Kinetics and mechanistic aspects of As(III) oxidation by aqueous chlorine, chloramines, and ozone: Relevance to drinking water treatment

Environmental Science and Technology

Volumn 40, Issue 10, 2006, Pages 3285-3292

  Dodd, Michael C ^a   Vu, Ngoc Duy ^b   Ammann, Adrian ^a   Le, Van Chieu ^b   Kissner, Reinhard ^c   Pham, Hung Viet ^b   Cao, The Ha ^b   Berg, Michael ^a   Von Gunten, Urs ^a  

^a SWISS FEDERAL INSTITUTE OF AQUATIC SCIENCE AND TECHNOLOGY   (Switzerland)

^b VIETNAM NATIONAL UNIVERSITY   (Viet Nam)

^c LABORATORY OF INORGANIC CHEMISTRY   (Switzerland)

Author keywords

[No Author keywords available]

Indexed keywords

CONCENTRATION (PROCESS); OXIDATION; OZONE; PH EFFECTS; REACTION KINETICS; STOICHIOMETRY; WATER TREATMENT;

BUFFERED REAGENT SOLUTIONS; DOC CONCENTRATIONS; TIME RESOLVED MEASUREMENTS;

ARSENIC;

AMMONIA; ARSENIC; CHLORAMINE DERIVATIVE; CHLORINE; DRINKING WATER; OZONE;

ARSENIC; CONCENTRATION (PROCESS); OXIDATION; OZONE; PH EFFECTS; REACTION KINETICS; STOICHIOMETRY; WATER TREATMENT;

ARSENIC; CHLORINE; DRINKING WATER; OXIDATION; OZONE; WATER TREATMENT;

AQUEOUS SOLUTION; ARTICLE; CHLORINATION; CONCENTRATION (PARAMETERS); KINETICS; MOLECULAR MODEL; OXIDATION; OZONATION; PH MEASUREMENT; STOICHIOMETRY; WATER TREATMENT;

AMMONIA; ARSENIC; CATIONS; CHLORAMINES; CHLORINE; HYDROGEN-ION CONCENTRATION; KINETICS; OXIDATION-REDUCTION; OZONE; WATER PURIFICATION; WATER SUPPLY;

EID: 33646720710     PISSN: 0013936X     EISSN: None     Source Type: Journal    
DOI: 10.1021/es0524999     Document Type: Article

References (36)

1. Cullen, W. R.; Reimer, K. J. Arsenic Speciation in the Environment. Chem. Rev. 1989, 89, 713-764.
2. Frey, M. M.; Edwards, M. A. Surveying arsenic occurrence. J. Am. Water Works Ass. 1997, 89, 105-117.
3. Berg, M.; Tran, H. C.; Nguyen, T. C.; Pham, H. V.; Schertenleib, R.; Giger, W. Arsenic contamination of groundwater and drinking water in Vietnam: A human health threat. Environ. Sci. Technol. 2001, 35, 2621-2626.
4. Smith, A. H.; Lingas, E. O.; Rahman, M. Contamination of drinking-water by arsenic in Bangladesh: A public health emergency. Bull. W. H. O. 2000, 78, 1093-1103.
5. Guidelines for Drinking-water Quality; 3rd ed.; World Health Organization: Geneva, Switzerland, 2004; Vol. 1.
6. Hering, J. G.; Chiu, V. Q. Arsenic occurrence and speciation in municipal groundwater-based supply system. J. Environ. Eng., ASCE 2000, 126, 471-474.
7. Council Directive 98/83/EC of 3 November 1998 on the quality of water intended for human consumption. Off. J. Eur. Communities 1998, 41, 32-54.
8. National Primary Drinking Water Regulations. Code of Federal Regulations, Part 141, Title 40, 2001, http://www.epa.gov/epahome/cfr40.htm.
9. Technologies and Costs for Removal of Arsenic from Drinking Water, United States Environmental Protection Agency-Office of Water: Washington, DC, 2000 (http://www.epa.gov/safewater/ars/treatments_and_costs.pdf).
10. Ghurye, G.; Clifford, D. As(III) oxidation using chemical and solid-phase oxidants. J. Am. Water Works Assoc. 2004, 96, 84-96.
11. Leupin, O. X.; Hug, S. J.; Badruzzaman, A. B. M. Arsenic removal from Bangladesh tube well water with filter columns containing zerovalent iron filings and sand. Environ. Sci. Technol. 2005, 39, 8032-8037.
12. McArthur, J. M.; Ravenscroft, P.; Safiulla, S.; Thirlwall, M. F., Arsenic in groundwater: Testing pollution mechanisms for sedimentary aquifers in Bangladesh. Water Resour. Res. 2001, 37, 109-117.
13. Duong, H. A.; Berg, M.; Hoang, M. H.; Pham, H. V.; Gallard, H.; Giger, W.; von Gunten, U. Trihalomethane formation by chlorination of ammonium- and bromide-containing groundwater in water supplies of Hanoi, Vietnam. Water Res. 2003, 37, 3242-3252.
14. Standard Methods for the Examination of Water and Wastewater, 20th ed.; APHA, AWWA, WPCF: Washington DC, 1998.
15. Kumar, K.; Day, R. A.; Margerum, D. W. Atom-transfer redox kinetics: General-acid-assisted oxidation of iodide by chloramines and hypochlorite. Inorg. Chem. 1986, 25, 4344-4350.
16. Bader, H.; Hoigné, J. Determination of ozone in water by the indigo method. Water Res. 1981, 15, 449-456.
17. Leitzke, A.; Reisz, E.; Flyunt, R.; von Sonntag, C. The reactions of ozone with cinnamic acids: formation and decay of 2-hydroperoxy-2-hydroxyacetic acid. J. Chem. Soc., Perkin Trans. 2 2001, 793-797.
18. Sadiq, M.; Zaidi, T. H.; Mian, A. A. Environmental behavior of arsenic in soils-theoretical. Water Air Soil Pollut. 1983, 20, 369-377.
19. Lide, D. R., Ed. CRC Handbook of Chemistry and Physics, 82nd ed.; CRC Press: Boca Raton, FL, 2001.
20. Stumm, W.; Morgan, J. J. Aquatic Chemistry, 3rd ed.; John Wiley and Sons: New York, 1996.
21. Fogelman, K. D.; Walker, D. M.; Margerum, D. W. Non-metal redox kinetics: hypochlorite and hypochlorous acid reactions with sulfite. Inorg. Chem. 1989, 28, 986-993.
22. Gerritsen, C. M.; Margerum, D. W. Non-metal redox kinetics: hypochlorite and hypochlorous acid reactions with cyanide. Inorg. Chem. 1990, 29, 2757-2762.
23. Qiang, Z.; Adams, C. D. Determination of monochloramine formation rate constants with stopped-flow spectrophotometry. Environ. Sci. Technol. 2004, 38, 1435-1444.
24. Yiin, B. S.; Walker, D. M.; Margerum, D. W. Nonmetal redox kinetics: general-acid-assisted reactions of chloramine with sulfite and hydrogen sulfite. Inorg. Chem. 1987, 26, 3435-3441.
25. Margerum, D. W.; Schurter, L. M.; Hobson, J.; Moore, E. E. Water Chlorination Chemistry: Nonmetal Redox Kinetics of Chloramine and Nitrite Ion. Environ. Sci. Technol. 1994, 28, 331-337.
26. Hoigné, J. In The Handbook of Environmental Chemistry; Hrubec, J., Ed.; Springer-Verlag: Berlin, Germany, 1998; pp 83-141.
27. Liu, Q.; Schurter, L. M.; Muller, C. E.; Aloisio, S.; Francisco, J. S.; Margerum, D.W. Kinetics and mechanisms of aqueous ozone reactions with bromide, sulfite, hydrogen sulfite, iodide, and nitrite ions. Inorg. Chem. 2001, 40, 4436-4442.
28. Gray, E. T., Jr.; Margerum, D. W.; Huffman, R. P. In Organometals and Organometalloids, Occurrence and Fate in the Environment; Brinkman, F. E., Bellama, J. M., Eds.; American Chemical Society: Washington, D. C., 1978; pp 264-277.
29. Hoigné, J.; Bader, H. Ozonation of water: Kinetics of oxidation of ammonia by ozone and hydroxyl radicals. Environ. Sci. Technol. 1978, 12, 79-84.
30. Buffle, M.-O.; Schumacher, J.; Salhi, E.; von Gunten, U. Measurement of the initial phase of ozone decomposition in water and wastewater by means of a continuous quench flow system: Application to disinfection and pharmaceutical oxidation. Water Res. 2006, in press.
31. von Gunten, U. Ozonation of drinking water: Part I. Oxidation kinetics and product formation. Water Res. 2003, 37, 1443-1467.
32. Klaening, U. K.; Bielski, B. H. J.; Sehested, K. Arsenic(IV)-a pulse-radiolysis study. Inorg. Chem. 1989, 28, 2717-2724.
33. ct concept. Ozone: Sci. Eng. 1999, 21, 239-260.
34. Conocchioli, T. J.; Hamilton, E. J.; Sutin, N. Formation of Iron(IV) in Oxidation of Iron(II). J. Am. Chem. Soc. 1965, 87, 926-927.
35. Løgager, T.; Holcman, J.; Sehested, K.; Pedersen, T. Oxidation of Ferrous-Ions by Ozone in Acidic Solutions. Inorg. Chem. 1992, 31, 3523-3529.
36. Pinkernell, U.; von Gunten, U. Bromate minimization during ozonation: Mechanistic considerations. Environ. Sci. Technol. 2001, 35, 2525-2531.