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33646458270
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note
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(a) Note: Mass spectroscopy detects the formation of carbene cation radicals from α-diazocarbonyl compounds in the gas phase. Furthermore, mass spectroscopic detection of charged Fischer-type copper and silver α-heterocarbenoid intermediates during the metal-mediated Wolff-rearrangement of diazomalonate has been reported recently (see the Supporting Information, SI-6.2).
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33646450591
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25
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33646449991
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note
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n (not shown in Scheme 1).
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