Acidic mesoporous silica for the catalytic conversion of fatty acids in beef tallow

Industrial and Engineering Chemistry Research

Volumn 45, Issue 9, 2006, Pages 3022-3028

  Mbaraka, Isa K ^a   McGuire, Kyle J ^a   Shanks, Brent H ^a  

^a 494 Town Engineering Building   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYTIC CONVERSION; CATALYTIC PERFORMANCE; MESOPOROUS SILICA; PROPYLSULFONIC ACID;

ACIDITY; CATALYSIS; CATALYST ACTIVITY; ESTERIFICATION; MESOPOROUS MATERIALS; SILICA; SYNTHESIS (CHEMICAL);

FATTY ACIDS;

ACIDITY; CATALYSIS; CATALYST ACTIVITY; ESTERIFICATION; FATTY ACIDS; MESOPOROUS MATERIALS; SILICA; SYNTHESIS (CHEMICAL);

EID: 33646505526     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie0601089     Document Type: Article

References (35)

1. Noureddini, H.; Harkey, D.; Medikonduru, V. A Continuous Process for the Conversion of Vegetable Oils into Methyl Esters of Fatty Acid. J. Am. Oil Chem. Soc. 1998, 75, 1775.
2. Gryglewicz, S. Rapeseed Oil Methyl Esters Preparation Using Heterogeneous Catalysts. Bioresour. Technol. 1999, 70, 249.
3. Raneses, A. R.; Glaser, L. K.; Price, J. M.; Duffield, J. A. Potential Biodiesel Markets and Their Economic Effects on the Agricultural Sector of the United States. Ind. Crops Prod. 1999, 9, 151.
4. Schuchardt, U.; Sercheli, R.; Vargas, R. M. Transesterification of Vegetable Oils: A Review. J. Braz. Chem. Soc. 1998, 9, 199.
5. Boocock, D. G. B.; Konar, S. K.; Mao, V.; Lee, C.; Buligan, S. Fast Formation of High-Purity Methyl Esters from Vegetable Oils. J. Am. Oil Chem. Soc. 1998, 75, 1167.
6. Sercheli, R.; Vargas, R. M.; Schuchardt, U. Alkyguanidine-Catalyzed Heterogeneous Transesterification of Soybean Oil. J. Am. Oil Chem. Soc. 1999, 76, 1207.
7. Rudbeck, J. 2000 in Review; Prospects for 2001. Render 2001 (Apr), 10.
8. Canakci, M.; Van Gerpen, J. Biodiesel Production via Acid Catalysis. Trans. ASAE 1999, 42, 1203.
9. Canakci, M.; Van Gerpen, J. Biodiesel Production from Oils and Fats with High Free Fatty Acids. Trans. ASAE 2001, 44, 1429.
10. Lotero, E.; Liu, Y.; Lopez, D. E.; Suwannakarn, K.; Brace, D. A.; Goodwin, J. G. Synthesis of Biodiesel via Acid Catalysis. Ind. Eng. Chem. Res. 2005, 44, 5353.
11. Basu, H. N.; Noms, M. E. Process for Production of Esters for Use as a Diesel Fuel Substitute Using a Non-Alkaline Catalyst. U.S. Patent 5,525,126, 1996.
12. Koono, S.; Moriya, O.; Noguchi, T.; Okamura, H. Process of Producing Carboxylic Acid Ester. E.P. Patent 566,047, 1993.
13. Stein, A.; Melde, B. J.; Schroden, R. C. Hybrid Inorganic-Organic Mesoporous Silicates-Nanoscopic Reactors Coming of Age. Adv. Mater. 2000, 12, 1403.
14. Ying, J. Y.; Mehnert, C. P.; Wong, M. S. Synthesis and Applications of Supramolecular-Templated Mesoporous Materials. Angew. Chem., Int. Ed. 1999, 38, 56.
15. Wight, A. P.; Davis, M. E. Design and Preparation of Organic-Inorganic Hybrid Catalysts. Chem. Rev. 2002, 102, 3589.
16. Soler-Illia, G. J. A.; Sanchez, C.; Lebeau, B.; Patarin, J. Chemical Strategies To Design Textured Materials: From Microporous and Mesoporous Oxides to Nanonetworks and Hierarchical Structures. Chem. Rev. 2002, 102, 4093.
17. Park, M.; Komameni, S. Stepwise Functionalization of Mesoporous Crystalline Silica Materials. Microporous Mesoporous Mater. 1998, 25, 75.
18. Lim, M. H.; Blanford, C. F.; Stein, A. Synthesis of Ordered Microporous Silicates with Organosulfur Surface Groups and Their Applications as Solid Acid Catalysts. Chem. Mater. 1998, 10, 467.
19. Jones, C. W.; Tsuji, K.; Davis, M. E. Organic-Functionalized Molecular Sieves as Shape-Selective Catalysts. Nature 1998, 393, 52.
20. Van Rhijin, W. M.; De Vos, D. E.; Bossaert, W. D.; Jacobs, P. A. Sulfonic Acid Functionalized Ordered Mesoporous Materials as Catalysts for Condensation and Esterification Reactions. Chem. Commun. 1998, 317.
21. Bossaert, W. D.; De Vos, D. E.; Van Rhijin, W. M.; Bullen, J.; Grobet, P. J.; Jacobs, P. A. Mesoporous Sulfonic Acids as Selective Heterogeneous Catalysts for the Synthesis of Monoglycerides. J. Catal. 1999, 182, 156.
22. Diaz, I.; Marquez-Alvarez, C.; Mohino, F.; Perez-Pariente, J.; Sastre, E. Combined Alkyl and Sulfonic Acid Functionalization of MCM-41 Type Silica Part 2. Esterification of Glycerol with Fatty Acids. J. Catal. 2000, 193, 295.
23. Diaz, I.; Mohino, F.; Perez-Pariente, J.; Sastre, E. Synthesis of MCM-41 Materials Functionalized with Dialkylsilane Groups and Their Catalytic Activity in the Esterification of Glycerol with Fatty Acids. Appl. Catal., A 2003, 242, 161.
24. Alvaro, M.; Corma, A.; Das, D.; Fornes, V.; Garcia, H. "Nafion"-Functionalized Mesoporous MCM-41 Silica Shows High Activity and Selectivity for Carboxylic Acid Esterification and Friedel-Crafts Acylation Reactions. J. Catal. 2005, 231, 48.
25. Mbaraka, I. K.; Radu, D. R.; Lin, V. S.-Y.; Shanks, B. H. Organosulfonic Acid-Functionalized Mesoporous Silicas for the Esterification of Fatty Acid. J. Catal. 2003, 219, 329.
26. Mbaraka, I. K.; Shanks, B. H. Design of Multifunctionalized Mesoporous Silicas for Esterification of Fatty Acid. J. Catal. 2005, 229, 365.
27. Verne, R. Pretreatment of Soapstocks Prior to Production of Biodiesel. Personal Communication, 2005.
28. Melero, J. A.; Stucky, G. D.; van Grieken, R.; Morales, G. Direct Syntheses of Ordered SBA-15 Mesoporous Materials Containing Arenesulfonic Acid Groups. J. Mater. Chem. 2002, 12, 1664.
29. Zhao, D.; Feng, J.; Huo, Q.; Melosh, N.; Fredrickson, G. H.; Chmelka, B. F.; Stucky, G. D. Triblock Copolymer Syntheses of Mesoporous Silica with Periodic 50 to 300 Angstrom Pores. Science 1998, 279, 548.
30. Kruk, M.; Jaroniec, M.; Ko, C. H.; Ryoo, R. Characterization of the Porous Structure of SBA-15. Chem. Mater. 2000, 12, 1961.
31. Margolese, D. I.; Melero, J. A.; Christiansen, S. C.; Chmelka, B. F.; Stucky, G. D. Direct Syntheses of Ordered SBA-15 Mesoporous Silica Containing Sulfonic Acid Groups. Chem. Mater. 2000, 12, 2448.
32. Diaz, I.; Marquez-Alvarez, C.; Mohino, F.; Perez-Pariente, J.; Sastre, E. Combined Alkyl and Sulfonic Acid Functionalization of MCM-41 Type Silica Part 1. Synthesis and Characterization. J. Catal. 2000, 193, 283.
33. Koujout, S.; Brown, D. R. The Influence of Solvent on the Acidity and Activity of Supported Sulfonic Acid Catalysts. Catal. Lett. 2004, 98, 195.
34. Freedman, B.; Butterfield, R. O.; Pryde, E. H. Transesterification Kinetics of Soybean Oil. J. Am. Oil Chem. Soc. 1986, 63, 1375.
35. Formo, M. W.; Jungermann, E.; Norris, F. A.; Sonntag, N. O. V. Bailey's Industrial Oil and Fat Products, 4th ed.; John Wiley & Sons: New York, 1979; p 500.