Study on soap-free P(MMA-EA-AA or MAA) latex particles with narrow size distribution

Polymers for Advanced Technologies

Volumn 17, Issue 3, 2006, Pages 193-198

  Kang, Kai ^a   Kan, Chengyou ^a   Du, Yi ^a   Liu, Deshan ^a  

^a TSINGHUA UNIVERSITY   (China)

Author keywords

Emulsion polymerization; Initiator; Methyl methacrylate based copolymer; Soap free latex particles; Swelling

Indexed keywords

COPOLYMERS; EMULSION POLYMERIZATION; LATEXES; MONOMERS; PARTICLE SIZE ANALYSIS; POLYMERIZATION; SYNTHESIS (CHEMICAL);

ACRYLIC ACID (AA); ETHYL ACRYLATE (EA); METHACRYLIC ACID (MAA); METHYL METHACRYLATE (MMA); SOAP-FREE LATEX PARTICLES;

POLYMETHYL METHACRYLATES;

COPOLYMERS; EMULSION POLYMERIZATION; LATEXES; MONOMERS; PARTICLE SIZE ANALYSIS; POLYMERIZATION; POLYMETHYL METHACRYLATES; SYNTHESIS (CHEMICAL);

LATEX; MONOMER; POLYMERIZATION; POLYMETHYL METHACRYLATE; SWELLING AGENT;

EID: 33646715853     PISSN: 10427147     EISSN: 10991581     Source Type: Journal    
DOI: 10.1002/pat.714     Document Type: Article

References (26)

1. Xia YN, Gates B, Yin Y, Lu Y. Monodispersed colloidal spheres: Old materials with new applications. Adv. Mater. 2000; 12(10): 693-713.
2. Kondo Y, Takayanagi K. Synthesis and characterization of helical multi-shell gold nanowires. Science 2000; 289(5479): 606-608.
3. Tuncel A, Kahraman R, Piskin E. Monosize polystyrene latices carrying functional groups on their surfaces. J. Appl. Polym. Sci. 1994; 51(5): 1485-1498.
4. Ishizu K. Synthesis and structural ordering of core-shell polymer microspheres. Prog. Polym. Sci. 1998; 23(8): 1383-1408.
5. Ugelstad J, Kaggerud KH, Fitch RM. In Polymer Colloid II, Fitch RM (ed.). Plenum: New York, 1980.
6. Okubo M, Katayama Y, Yamamoto Y. Preparation of micron-size monodisperse polymer microspheres having crosslinked structures and vinyl groups. Colloid Polym. Sci. 1991; 269(3): 217-221.
7. Ugelstad J, Mfutakamba HR, Mork PC, Elingsen T, Berge A, Schmid R, Holm L, Jorgedal A, Hansen FK, Nustad K. Preparation and application of monodisperse polymer particles. J. Polym. Sci., Polym. Symp. 1985; 72: 225-240.
8. Keville KM, Caruthers JM, Franses EI. Characterization of dimensions of ellipsoidal microparticles via electron microscopy. J. Microscopy 1986; 142: 327-340.
9. Ho CC, Keller A, Ottewill RH, Odell JA. International Symposium on Polymeric Microspheres, Japan, 1991; 105.
10. Cheng CM, Vanderhoff JW, El-Aasser MS. Monodisperse porous polymer particles: Formation of the porous structure. J. Polym. Sci., Polym Chem. 1992; 30(2): 245-256.
11. Kan CY, Li HH, Yuan Q, Kong XZ. Preparation of porous latex particles by emulsion polymerization. Korea Polym. J. 1997; 5: 221-227.
12. Kan CY, Li HH, Sun J, Yuan Q, Kong XZ. Preparation of multihollow particles by seeded emulsion copolymerization. Acta Polym. Sincia 1999; 2: 199-203.
13. Kong XZ, Kan CY, Li HH, Yu DO, Yuan Q. Synthesis and characterization of hollow polymer latex particles. Polym. Adv. Technol. 1997; 8: 627-630.
14. Kang K, Kan CY, Du Y, Liu DS. Control of particle size and carboxyl group distribution in soap-free emulsion copolymerization of methyl methacrylate-ethyl acrylate-acrylic acid. J. Appl. Polym. Sci. 2004; 92(1): 433-438.
15. Kang K, Kan CY, Du Y, Liu DS. Effects of alkali post-treatment on the particle morphology of soap-free poly(methyl methacrylate-ethyl acrylate-acrylic acid) latices. Polym. Adv. Technol. 2004; 15(11): 676-682.
16. Muroi S, Hosoi K, Ishikawa T. Alkali solubility of carboxylated polymer emulsions. J. Appl. Polym. Sci. 1967; 11(10): 1963-1978.
17. Green BW. Quantitative determination of surface carboxyl groups in vinyl acid modified styrene/butadiene copolymer. I. Latexes prepared with acrylic acid. J. Colloid Interf. Sci. 1973; 43(2): 449-461.
18. Meier GL. Stable Latex for Paper Coating Compositions. US Patent 3575913, 1971.
19. Sakota K, Okaya T. Polymerization behavior of carboxylic monomers in the preparation of carboxylated latexes. J. Appl. Polym. Sci. 1976; 20(9): 2583-2587.
20. Kawaguchi H, Sugi Y, Ohtsuka Y. Copolymerization of styrene with acrylamide derivatives in an emulsifier-free aqueous medium. J. Appl. Polym. Sci. 1981; 26(5): 1649-1657.
21. Ugelstad J, Mork PC, Kaggerud KH, Ellingsen T, Berge A. Swelling of oligomer-polymer particles: New methods of preparation of emulsions and polymer dispersions. Adv. Colloid Interf. Sci. 1980; 13: 101-140.
22. Wang ST, Poehlein GW. Studies of water-soluble oligomers formed in emulsion copolymerization. J. Appl. Polym. Sci. 1994; 51(4): 593-604.
23. Ou JL, Yang JK, Chen H. Styrene/potassium persulfate/water systems: Effects of hydrophilic comonomers and solvent additives on the nucleation mechanism and the particle size. Eur. Polym. J. 2001; 37(4): 789-799.
24. Greene BW. Quantitative determination of surface carboxyl groups in vinyl acid modified styrene/butadiene copolymer. II. Latexes prepared with methacrylic acid. J. Colloid Interf. Sci. 1973; 43(2): 462-472.
25. Vijayendran BR. Effect of carboxylic monomers on acid distribution in carboxylated polystyrene latices. J. Appl. Polym. Sci. 1979; 23(3): 893-901.
26. Peula-Garcia JM, Hidalgo-Alvarez R, de las Nieves FJ. Colloid stability and electrokinetic characterization of polymer colloids prepared by different methods. Colloid and Surface A 1997; 127: 19-24.