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Volumn 128, Issue 16, 2006, Pages 5334-5335

Synthesis and structure of a nucleoside with π-conjugated nitroxide spin label forming a one-dimensional ferromagnetic chain

Author keywords

[No Author keywords available]

Indexed keywords

DEOXYURIDINE; DNA BASE; FERROMAGNETIC MATERIAL; NITROXIDE; NUCLEOSIDE;

EID: 33646451702     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja060846o     Document Type: Article
Times cited : (24)

References (23)
  • 8
    • 0037733942 scopus 로고    scopus 로고
    • Iminoyl nitroxide connected to uradinyl, with no significant spin delocalization into the base moiety: Taylor, P.; Serwinski, P. R.; Lahti, P. M. Chem. Commun. 2003, 1400-1401.
    • (2003) Chem. Commun. , pp. 1400-1401
    • Taylor, P.1    Serwinski, P.R.2    Lahti, P.M.3
  • 13
    • 33646440878 scopus 로고    scopus 로고
    • note
    • The angles between the least-squares planes of a nitroxide moiety and p-phenylene, and p-phenylene and uracyl are 6.8(0.4)° and 28.5(0.1)°, respectively.
  • 14
    • 33646454125 scopus 로고    scopus 로고
    • note
    • (a) Using a model compound 9 (Figures S6-S9, Supporting Information), in which the deoxyribose moiety is replaced with a methyl group, spin densities of 0.04, -0.03, and 0.005 at the atoms corresponding to C6, C5, and O2 in 1 are calculated at the UB3LYP/6-31(d) level, respectively.
  • 15
    • 0038626673 scopus 로고    scopus 로고
    • Gaussian, Inc.: Wallingford CT
    • (b) Frisch, M. J.; et al. Gaussian 03; Gaussian, Inc.: Wallingford CT, 2004.
    • (2004) Gaussian 03
    • Frisch, M.J.1
  • 16
    • 33646454730 scopus 로고    scopus 로고
    • note
    • -1 are obtained.
  • 20
    • 33646457541 scopus 로고    scopus 로고
    • note
    • 1/2kT.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.