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Volumn 12, Issue 17, 2006, Pages 4662-4667

α-Carbonyl substituent effect on the lifetimes of triplet 1,4-biradicals from norrish-type-II reactions

Author keywords

Hyperconjugation; Laser spectroscopy; Photochemistry; Radicals

Indexed keywords

HYDROGEN; LASER BEAM EFFECTS; PHOTOLYSIS; REACTION KINETICS; SPECTROSCOPIC ANALYSIS;

EID: 33745132750     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200600011     Document Type: Article
Times cited : (19)

References (39)
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    • 34247244934 scopus 로고    scopus 로고
    • (Eds.: A. G. Cries-beck, J. Mattay), Dekker, New York
    • P. J. Wagner, Synthetic Organic Photochemistry (Eds.: A. G. Cries-beck, J. Mattay), Dekker, New York, 2005, p. 11.
    • (2005) Synthetic Organic Photochemistry , pp. 11
    • Wagner, P.J.1
  • 31
    • 33745145286 scopus 로고    scopus 로고
    • note
    • w = 0.0816, residual electron density: 0.224/ -0.327.
  • 34
    • 0011083499 scopus 로고
    • According to second-order pertubation theory analyses of Fock matrices in NBO bases, the largest energetic contributions arise from spin to σ* C-X donations, according to a description of negative hyperconjugation: NBO(3.1)-Analysis: a) A. E. Reed, L. A. Curtiss, F. Weinhold, Chem. Rev. 1988, 55, 899;
    • (1988) Chem. Rev. , vol.55 , pp. 899
    • Reed, A.E.1    Curtiss, L.A.2    Weinhold, F.3
  • 39
    • 33745116731 scopus 로고    scopus 로고
    • note
    • -3 M. The transient absorption spectrum was obtained 400 ns after the 355 nm laser flash.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.