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Volumn 4, Issue 9, 2006, Pages 1650-1652

A facile and chemoselective conjugate reduction using polymethylhydrosiloxane (PMHS) and catalytic B(C6F5) 3

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSTS; ESTERS; KETONES; NITROGEN COMPOUNDS; REACTION KINETICS;

EID: 33744831770     PISSN: 14770520     EISSN: None     Source Type: Journal    
DOI: 10.1039/b603610b     Document Type: Article
Times cited : (35)

References (68)
  • 64
    • 84921681438 scopus 로고    scopus 로고
    • Electronic Encyclopedia of Organic Reagents for Organic Synthesis
    • ' Electronic Encyclopedia of Organic Reagents for Organic Synthesis ', S. Chandrasekhar, B. N. Babu and G. Chandrashekar, eEROS, 2005, and references therein
    • (2005) EEROS
    • Chandrasekhar, S.1    Babu, B.N.2    Chandrashekar, G.3
  • 65
    • 0037073839 scopus 로고    scopus 로고
    • 3 (5 mg, 0.01 mmol) and PMHS (4 mmol), and the solution was stirred at room temperature for the appropriate time (monitored by TLC). Water was added to the reaction mixture, which was then extracted with methylene chloride (3 × 5 mL). The combined organic layers were washed with brine, dried over anhydrous sodium sulfate, concentrated in vacuo, and the crude product purified by flash chromatography For a few earlier chiral asymmetric conjugate reductions, see:
    • S. Chandrasekhar C. R. Reddy B. N. Babu J. Org. Chem. 2002 67 9080
    • (2002) J. Org. Chem. , vol.67 , pp. 9080
    • Chandrasekhar, S.1    Reddy, C.R.2    Babu, B.N.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.