Inorganic-organic phase arrangement as a factor affecting gas-phase desulfurization on catalytic carbonaceous adsorbents

Environmental Science and Technology

Volumn 39, Issue 16, 2005, Pages 6217-6224

  Ansari, Adil ^a   Bandosz, Teresa J ^a  

^a CITY COLLEGE OF NEW YORK   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION; CARBONIZATION; CATALYST ACTIVITY; DESULFURIZATION; HYDRATED LIME; HYDROGEN SULFIDE; MICROPOROSITY; SCANNING ELECTRON MICROSCOPY; SEWAGE SLUDGE; TITRATION;

MACROPOROUS CHAR; MESOPORES; PERCURSORS; POTENTIOMETRIC TITRATION;

CARBONACEOUS ADSORBENTS;

ADSORBENT; CALCIUM HYDROXIDE; CELLULOSE; HYDROGEN SULFIDE; INORGANIC COMPOUND; NITROGEN; ORGANIC COMPOUND; SULFATE; SULFUR;

DESULFURIZATION;

ADSORPTION; ARTICLE; CATALYSIS; DESULFURIZATION; GAS ANALYSIS; INDUSTRIAL SLUDGE; NONHUMAN; POROSITY; POTENTIOMETRIC TITRATION; REACTION ANALYSIS;

ADSORPTION; AIR POLLUTANTS; CARBON; CATALYSIS; CELLULOSE; HYDROGEN SULFIDE; PAPER; POROSITY; SEWAGE;

EID: 23844525518     PISSN: 0013936X     EISSN: None     Source Type: Journal    
DOI: 10.1021/es050053m     Document Type: Article

References (24)

1. Manahan S. E. Environmental Chemistry, 6th ed.; CRC Press: Boca Raton, FL, 1994.
2. http://www.epa.gov/air/caaac/dieselreview.pdf.
3. Bansal, R. C.; Donnet J. B.; Stoeckli, F. Active Carbon; Marcel Dekker: New York, 1988.
4. Bandosz, T. J. On the Adsorption/Oxidation of Hydrogen Sulfide on Unmodified Activated Carbon at Temperatures Near Ambient. J. Colloid Interface Sci. 2002, 246 (1), 1-20.
5. 2S Removal by Activated Carbons. J. Colloid Interface Sci. 1999, 216, 360.
6. 2S Removal Capacity and Surface Properties of Unimpregnated Activated Carbons. Environ. Sci. Technol. 2000, 34, 686.
7. Matviya, T. M.; Hayden, R. A. Catalytic Carbon. U.S. Patent 5,-356,849, 1994.
8. Graham, J. Activated Carbon for Odor Control and Method for Making Some. US Patent Provisional Application Aerial No. 60/ 254,900, Dec 11, 2000.
9. Bagreev, A.; Bandosz T. J. On the Mechanism of Hydrogen Sulfide Adsorption/Oxidation on Catalytic Carbons. Ind. Eng. Chem. Res. 2005, 44, 530-538.
10. Bagreev, A.; Bashkova, S.; Locke, D. C.; Bandosz, T. J. Sewage Sludge-Derived Materials as Efficient Adsorbents for Removal of Hydrogen Sulfide. Environ. Sci. Technol. 2001, 35, 1537.
11. Bagreev, A.; Bandosz, T. J. Efficient Desulfurization Adsorbents Obtained by Pyrolysis of Sewage Sludge Derived Fertilizer Modified with Spent Mineral Oil. Environ. Sci. Technol. 2004, 38, 345-351.
12. 2S Removal on Sewage Sludge-Based Materials Enriched with Carbonaceous Phase. Carbon 2005, 43 (2) 359-367.
13. Sioukri, E.; Bandosz, T. J. Enhancement of the performance of Activated carbons as Municipal Odor removal media by Addition of Sewage Sludge Derived Phase. Environ. Sci. Technol. 2005, 39, 6225-6230.
14. Bota, A.; Laszlo, K.; Nagy L. G.; Copitzky, T. Comparative Study of Active Carbons from Different Precursors. Langmuir 1997, 13, 6502-6509.
15. Laszlo, K.; Marthi, K.; Rochas, C.; Ehrburger-Dolle, F.; Livet, F.; Geissler, E. Morphological Investigation of Chemically Treated Poly(ethylene tetraphthalate)-Based Activated Carbons. Langmuir 2004, 20, 1321-1328.
16. Olivier, J. P. Modeling Physical Adsorption on Porous and Nonporous Solids Using Density Functional Theory. J. Porous Mater. 1995, 2, 9.
17. Lastoskie, C. M.; Gubbins, K. E.; Quirke, N. Pore Size Distribution Analysis of Microporous Carbons: A Density Functional Theory Approach. J. Phys. Chem. 1993, 97, 7: 4786-4796.
18. Bandosz, T. J.; Jagiello, J.; Contescu, C.; Schwarz, J. A. Characterization of Surfaces of Activated Carbons in Terms of the Acidity Constant Distribution. Carbon 1993, 31, 1193-1200.
19. Jagiello, J.; Bandosz, T. J.; Schwarz, J. A. Carbon Surface Characterization in Terms of its Acidity Constant Distribution. Carbon 1994, 32, 1026-1028.
20. Jagiello, J.; Bandosz, T. J.; Putyera, K.; Schwarz, J. A. Determination of Proton Affinity Distributions for Chemical Systems in Aqueous Environments using Stable Numerical Solution of the Adsorption Integral. J. Colloid Interface Sci. 1995, 172, 341-346.
21. Jagiello J. Stable Numerical Solution of the Adsorption Integral Equation using Splines Langmuir 1994, 10, 2778-2785.
22. Refractories; Carbon and Graphite Products; Activated Carbon; Advanced Ceramics. Standard Test for Method for Determination of the Accelerated Hydrogen Sulfide Breakthrough Capacity of Granular and Palletized Activated Carbon; ASTM Standards, Vol. 15.01; ASTM D6646-01; ASTM: West Conshohocken, PA, 1998.
23. Leon y Leon, C. A.; Radovic, L. R. Interfacial Chemistry and Electrochemistry of Carbon Surfaces. In Chemistry and Physics of Carbon; Thrower, P.A., Ed.; Marcel Dekker: New York, 1992; Vol. 24, pp 213-310.
24. Handbook of Chemistry and Physics, 67th ed.; Weast, R. C., Ed.; CRC Press: Boca Raton, FL, 1986.