EPR spectroscopic and computational characterization of the hydroxyethylidene-thiamine pyrophosphate radical intermediate of pyruvate:ferredoxin oxidoreductase

Biochemistry

Volumn 45, Issue 23, 2006, Pages 7122-7131

  Mansoorabadi, Steven O ^a   Seravalli, Javier ^b   Furdui, Cristina ^b,e   Krymov, Vladimir ^c   Gerfen, Gary J ^c   Begley, Tadhg P ^d   Melnick, Jonathan ^d   Ragsdale, Stephen W ^b   Reed, George H ^a  

^a UNIVERSITY OF WISCONSIN MADISON   (United States)

^b UNIVERSITY OF NEBRASKA LINCOLN   (United States)

^c ALBERT EINSTEIN COLLEGE OF MEDICINE   (United States)

^d Cornell University ^*  (United States)

^e YALE UNIVERSITY SCHOOL OF MEDICINE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

COMPUTER SIMULATION; ELECTRON SPIN RESONANCE SPECTROSCOPY; ELECTRONIC STRUCTURE; ENZYMES; HYDROGEN BONDS; MICROWAVES; NATURAL FREQUENCIES;

HYDROXYETHYLIDENE-THIAMINE PYROPHOSPHATE; HYPERFINE SPLITTING; MOORELLA THERMOACETICA; THIAMINE PYROPHOSPHATE (TPP);

NUCLEIC ACIDS;

CARBON 13; CATION; HYDROGEN; HYDROXYETHYLIDENE THIAMINE PYROPHOSPHATE; PYROPHOSPHATE; PYRUVATE SYNTHASE; PYRUVIC ACID; UNCLASSIFIED DRUG;

ARTICLE; CATION TRANSPORT; COMPUTER PREDICTION; ELECTRON SPIN RESONANCE; ENZYME ANALYSIS; ENZYME SUBSTRATE; HYDROGEN BOND; ISOTOPE LABELING; MICROWAVE RADIATION; MOORELLA THERMOACETICA; NONHUMAN; PRIORITY JOURNAL; SIMULATION; STRUCTURE ANALYSIS;

ELECTRON SPIN RESONANCE SPECTROSCOPY; MODELS, MOLECULAR; PYRUVATE SYNTHASE; THIAMINE PYROPHOSPHATE;

MOORELLA THERMOACETICA;

EID: 33745025223     PISSN: 00062960     EISSN: None     Source Type: Journal    
DOI: 10.1021/bi0602516     Document Type: Article

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