Linking microscopic and macroscopic data for heterogeneous reactions illustrated by the oxidation of manganese (II) at mineral surfaces

Geochimica et Cosmochimica Acta

Volumn 61, Issue 1, 1997, Pages 149-159

  Junta Rosso, Jodi L ^a   Hochella Jr , Michael F ^a   Rimstidt, J Donald ^a  

^a VIRGINIA POLYTECHNIC INSTITUTE AND STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALBITE; HAEMATITE; MANGANESE; MINERAL SURFACE; OXIDATION;

EID: 0030834147     PISSN: 00167037     EISSN: None     Source Type: Journal    
DOI: 10.1016/s0016-7037(96)00329-8     Document Type: Article

References (20)

1. Brown G. E., Jr. (1990) Spectroscopic studies of chemisorption reaction mechanisms at oxide-water interfaces. In Mineral-Water Interface Geochemistry (ed. M. F. Hochella Jr. and A. F. White); Rev. Mineral. 23, 309-364. MSA.
2. Brown G. E., Jr., Parks G. A., and O'Day P. A. (1994) Sorption at the mineral-water interface: Macroscopic and microscopic prospective. In Mineral Surfaces (ed. D. J. Vaughn and R. A. D. Pattrick); Mineral. Soc. Ser. 5, 129-183. Chapman & Hall.
3. Chao T. T. and Theobald P. K., Jr. (1976) The significance of secondary iron and manganese oxides in geochemical exploration. Econ. Geol. 71, 1560-1569.
4. Cheronov A. A. and Nishinaga T. (1987) Growth shapes and their stability at anisotropic interface kinetics: Theoretical aspects for solution growth. In Morphology of Crystals (ed. I. Sunagawa), pp. 211-267. Terra Sci. Publ. Co.
5. Coughlin R. W. and Matsui I. (1976) Catalytic oxidation of aqueous Mn(II). J. Catalysis 41, 108-123.
6. Davies S. H. R. and Morgan J. J. (1989) Manganese (II) oxidation kinetics on metal oxide surfaces. J. Colloid Interface Sci. 129, 63-77.
7. 2 in absence of Mn-bacteria or surface catalysts? Geochim. Cosmochim. Acta 48, 1571-1573.
8. Hem J. D. (1963) Increased oxidation rate of manganese ions in contact with feldspar grains. USGS Prof. Paper 475-C, C216-C217.
9. Hochella M. F., Jr. (1994) Mineral surfaces: Their characterization and their chemical, physical, and reactive nature. In Mineral Surfaces (ed. D. J. Vaughn and R. A. D. Pattrick); Mineral. Soc. Ser. 5, 17-60. Chapman & Hall.
10. Jenne E. A. (1968) Controls on Mn, Fe, Co, Ni, Cu, and Zn concentrations in soils and water: The significant role of hydrous Mn and Fe oxides. In Trace Inorganics in Water (ed. R. A. Baker); Adv. Chem. Ser. 73, 337-387. ACS.
11. Junta J. L. and Hochella M. F., Jr. (1994) Manganese (II) oxidation at mineral surfaces: A microscopic and spectroscopic study. Geochim. Cosmochim. Acta 58, 4985-4999.
12. Junta-Rosso J. L. (1995) Precipitation at the Mineral-Water Interface: Linking Microscopic to Macroscopic Processes. Ph.D. dissertation, Stanford Univ.
13. Matsui I. (1973) Catalysis and kinetics of manganous ion oxidation in aqueous solution and adsorbed on the surfaces of solid oxides. Ph.D. dissertation, Lehigh Univ.
14. Moore J. N., Ficklin W. H., and Johns C. (1988) Partitioning of arsenic and metals in reducing sulfidic sediments. Environ. Sci. Tech. 22, 432-437.
15. Morgan J. J. (1967) Chemical equilibria and kinetic properties of manganese in natural waters. In Principles and Applications of Water Chemistry (ed. S. Faust and J. Hunter), pp. 561-624. Wiley.
16. Rimstidt J. D. and Newcomb W. D. (1993) Measurement and analysis of rate data: The rate of reaction of ferric iron with pyrite. Geochim. Cosmochim. Acta 57, 1919-1934.
17. Sposito G. (1986) Distinguishing adsorption from surface precipitation. In Geochemical Processes at Mineral Surfaces (ed. J. A. Davis and K. F. Hayes); ACS Symp. Ser. 323, 217-228. ACS.
18. Sung W. and Morgan J. J. (1981) Oxidative removal of Mn(II) from solution catalyzed by the γ-FeOOH (lepidocrocite) surface. Geochim. Cosmochim. Acta 45, 2377-2383.
19. Westall J. and Hohl H. (1980) A comparison of electrostatic models for the oxide/solution interface. Advances Colloid Interface Sci. 12, 265-294.
20. Wilson D. E. (1980) Surface and complexation effects on the rate of Mn(II) oxidation in natural waters. Geochim. Cosmochim. Acta 44, 1311-1317.