Synthesis of peroxynitrite using isoamyl nitrite and hydrogen peroxide in a homogeneous solvent system

Analytical Biochemistry

Volumn 354, Issue 2, 2006, Pages 165-168

  Uppu, Rao M ^a  

^a SOUTHERN UNIVERSITY   (United States)

Author keywords

Alkyl nitrites; Homogeneous solvent system; Hydrogen peroxide; Oxidation, nitration and nitrosation; Synthesis of peroxynitrite

Indexed keywords

HYDROGEN PEROXIDE; MANGANESE OXIDE; OXIDATION; PEROXIDES; SOLVENT EXTRACTION;

ALKYL NITRITES; CATALYTIC DECOMPOSITION; ISOAMYL ALCOHOL; ISOPROPYL ALCOHOLS; LARGE SCALE SYNTHESIS; NITROSATION; PEROXYNITRITES; SOLVENT SYSTEM;

SOLVENTS;

2 PROPANOL; ALKALI; AMYL NITRITE; BUTYL NITRITE; HYDROGEN PEROXIDE; MANGANESE DIOXIDE; PEROXYNITRITE; SOLVENT; WATER;

ADDITION REACTION; ARTICLE; BIOCHEMISTRY; CATALYSIS; CHEMICAL REACTION; CHEMISTRY; CONCENTRATION (PARAMETERS); DECOMPOSITION; INCUBATION TIME; NITROSATION; PH MEASUREMENT; PRIORITY JOURNAL; SOLVENT EXTRACTION; SYNTHESIS;

EID: 33745203244     PISSN: 00032697     EISSN: 10960309     Source Type: Journal    
DOI: 10.1016/j.ab.2005.11.003     Document Type: Article

References (17)

1. Beckman J.S., Beckman T.W., Chen J., Marshall P.A., and Freeman B.A. Apparent hydroxyl radical production by peroxynitrite: implications for endothelial injury from nitric oxide and superoxide. Proc. Natl. Acad. Sci. USA 87 (1990) 1620-1624
2. Huie R.E., and Padmaja S. The reaction of NO with superoxide. Free Radic. Res. Commun. 18 (1993) 195-199
3. Doyle M.P., and Hoekstra J.W. Oxidation of nitrogen oxides by bound dioxygen in hemoproteins. J. Inorg. Biochem. 14 (1981) 351-358
4. {radical dot}NO-mediated oxidation of oxymyoglobin and oxyhemoglobin. Biochemistry 40 (2001) 3385-3395
5. Beckman J.S., Chen J., Ischiropoulos H., and Crow J.P. Oxidative chemistry of peroxynitrite. Methods Enzymol. 233 (1994) 229-240
6. -, and its characterization as a tetramethylammonium. J. Am. Chem. Soc. 116 (1994) 7423
7. Koppenol W.H., Kissner R., and Beckman J.S. Synthesis of peroxynitrite: to go with the flow or on solid grounds?. Methods Enzymol. 269 (1996) 296-302
8. Uppu R.M., Squadrito G.L., Cueto R., and Pryor W.A. Selecting the most appropriate synthesis of peroxynitrite. Methods Enzymol. 269 (1996) 285-296
9. Uppu R.M., and Pryor W.A. Synthesis of peroxynitrite in a two-phase system using isoamyl nitrite and hydrogen peroxide. Anal. Biochem. 236 (1996) 242-249
10. Bergmeyer H.U., Grassl M., and Walter H.-E. Biochemical reagents for general use. In: Bergmeyer H.U. (Ed). Methods of Enzymatic Analysis. 3rd ed. vol. 2 (1983), Verlag-Chemie, Weinheim, Germany 126-328
11. Hughes M.N., and Nicklin H.G. The chemistry of pernitrites: I. Kinetics and decomposition of pernitrous acid. J. Chem. Soc. A (1968) 450-452
12. Uppu R.M., Winston G.W., and Pryor W.A. Reactions of peroxynitrite with aldehydes as probes for the reactive intermediates responsible for biological nitration. Chem. Res. Toxicol. 10 (1997) 1331-1337
13. Squadrito G.L., Cueto R., Splenser A.E., Valvanidis A., Zhang H., Uppu R.M., and Pryor W.A. Reaction of uric acid with peroxynitrite and implications for the mechanism of neuroprotection by uric acid. Arch. Biochem. Biophys. 376 (2000) 333-337
14. Leis J.R., Pena M.E., and Rios A.A. Novel route to peroxynitrite anion. J. Chem. Soc. Chem. Commun. 16 (1993) 1298-1299
15. Uppu R.M., Squadrito G.L., Cueto R., and Pryor W.A. Synthesis of peroxynitrite by azide-ozone reaction. Methods Enzymol. 269 (1996) 311-321
16. S.A. Madison, J.E.B. McCallum, R.U. Rojas Wahl, Peroxynitrite based bleaching systems, U.S. patent 5,914,305, 1999.
17. 2 and evidence for common intermediates. J. Am. Chem. Soc. 122 (2000) 6911-6916