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34
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0011083499
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According to second-order pertubation theory analyses of Fock matrices in NBO bases, the largest energetic contributions arise from spin to σ* C-X donations, according to a description of negative hyperconjugation: NBO(3.1)-Analysis: a) A. E. Reed, L. A. Curtiss, F. Weinhold, Chem. Rev. 1988, 55, 899;
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33745116731
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note
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-3 M. The transient absorption spectrum was obtained 400 ns after the 355 nm laser flash.
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