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Volumn 110, Issue 14, 2006, Pages 7519-7527

The role of excited Rydberg states in electron transfer dissociation

Author keywords

[No Author keywords available]

Indexed keywords

BINDING ENERGY; DISSOCIATION; ELECTRON TRANSITIONS; ELECTRONIC STRUCTURE; POSITIVE IONS;

EID: 33646244990     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp0604701     Document Type: Article
Times cited : (57)

References (34)
  • 4
    • 0036911329 scopus 로고    scopus 로고
    • Much of the pioneering work aimed at understanding the mechanism(s) by which ECD operates has been reported in ref 1 and by the Turecek and Uggerud groups in, for example
    • (d)Zubarev, R. A.;Haselmann, K. F.; Budnik, B.; Kjeldsen, F.; Jensen, F. Eur. J. Mass Spectrom. 2002, 8, 337. Much of the pioneering work aimed at understanding the mechanism(s) by which ECD operates has been reported in ref 1 and by the Turecek and Uggerud groups in, for example:
    • (2002) Eur. J. Mass Spectrom. , vol.8 , pp. 337
    • Zubarev, R.A.1    Haselmann, K.F.2    Budnik, B.3    Kjeldsen, F.4    Jensen, F.5
  • 23
    • 84906368895 scopus 로고    scopus 로고
    • note
    • The energy defects (A) pertinent to the species studied here are > 1 eV, which greatly exceeds the thermal collision energies used in most ETD experiments, so this assumption is valid.
  • 24
    • 84906397686 scopus 로고    scopus 로고
    • note
    • 2 and display quadratic rather than cubic dependence on the cation's charge (Z).
  • 29
    • 84906368894 scopus 로고    scopus 로고
    • See, for example, the description offered in ref 8
    • See, for example, the description offered in ref 8.
  • 32
    • 84906397683 scopus 로고    scopus 로고
    • note
    • This is done to keep the Coulomb stabilization of the S-S σ* orbital constant and to attempt to represent the effect a disulfide linkage in a peptide would experience in the presence of a protonated side chain whose charge center is geometrically constrained.
  • 33
    • 84906383245 scopus 로고    scopus 로고
    • note
    • Our basis of 1s and 1p extra diffuse functions limits us to only the ground and three excited states.
  • 34
    • 84906397684 scopus 로고    scopus 로고
    • note
    • 1,2 matrix element.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.