Total synthesis of two isoflavone C-glycosides: genistein and orobol 8-C-β-d-glucopyranosides

Carbohydrate Research

Volumn 341, Issue 9, 2006, Pages 1091-1095

  Sato, Shingo ^a   Hiroe, Kaoru ^a   Kumazawa, Toshihiro ^a   Jun ichi, Onodera ^a  

^a YAMAGATA UNIVERSITY   (Japan)

Author keywords

C Glycosylation; Isoflavone C glycosides; O Debenzylation; Oxidative rearrangement; Total synthesis

Indexed keywords

ACETAL RESINS; CONDENSATION; MOLECULAR DYNAMICS; OXIDATION; SYNTHESIS (CHEMICAL); THALLIUM COMPOUNDS;

C-GLYCOSYLATION; ISOFLAVONE C-GLYCOSIDES; O-DEBENZYLATION; OXIDATIVE REARRANGEMENT; TOTAL SYNTHESIS;

GLUCOSE;

2' ACETOXY 3,4,4',6' TETRABENZYLOXY 3' C (2,3,4,6 TETRA O BENZYL BETA DEXTRO GLUCOPYRANOSYL)CHALCONE; 2' ACETOXY 4,4',6' TRIBENZYLOXY 3' C (2,3,4,6 TETRA O BENZYL BETA DEXTRO GLUCOPYRANOSYL)CHALCONE; 2,4 DI O BENZYLPHLOROACETOPHENONE; 3,4,4' 6' TETRABENZYLOXY 2' HYDROXY 3' C (2',3' ,4' ,6' TETRA O BENZYL BETA DEXTRO GLUCOPYRANOSYL)CHALCONE; 4,4',6' TRIBENZYLOXY 2' HYDROXY 3' C (2,3,4,6 TETRA O BENZYL BETA DEXTRO GLUCOPYRANOSYL)CHALCONE; 5,7,3',4' TETRABENZYLOXY 8 C (2,3,4,6 TETRA O BENZYL BETA DEXTRO GLUCOPYRANOSYL)ISOFLAVONE; 5,7,4' TRIBENZYLOXY 8 C (2,3,4,6 TETRA O BENZYL BETA DEXTRO GLUCOPYRANOSYL)ISOFLAVONE; 7,3',4' TRIBENZYLOXY 5 HYDROXY 8 C (2,3,4,6, TETRA O BENZYL BETA DEXTRO GLUCOPYRANOSYL)ISOFLAVONE; 7,4' DIBENZYLOXY 5 HYDROXY 8 C (2,3,4,6 TETRA O BENZYL BETA DEXTRO GLUCOPYRANOSYL)ISOFLAVONE; ACETAL; ACID; C GLYCOSYLPHLOROACETOPHENONE; CHALCONE; GENISTEIN; GLYCOSIDE; ISOFLAVONE; ISOFLAVONE DERIVATIVE; NITROGEN; OROBOL 8 C BETA DEXTRO GLUCOPYRANOSIDE; OXYGEN; PYRANOSIDE; UNCLASSIFIED DRUG;

ALDOL REACTION; ARTICLE; CATALYSIS; CYCLIZATION; DEBENZYLATION; HYDROGENOLYSIS; OXIDATION; POLYMERIZATION; PRIORITY JOURNAL; REACTION ANALYSIS; STRUCTURE ACTIVITY RELATION; SYNTHESIS;

FLAVONOIDS; GENISTEIN; GLUCOSE;

EID: 33646524487     PISSN: 00086215     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.carres.2006.03.038     Document Type: Article

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