Thermally induced saccharinate ligand flips close to ambient temperature

Crystal Growth and Design

Volumn 6, Issue 4, 2006, Pages 815-817

  Naumov, Panče ^a   Jovanovski, Gligor ^b   Sakurai, Kenji ^a  

^a NATIONAL INSTITUTE FOR MATERIALS SCIENCE   (Japan)

^b SS CYRIL AND METHODIUS UNIVERSITY   (Macedonia)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 33646363568     PISSN: 15287483     EISSN: None     Source Type: Journal    
DOI: 10.1021/cg050468j     Document Type: Article

References (34)

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31. DSC experimental conditions: instrument EXTAR6000 (SII), dynamic nitrogen atmosphere, Pt crucibles, sample weight: 3-4 mg. The thermal measurements of the samples were started from ambient temperature, in flow of nitrogen gas. The samples were first cooled and then heated, and then this cycling was repeated. The same procedure was repeated with a fresh sample for each temperature rate: 2, 5, and 10 K/min.
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34. 2) bond (deposited as Figure S1, Supporting Information) mirrors the change of the length of the C1-O1 bond, which may be an indication for possible correlation during the refinement between the positions of the adjacent C1 and C2. Although this does not contrast the flipping motion, it would introduce further bias to the populations of the two components estimated from the refinement. Therefore, for the ratio of the two components we chose to rely on the qualitative conclusions based on the alteration of the difference electron density, rather than on the values obtained by the above refinement.