Structural investigations of natural and synthetic chlorite minerals by x-ray diffraction, Mössbauer spectroscopy and solid-state nuclear magnetic resonance

Clays and Clay Minerals

Volumn 54, Issue 2, 2006, Pages 252-265

  Zazzi, Åsa ^a   Hirsch, Tomas K ^b,c   Leonova, Ekaterina ^b   Kaikkonen, Andrei ^b   Grins, Jekabs ^b   Annersten, Hans ^d   Edén, Mattias ^b  

^a ROYAL INSTITUTE OF TECHNOLOGY   (Sweden)

^b STOCKHOLM UNIVERSITY   (Sweden)

^c SLAC NATIONAL ACCELERATOR LABORATORY   (United States)

^d UPPSALA UNIVERSITY   (Sweden)

Author keywords

27Al NMR; 29Si NMR; Cation distrubutions; Chlorite; Layered mineral; Mineral structure; M ssbauer spectroscopy; XRD

Indexed keywords

ALUMINUM; CRYSTAL STRUCTURE; CRYSTALLOGRAPHY; IRON; MOSSBAUER SPECTROSCOPY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POSITIVE IONS; SILICON; X RAY DIFFRACTION ANALYSIS;

CATION DISTRIBUTIONS; LAYERED MINERAL; MINERAL STRUCTURE;

CHLORITE MINERALS;

CATION; CHLORITE GROUP; CRYSTAL STRUCTURE; CRYSTALLOGRAPHY; IONIC COMPOSITION; LAYERED MEDIUM; MOSSBAUER SPECTROSCOPY; NUCLEAR MAGNETIC RESONANCE; X-RAY DIFFRACTION;

EID: 33646558014     PISSN: 00098604     EISSN: None     Source Type: Journal    
DOI: 10.1346/CCMN.2006.0540210     Document Type: Article

References (42)

1. Annersten, H. (1974) Mössbauer studies of biotites. American Mineralogist, 59, 143-151.
2. Bailey, S.W. (1980) Structures of layer silicates. Pp. 1-123 in: Crystal Structures of Clay Minerals and their X-ray Identification (G.W. Brindley and G. Brown, editors). Monograph 5, Mineralogical Society, London.
3. Bailey, S.W. (1988) Chlorites: structures and crystal chemistry. Pp. 347-403 in: Hydrous Phyllosilicates (Exclusive of Micas). (S.W. Bailey, editor). Reviews in Mineralogy, 19. Mineralogical Society of America, Washington, D.C.
4. Bailey, S.W., Brindley, G.W., Johns, W.D., Martin, R.T. and Ross, M. (1971) Summary of national and international recommendations on clay mineral nomenclature by 1969-1970. Clay Minerals Society Nomenclature Committee. Clays and Clay Minerals, 64, 129-132.
5. Barron, P.F., Slade, P. and Frost, R.L. (1985) Ordering of aluminum in tetrahedral sites in mixed-layer 2:1 phyllosilicates by solid-state high-resolution NMR. Journal of Physical Chemistry, 89, 3880-3885.
6. Brandt, F., Bosbach, D., Krawczyk-Bärsch, E., Arnold, T. and Bernhard, G. (2003) Chlorite dissolution in the acid pH-range: a combined microscopic and macroscopic approach. Geochimica et Cosmochimica Acta 67, 1451-1461.
7. Brindley, G.W. and Brown, G. (1984) Crystal Structures of Clay Minerals and their X-ray Identification (G.W. Brindley and G. Brown, editors). Monograph 5. Mineralogical Society, London.
8. Brown, S.P. and Wimperis, S. (1997) Two-dimensional multiple-quantum MAS NMR of quadrupolar nuclei: A comparison of methods. Journal of Magnetic Resonance, 128, 42-61.
9. Dempsey, E. (1969) The calculation of Madelung potentials for Faujasite-type zeolites. I. Journal of Physical Chemistry, 73, 3660-3668.
10. Ericsson, T. and Wäppling, R. (1976) Texture effects in 3/2-1/2 Mössbauer spectra. Journal de Physic, Colloque C6 supplement, 12, 719-723.
11. Ferrow, E. and Roots, M. (1989) A preparation technique for TEM specimens: application to synthetic Mg-chlorite. European Journal of Mineralogy, 1, 815-819.
12. Foster, M.D. (1962) Interpretation of the composition and a classification of chlorites. US Geological Survey, Professional Paper, 414-A, 1-33.
13. Frydman, L. and Harwood, J.S. (1995) Isotropic spectra of half-integer quadrupolar spins from bidimensional Magic-Angle Spinning NMR. Journal of the American Chemical Society, 117, 5367-5368.
14. 2+ in olivinen. Zeitschrift für Chemie, 23, 343-344.
15. 29NMR spectra. Journal of Physical Chemistry, 93, 4311-4315.
16. Johansson, K.E., Palm, T. and Werner, P.-E. (1980) An automatiac microdensitometer for X-ray powder diffraction photographs. Journal of Physics E: Scientific Instruments, 13, 1289-1291.
17. Joswig, W., Fuess, H., Rothbauer, R., Takéuchi, Y. and Mason, S.A. (1980) A neutron diffraction study of a one-layer triclinic chlorite (pennite). American Mineralogist, 65, 349-352.
18. Klein, C. (2002) The 22nd edition of the Manual of Mineral Science. John Wiley & Sons, Inc., New Jersey, 641 pp.
19. 29Si magic-angle-spinning NMR spectroscopy. Journal of the American Ceramic Society, 69, C-45-C-47.
20. 29Si MAS NMR studies of illite and illite-smectite from shale. American Mineralogist, 84, 1433-1438.
21. Levitt, M.H. (1997) The signs of frequencies and phases in NMR. Journal of Magnetic Resonance, 126, 164-182.
22. 27Al NMR of aluminosilicates. Journal of the American Chemical Society, 108, 1730-1735.
23. Loewenstein, W. (1959) The distribution of aluminum in the tetrahedra of silicates and aluminates. American Mineralogist, 39, 92-96.
24. Lougear, A., Grodzicki, M., Bertoldi, C., Trautwein, A.X., Steiner, K. and Amthauer, G. (2000) Mössbauer and molecular orbital study of chlorites. Physics and Chemistry of Minerals, 27, 258-269.
25. Madhu, P.K., Goldbourt, A., Frydman, L. and Vega, S. (1999) Sensitivity enhancement of the MQMAS NMR experiment by fast amplitude modulation of the pulses. Chemical Physics Letters, 307, 41-47.
26. Man, P.P. (1998) Scaling and labeling the high-resolution isotropic axis of two-dimensional multiple-quantum magic-angle-spinning spectra of half-integer quadropole spins. Physical Review B, 58, 2764-2782.
27. Massiot, D., Touzo, B., Trumeau, D., Coutures, J.P., Virlet, J., Florian, P. and Grandinetti, P.J. (1996) Two-dimensional magic-angle spinning isotropic reconstruction sequences for quadrupolar nuclei. Solid State Nuclear Magnetic Resonance 6, 73-83.
28. Moore, D.M. and Reynolds, R.C., Jr. (1997) X-ray Diffraction and the Identification and Analysis of Clay Minerals. Oxford University Press, New York, 378 pp.
29. 27Al NMR spectroscopy of iron-bearing montmorillonite clays. Journal of Physical Chemistry, 94, 3121-3129.
30. Mägi, M., Lippmaa, E., Samoson, A., Engelhardt, G. and Grimmer, A.-R. (1984) Solid-state high-resolution silicon-29 chemical shifts in silicates. Journal of Physical Chemistry, 88, 1518-1522.
31. Nagy, K.L. (1995) Dissolution and precipitation kinetics of sheet silicates. Pp. 173-233 in: Chemical Weathering Rates of Silicate Minerals (P.H. Ribbe, editor). Reviews in Mineralogy, 31. Mineralogical Society of America, Washington, D.C.
32. Nakata, S., Asaoka, S., Tadami, K. and Takahashi, H. (1986) Characterization of natural zeolites and clays by high-resolution solid-state NMR. Nendo-Kagaku 26, 197-208.
33. Newman, A.C.D. and Brown, G. (1987) The chemical constitution of clay. Pp. 1-128 in: Chemistry of Clays and Clay Minerals (A.C.D. Newman, editor). Longman Scientific and Technical, Essex, UK.
34. 27Al MQMAS NMR. Clays and Clay Minerals 51, 513-518.
35. Oldfield, E., Kinsey, R.A., Smith, K.A., Nichols, J.A. and Kirkpatrick, J.R. (1983) High-resolution NMR of inorganic solids. Influence of magnetic centers on magic-angle sample spinning lineshapes in some natural aluminosilicates. Journal of Magnetic Resonance, 51, 325-329.
36. 3+ coordination in chlorites: a structural study of ten chromian chlorites. American Mineralogist, 65 112-122.
37. Rodriguez-Carjaval, J. (2002) Fullprof_2000 [http://www-llb.cea.fr/ fullweb/fp2k/fp2k_intro.htm]. Published online by Leon Brilloin.
38. 27Al high-resolution MAS-NMR spectra of phyllosilicates. Journal of the American Chemical Society, 106, 4790-4793.
39. 27Al NMR techniques to structure determination in solids. Applied Magnetic Resonance, 34, 159-201.
40. 29Si-NMR and EPR. Chemistry Letters, 8, 1293-1296.
41. 29Si NMR spectroscopy of 2:1 layer silicates: Correlations among chemical shift, structural distortions and chemical variations. American Mineralogist, 72, 935-942.
42. Welch, M.D., Barras J. and Klinowski, J. (1995) A multinuclear NMR study of clinochlore. American Mineralogist, 80, 441-447.