESTER; 3 (4 TERT BUTYLPHENYL) 5 METHYL 4,5 DIHYDROISOXAZOLE 4 CARBOXYLIC ACID METHYL ESTER; 4 ADAMANTAN 2 YLIDENE 3 (4 TERT BUTYLPHENYL) 4,6A DIHYDRO 3AH CYCLOPENTA[D]ISOXAZOLE; 4 ADAMANTAN 2 YLIDENE 3 (5 CHLOROTHIOPHEN 2 YL) 4,6A DIHYDRO 3AH CYCLOPENTA[D]ISOXAZOLE; 4 ADAMANTAN 2 YLIDENE 3 METHYL 4,6A DIHYDRO 3AH CYCLOPENTA[D]ISOXAZOLE; 4 ADAMANTAN 2 YLIDENE 3 PHENYL 3A,6A DIHYDRO 3AH CYCLOPENTA[D]ISOXAZOLE; 4 TERT BUTYLPHENYLHYDROXIMINOYL CHLORIDE; 6 ADAMANTAN 2 YLIDENE 3 (4 TERT BUTYLPHENYL) 6,6A DIHYDRO 3AH CYCLOPENTA[D]ISOXAZOLE; 6 ADAMANTAN 2 YLIDENE 3 (5 CHLOROTHIOPHEN 2 YL) 6,6A DIHYDRO 3AH CYCLOPENTA[D]ISOXAZOLE; 6 ADAMANTAN 2 YLIDENE 3 METHYL 6,6A DIHYDRO 3AH CYCLOPENTA[D]ISOXAZOLE; 6 ADAMANTAN 2 YLIDENE 3 PHENYL 3A,6A DIHYDRO 3AH CYCLOPENTA[D]ISOXAZOLE; 7 ADAMANTAN 2 YLIDENE 3,4 BIS(4 TERT BUTYLPHENYL) 3B,6A,7,7A TETRAHYDRO 3AH CYCLOPENTA[2,1 D:3,4 D']DIISOXAZOLE; 7 ADAMANTAN 2 YLIDENE 3,4 DIPHENYL 3A,3B,6A,7A TETRAHYDRO 3AH CYCLOPENTA[2,1 D:3,4 D']DIISOXAZOLE; 7 ADAMANTAN 2 YLIDENE 3,6 BIS(4 TERT BUTYLPHENYL) 3B,6A,7,7A TETRAHYDRO 3AH CYCLOPENTA[1,2 D:3,4 D']DIISOXAZOLE; 7 ADAMANTAN 2 YLIDENE 3,6 DIPHENYL 3A,3B,6A,7A TETRAHYDRO 3AH CYCLOPENTA[2,1 D:3,4 D']DIISOXAZOLE; [3 (4 TERT BUTYLPHENYL) 4 PHENYL 4,5 DIHYDROISOXAZOL 5 YL]PHENYLMETHANONE; [3 (4 TERT BUTYLPHENYL) 5 PHENYL 4,5 DIHYDROISOXAZOL 4 YL]PHENYLMETHANONE; ACETONE; ADAMANTANE DERIVATIVE; ADAMANTYLIDENEFULVENE; BETA CYCLODEXTRIN; CYCLODEXTRIN; NITRILE OXIDE; REAGENT; UNCLASSIFIED DRUG;

AQUEOUS SOLUTION; ARTICLE; BINDING AFFINITY; CHEMICAL MODIFICATION; CYCLOADDITION; ELECTRICITY; ENANTIOMER; MICROWAVE RADIATION; MOLECULAR DYNAMICS; PRIORITY JOURNAL; PROTON NUCLEAR MAGNETIC RESONANCE; STEREOCHEMISTRY; TITRIMETRY;

EID: 33745208235     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tet.2006.05.021     Document Type: Article

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