Kinetic and microscopic studies of reductive transformations of organic contaminants on goethite

Environmental Science and Technology

Volumn 40, Issue 10, 2006, Pages 3299-3304

  Chun, Chan Lan ^a   Penn, R Lee ^b   Arnold, William A ^a  

^a UNIVERSITY OF MINNESOTA   (United States)

^b University of Minnesota   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

DEGRADATION; IMPURITIES; IRON; MORPHOLOGY; TRANSMISSION ELECTRON MICROSCOPY; X RAY DIFFRACTION ANALYSIS;

GOETHITE GROWTH; IRON MINERAL SURFACES; PSEUDO-FIRST-ORDER REACTIONS; TRICHLORONITROMETHANE;

ORGANIC COMPOUNDS;

1 CHLORO 4 NITROBENZENE; CHLOROPICRIN; FERRIC HYDROXIDE; IRON DERIVATIVE; IRON OXIDE; MINERAL WATER; ORGANIC COMPOUND;

DEGRADATION; IMPURITIES; IRON; MORPHOLOGY; ORGANIC COMPOUNDS; TRANSMISSION ELECTRON MICROSCOPY; X RAY DIFFRACTION ANALYSIS;

DEGRADATION; GOETHITE; IRON; POLLUTANT;

AQUEOUS SOLUTION; ARTICLE; CHEMICAL MODIFICATION; DEGRADATION; KINETICS; PARTICLE SIZE; QUANTITATIVE ANALYSIS; REDUCTION; SURFACE PROPERTY; TRANSMISSION ELECTRON MICROSCOPY; X RAY DIFFRACTION;

FERROUS COMPOUNDS; HYDROCARBONS, CHLORINATED; IRON COMPOUNDS; KINETICS; MICROSCOPY, ELECTRON, TRANSMISSION; MINERALS; NITROBENZENES; ORGANIC CHEMICALS; PARTICLE SIZE; SOIL POLLUTANTS; WATER; WATER POLLUTANTS; X-RAY DIFFRACTION;

EID: 33646751915     PISSN: 0013936X     EISSN: None     Source Type: Journal    
DOI: 10.1021/es0600983     Document Type: Article

References (35)

1. Klausen, J.; Troeber, S. P.; Haderlein, S. B.; Schwarzenbach, R. P. Reduction of substituted nitrobenzenes by Fe(II) in aqueous mineral suspensions. Environ. Sci. Technol. 1995, 29, 2396-2404.
2. IIOH° species, as major reductant. Chem. Geol. 1998, 151, 85-93.
3. Amonette, J. E.; Workman, D. J.; Kennedy, D. W.; Fruchter, J. S.; Gorby, Y. A. Dechlorination of carbon tetrachloride by Fe(II) associated with goethite. Environ. Sci. Technol. 2000, 34, 4606-4613.
4. Pecher, K.; Haderlein, S. B.; Schwarzenbach, R. P. Reduction of polyhalogenated methanes by surface-bound Fe(II) in aqueous suspensions of iron oxides. Environ. Sci. Technol. 2002, 36, 1734-1741.
5. II and oxime carbamate pesticides. Geochim. Cosmochim. Acta 2003, 67, 2775-2791.
6. Elsner, M.; Schwarzenbach, R. P.; Haderlein, S. B. Reactivity of Fe(II)-bearing minerals toward reductive transformation of organic contaminants. Environ. Sci. Technol. 2004, 38, 799-807.
7. Klupinski, T. P.; Chin, Y.-P.; Traina, S. J. Abiotic degradation of pentachloronitrobenzene by Fe(II): Reactions on goethite and iron oxide nanoparticles. Environ. Sci. Technol. 2004, 38, 4353-4360.
8. Chun, C. L.; Hozalski, R. M.; Arnold, W. A. Degradation of drinking water disinfection byproducts by synthetic goethite and magnetite. Environ. Sci. Technol. 2005, 39, 8525-8532.
9. Cui, D.; Friksen, T. E. Reduction of pertechnetate by ferrous iron in solution: Influence of sorbed and precipitated Fe(II). Environ. Sci. Technol. 1996, 30, 2259-2262.
10. Buerge, I. J.; Hug, S. J. Influence of mineral surfaces on chromium (VI) reduction by iron(II). Environ. Sci. Technol. 1999, 33, 4285-4291.
11. Liger, E.; Charlet, L.; Van Cappellen, P. Surface catalysis of uranium (VI) reduction by iron(II). Geochim. Cosmochim. Acta 1999, 63, 2939-2955.
12. Vikesland, P. J.; Valentine, R. L. Iron oxide surface-catalyzed oxidation of ferrous iron by monochloramine: Implications of oxide type and carbonate on reactivity. Environ. Sci. Technol. 2002, 36, 512-519.
13. Wang, S.; Arnold, W. A. Abiotic reduction of dinitroaniline herbicides. Water Res. 2003, 37, 4191-4201.
14. Klupinski, T. P.; Chin, Y.-P. Abiotic degradation of trifluralin by Fe(II): kinetics and transformation pathways. Environ. Sci. Technol. 2003, 37, 1311-1318.
15. Jeon, B. H.; Dempsey, B. A.; Burgos, W. D.; Royer, R. A. Reactions of ferrous iron with hematite. Colloids Surf., A 2001, 191, 41-55.
16. Jeon, B.-H.; Dempsey, B. A.; Burgos, W. D. Kinetics and mechanisms for reactions of Fe(II) with iron(III) oxides. Environ. Sci. Technol. 2003, 37, 3309-3315.
17. Williams, A. G. B.; Scherer, M. M. Spectroscopic evidence for Fe(II)-Fe(III) electron transfer at the iron oxide-water interface. Environ. Sci. Technol. 2004, 38, 4782-4790.
18. Lee, W.; Batchelor, B. Abiotic reductive dechlorination of chlorinated ethylenes by iron-bearing soil minerals. 1. Pyrite and magnetite. Environ. Sci. Technol. 2002, 36, 5147-5154.
19. Lee, W.; Batchelor, B. Abiotic reductive dechlorination of chlorinated ethylenes by iron-bearing soil minerals. 2. Green rust. Envrion. Sci. Technol. 2002, 36, 5348-5354.
20. Junta, J. L.; Hochella, M. F., Jr. Manganese(II) oxidation at mineral surfaces: a microscopic and spectroscopic study. Geochim. Cosmochim. Acta 1994, 58, 4985-4999.
21. Junta-Rosso, J. L.; Hochella, M. F., Jr.; Rimstidt, J. D. Linking microscopic and macroscopic data for heterogeneous reactions illustrated by the oxidation of manganese(II) at mineral surfaces. Geochim. Cosmochim. Acta 1997, 61, 149-159.
22. Jun, Y.-S.; Martin, S. T. Microscopic observations of reductive manganite dissolution under oxic conditions. Environ. Sd. Technol. 2003, 37, 2363-2370.
23. Weidler, P. G.; Hug, S. J.; Welche, T. P.; Hiemstra, T. Determination of growth rates of (100) and (110) faces of synthetic goethite by scanning force microscopy. Geochim. Cosmochim. Acta 1998, 62, 3407-3412.
24. Charlet, L.; Bosbach, D.; Peretyashko, T. Natural attenuation of TCE, As, Hg linked to the heterogeneous oxidation of Fe(II): An AFM study. Chem. Geol. 2002, 190, 303-319.
25. Anschutz, A. J.; Penn, R. L. Reduction of crystalline iron(III) oxyhydroxides using hydroquinone: Influence of phase and particle size. Geochem. Trans. 2005, 6, 60-66.
26. Lin, J.; Rester, D. R. The kinetics of iron(II) complexation by Ferrozine in seawater. Mar. Chem. 1992, 38, 283-301.
27. Gustafsson, J. P. Visual MINTEQ, version 2.30; KTH Department of Land and Water Resource Engineering: Stockholm, Sweden, 2004.
28. Burleson, D. J.; Penn, R. L. Two-step growth of goethite from ferrihydrite. Langmuir 2006, 22, 402-409.
29. Barron, V.; Torrent, J. Surface hydroxyl configuration of various crystal faces of hematite and goethite. J. Colloid Interface Sci. 1996, 177, 407-410.
30. Cornell, R. M.; Schwertmann, U. The Iron Oxides-Structure, Properties, Reactions, Occurrence and Uses; VCH: New York, 1996.
31. Weidler, P. G.; Schwinn, T.; Gaub, H. E. Vicinal faces on synthetic goethite observed by atomic force microscopy. Clays Clay Miner. 1996, 44, 437-442.
32. Gaboriaud, F.; Ehrhardt, J.-J. Effects of different crystal faces on the surface charge of colloidal goethite (α-FeOOH) particles: An experimental and modeling study. Geochim. Cosmochim. Acta 2003, 67, 967-983.
33. 2, and S(-II) in porewaters of marine and freshwater sediments. Environ. Sci. Technol. 1995, 29, 751-761.
34. Penn, R. L.; Zhu, C.; Xu, H.; Veblen, D. R. Iron oxide coatings on sand grains from the Atlantic Coastal Plain: High-resolution transmission electron microscopy characterization. Geology 2001, 29, 843-846.
35. Van der Zee, C.; Roberts, D. R.; Rancourt, D. G.; Slomp, C. P. Nanogoethite is the dominant reactive oxyhydroxide phase in lake and marine sediments. Geology 2003, 31 (11), 993-996.