Gas-phase synthesis of charged copper and silver Fischer carbenes from diazomalonates: Mechanistic and conformational considerations in metal-mediated Wolff rearrangements

Journal of the American Chemical Society

Volumn 125, Issue 15, 2003, Pages 4478-4486

  Julian, Ryan R ^a   May, Jeremy A ^b   Stoltz, Brian M ^b   Beauchamp, J L ^a  

^a CALIFORNIA INSTITUTE OF TECHNOLOGY   (United States)

^b CALIFORNIA INSTITUTE OF TECHNOLOGY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON MONOXIDE; CONFORMATIONS; DISCRETE FOURIER TRANSFORMS; IONS; SILVER COMPOUNDS; SYNTHESIS (CHEMICAL);

CARBENES;

COPPER COMPOUNDS;

CARBENOID; CARBON MONOXIDE; COORDINATION COMPOUND; COPPER; DIAZOMALONATE DERIVATIVE; DIAZONIUM COMPOUND; FUNCTIONAL GROUP; ION; METAL; NITROGEN; PROTON; SILVER; UNCLASSIFIED DRUG;

ARTICLE; CALCULATION; CONFORMATION; ENERGY TRANSFER; GAS; IONIZATION; ISOTOPE LABELING; MOLECULAR STABILITY; OSCILLATION; PRECURSOR; REACTION ANALYSIS; SURFACE CHARGE; SYNTHESIS; WOLFF REARRANGEMENT;

EID: 0037448918     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja028337j     Document Type: Article

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