Highly active nickel complexes containing functionalized bipyridine ligands for norbornene polymerization

Bulletin of the Korean Chemical Society

Volumn 27, Issue 4, 2006, Pages 475-476

  Shin, Ae Lee ^a   Ki, Youn Shin ^a   Byung, Joo Park ^a   Moon, Kun Choi ^b   Lee, Ik Mo ^a  

^a Inha University   (South Korea)

^b Yonsei University   (South Korea)

Author keywords

Functionalized bipyridine; MMAO; Nickel complexes; Norbornene polymerization; Vinyl addition polymerization

Indexed keywords

EID: 33646541089     PISSN: 02532964     EISSN: 12295949     Source Type: Journal    
DOI: 10.5012/bkcs.2006.27.4.475     Document Type: Article

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25. 2) atmosphere, MMAO (catalyst : cocatalyst = 1 : 1000) was placed into a small vial. To this was added approximately 5 mL of solvent, and the mixture gently shaken to dissolve the solids. This solution was then added to 0.001 g of catalyst, 100000 equivalent of norbornene dissolved in approximately 10 mL of solvent in a vial containing a stirring bar. The solution was stirred rapidly for about 2 min. The product was quenched by adding acidified methanol. The solid was washed with methanol and dried under vacuum.