Municipal sludge-industrial sludge composite desulfurization adsorbents: Synergy enhancing the catalytic properties

Environmental Science and Technology

Volumn 40, Issue 10, 2006, Pages 3378-3383

  Bandosz, Teresa J ^a   Block, Karin ^b  

^a CITY COLLEGE OF NEW YORK   (United States)

^b CITY UNIVERSITY OF NEW YORK   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

DESULFURIZATION; HYDROGEN SULFIDE; OXIDATION; PH EFFECTS; PYROLYSIS; THERMOANALYSIS; WASTES; X RAY DIFFRACTION ANALYSIS;

BREAKTHROUGH CAPACITY; CATALYTIC CENTERS; METAL OIL SLUDGE; REACTIVE ADSORPTION;

SEWAGE SLUDGE;

CARBON; HYDROGEN SULFIDE; NITROGEN; SULFUR; SULFURIC ACID;

DESULFURIZATION; HYDROGEN SULFIDE; OXIDATION; PH EFFECTS; PYROLYSIS; SEWAGE SLUDGE; THERMOANALYSIS; WASTES; X RAY DIFFRACTION ANALYSIS;

ADSORPTION; INDUSTRIAL WASTE; MUNICIPAL SOLID WASTE; NITROGEN; SULFUR;

ADSORPTION; ARTICLE; CATALYSIS; DESULFURIZATION; DISSOCIATION; INDUSTRIAL SLUDGE; MUNICIPAL SOLID WASTE; OXIDATION; PH MEASUREMENT; PYROLYSIS; SEWAGE TREATMENT; THERMAL ANALYSIS;

ADSORPTION; CARBON; CATALYSIS; CITIES; ENVIRONMENTAL POLLUTION; HYDROGEN SULFIDE; HYDROGEN-ION CONCENTRATION; INCINERATION; INDUSTRIAL WASTE; NITROGEN; OXIDATION-REDUCTION; SEWAGE; SPECTROMETRY, X-RAY EMISSION; SULFUR;

EID: 33646739738     PISSN: 0013936X     EISSN: None     Source Type: Journal    
DOI: 10.1021/es052272d     Document Type: Article

References (38)

1. Manahan, S. E. Environmental Chemistry, 6th ed.; CRC Press: Boca Raton, FL, 1994.
2. U.S. EPA. Biosolids Regeneration, Use, and Disposal in the United States; EPA530-R-99-009; U.S. EPA: Washington, DC, September 1999; www.epa.gov.
3. Lundin, M.; Olofsson, M.; Pettersson, G. J.; Zetterlund, H. Environmental and economic assessment of sewage sludge handing options. Resour., Conserv. Recycl. 2004, 41, 255-278.
4. Fullana, A.; Conesa, J. A.; Font, R.; Martin-Gullon, I. Pyrolysis of sewage sludge: nitrogenated compounds and pretreatment options. J. Anal. Appl. Pyrolysis 2003, 68-69, 561-575.
5. Wang, K. S.; Tseng, Ch-J.; Chiou, I.-J.; Shih, M.-H. The thermal conductivity mechanism of sewage sludge ash lightweight materials. Cem. Concr. Res. 2005, 35, 803-809.
6. Piskorz, J.; Scott, D. S.; Westerberg, I. B. Flash pyrolysis of sewage sludge. IEC Process Des. Dev. 1996, 25, 265.
7. Chiang, P. C.; You, J. H. Use of sewage sludge for manufacturing adsorbents. Can. J. Chem. Eng. 1987, 65, 922.
8. Lewis, F. M. Method of pyrolyzing sewage sludge to produce activated carbon. U.S. Patent 4,122,036, 1977.
9. Sutherland, J. Preparation of activated carbonaceous material from sewage sludge and sulfuric acid. U.S. Patent 3,998,757, 1976.
10. Nickerson, R. D.; Messman, H. C. Making activated carbon from sewage sludge. U.S. Patent 3,887,461, 1975.
11. Abe, H.; Kondoh, T.; Fukuda, H.; Takahashi, M.; Aoyama, T.; Miyake, M. Active carbon materials, process for the preparation thereof and the use thereof. U.S. Patent 5,338,462, 1994.
12. Khalili, N. R.; Arastoopour, H.; Walhof, L. K. Synthesizing Carbon from sludge. U.S. Patent 6,030,922, 2000.
13. Lu, G. Q.; Low J. C. F.; Liu, C. Y.; Lau, A. C. Surface area development of sewage sludge during pyrolysis. Fuel 1995, 74, 3444.
14. 2S Adsorption/Oxidation on Adsorbents Obtained from Pyrolysis of Sewage Sludge-Derived Fertilizer Using Zinc Chloride Activation. Ind. Eng. Chem Res. 2001, 40, 3502-3510.
15. Martin, M. J.; Serra, E.; Ros, A.; Balaguer, M. D.; Rigola, M. Carbonaceous Adsorbents from Sewage Sludge and their Application in a Combined Activated Sludge-powered Activated Carbon (AS-PAC) Treatment. Carbon 2004, 42, 1389-1394.
16. Bagreev, A.; Bandosz, T. J. Locke, D. C. Pore Structure and Surface Chemistry of Adsorbents Obtained by Pyrolysis of Sewage Sludge-Derived Fertilizer. Carbon 2001, 39, 1971.
17. 2S Adsorption/Oxidation on Materials Obtained using Sulfuric Acid Activation of Sewage Sludge Derived Fertilizer. J. Colloid Interface Sci. 2002, 252, 188-194.
18. Bagreev, A.; Bashkova, S.; Locke, D. C.; Bandosz, T. J. Sewage Sludge Derived Materials as Efficient Adsorbents for Removal of Hydrogen Sulfide. Environ. Sci. Technol. 2001, 35, 1537.
19. 2. In Fundamentals of Adsorption-7; Kaneko, K., Kanoh, H., Hanzawa, Y., Eds.; IK International: Chiba, Japan, 2002; pp 239-246.
20. Bagreev, A.; Bashkova, S.; Reznik, B.; Zibat, V.; Bandosz, T. J. Heterogeneity of Sewage Sludge Derived Materials as a Factor Governing their Performance as Adsorbents Of Acidic Gases. In Proceedings of Conference on Characterization of Porous Solids - 6 (Studies in Surface Science and Catalysis 144); Rodriguez-Reinoso, F., et al., Ed.; Elsevier: Amsterdam, 2003; pp 217-224.
21. Zang, F. S.; Toh, H. Adsorption of mercury on adsorbents obtained from sewage sludge. J. Hazard. Mater. B 2003, 101, 323.
22. 2-modified sewage sludge carbon. J. Phtotochem. Photobiol. A: Chem. 2004, 167, 223-228.
23. Rio, S.; Faur-Brasquet, C.; Le Coq, L.; Courcoux, P.; Le Cloirec, P. Experimental design methodology for the preparation of carbonaceous sorbents from sewage sludge by chemical activation - application to air and water treatments. Chemosphere 2005, 58, 423-437.
24. Rio, S.; Faur-Brasquet, C.; Le Coq, L.; Le Cloirec, P. Structure Characterization and Adsorption Properties of Pyrolyzed Sewage Sludge. Environ. Sci. Technol. 2005, 39 (11), 4249-4257.
25. 2S Removal on Sewage Sludge-Based Materials Enriched with Carbonaceous Phase. Carbon 2005, 43 (2), 359-367.
26. Ansari, A.; Bandosz, T. J. Inorganic-Organic Phase Arrangement as a factor Affecting Gas-Phase Desulfurization on catalytic Carbonaceous Adsorbents. Environ. Sci. Technol. 2005, 39 (16), 6217-6224.
27. Sioukri, E.; Bandosz, T. J. Enrichment of the performance of activated carbons as municipal odor removal media by addition of sewage sludge derived phase. Environ. Sci. Technol 2005, 39 (16), 6225-6230.
28. Bandosz, T. J. Sewage Sludge As a Single Precursor for Carbon Nanostructure/Activated Carbon/Catalytic Oxide Composite. Catal. Commun., submitted for publication.
29. Graham, J. Activated Carbon for Odor Control and Method for Making Same. U.S. Patent 6,858,192, 2005.
30. Bagreev, A.; Bandosz, T. J. On the mechanism of hydrogen sulfide adsorption/oxidation on catalytic carbons. Ind. Chem. Eng. Res. 2005, 44, 530-538.
31. Adib, F.; Bagreev, A.; Bandosz, T. J. Effect of Surface Characteristics of Wood-Based Activated Carbons on Adsorption of Hydrogen Sulfide. J. Colloid Interface Sci. 1999, 214, 407.
32. Adib, F.; Bagreev, A.; Bandosz, T. J. Adsorption/oxidation of Hydrogen Sulfide on Nitrogen Modified Activated Carbons. Langmuir 2000, 16, 1980.
33. Bandosz, T. J. On the adsorption/oxidation of hydrogen sulfide on unmodified activated carbon at temperatures near ambient. J. Colloid Interface Sci. 2002, 246 (1), 1-20.
34. Dubinin, M. M. In Chemistry and Physics of Carbon; P. L. Walker, Ed.; M. Dekker: New York, 1966; Vol. 2, pp 51-120.
35. Lastoskie, Ch. M.; Gubbins, K. E.; Quirke, N. Pore Size Distribution Analysis of Microporous Carbons: A Density Functional Theory Approach. J. Phys. Chem. 1993, 97, 4786-4796.
36. Olivier, J. P. Modeling Physical Adsorption on Porous and Nonporous Solids Using Density Functional Theory. J. Porous Mater. 1995, 2, 9.
37. 2+ on the Formation of α-SiAlON by the Carbothermal Reduction-Nitridation of Homogeneous Gel. Int. J. Inorg. Mater. 2001, 3 (7), 715-719.
38. 4 from Carbon Coated Silica by Carbothermal Reduction and Nitridation. J. European Ceramic Soc. 1998, 18 (10), 1471-1477.