Quantitative determination of ciprofloxacin and norfloxacin in pharmaceutical preparations by high performance liquid chromatography

Revista Brasileira de Ciencias Farmaceuticas/Brazilian Journal of Pharmaceutical Sciences

Volumn 41, Issue 4, 2005, Pages 507-513

  Kassab, Nájla Mohamad ^a   Singh, Anil Kumar ^a   Kedor Hackmam, Erika Rosa Maria ^a   Santoro, Maria Inês Rocha Miritello ^a  

^a UNIVERSITY OF SÃO PAULO   (Brazil)

Author keywords

Ciprofloxacin; Liquid chromatography; Norfloxacin; Pharmaceutical preparations; Quantitative determination

Indexed keywords

ACETONITRILE; CIPROFLOXACIN; NORFLOXACIN; PHOSPHORIC ACID; QUINOLINE DERIVED ANTIINFECTIVE AGENT; TRIETHYLAMINE;

ARTICLE; CALIBRATION; DRUG SYNTHESIS; FLOW RATE; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; PH; QUANTITATIVE ANALYSIS; ROOM TEMPERATURE; TABLET FORMULATION; VALIDATION PROCESS;

EID: 33646230546     PISSN: 15169332     EISSN: None     Source Type: Journal    
DOI: 10.1590/S1516-93322005000400014     Document Type: Article

References (33)

1. ARTESEROS, J.A.H.; BARBOSA, J.; COMPANO, R.; PRAT, M.D. Analysis of quinolone residues in edible animal products. J. Chromatogr. A, Amsterdam, v.945, p.1-24, 2002.
2. ASSOCIATION OF OFFICIAL ANALYTICAL CHEMISTS INTERNATIONAL. Official methods of analysis of AOAC International, 17 ed. Gaithersburg: AOAC, 2002. v.1, p.xx.
3. BARBOSA, J.; BERGES, R.; SANZ-NEBOT, V. Solvatochromic parameter values and pH in aqueous-organic mixture and use in liquid chromatography. Prediction of retention of series of quinolones. J. Chromatogr., A, Amsterdam, v.719, p.27-36, 1996.
4. BELAL, F.; AL-MAJED, A.A.; AL-OBAID, A.M. Methods of analysis of 4-quinolone antibacterials. Talanta, Amsterdam, v.50, n.4. p.765-786, 1999.
5. BERTINO, J.; FISH, D. Safety profiles of the fluoroquinolones. Clin. Ther., Hillsborough, v.22, p.798-817, 2000.
6. BHOWAL, S.K.; DAS, T.K. Spectrophotometric determination of same recently introduced antibacterial drugs using ferric chloride. Anal. Lett., New York, v.24, p.25-37, 1991.
7. BRITISH pharmacopoeia 1999. London: Her Majesty's Stationery Office, 1999. p.369-370, 1034-1035.
8. BUDVARI-BARANY, Z.S.; SZASZ, G.Y.; TAKACSNOVAK, K.; HERMECZ, I.; LORE, A. The pH influence on the HPLC-retention of chemotherapeutic fluorquinolone derivatives. J. Liq. Chromatogr., New York, v.14, p.3411-3424, 1991.
9. CHOWDARY, K.P.R.; RAO, G.D. Spectrophotometric method for the determination of lomefloxacino hydrochroride. Indian Drugs, Mumbai, v.34, p.107-108, 1997.
10. CORDOBA-BORREGO, M.; CORDOBA-DIAZ, M.; CORDOBA-DIAZ, D. Validation of high-performance liquid chromatographic method for the determination of norfloxacin and its application to stability studies (photo-stability study of norfloxacin). J. Pharm. Biomed. Anal., Amsterdam, v.18, p.919-926, 1999.
11. FIERENS C.; HILLAER T. S.; VAN DEN BOSSCHE W. The qualitative and quantitative determination of quinolones of first and second generation by capillary electrophoresis. J. Pharm. Biomed. Anal., Amsterdam, v.22, p.763-772, 2000.
12. FLURER, C.L. Analysis of antibiotics by capillary electrophoresis. Electrophoresis, Weinheim, v.18, p.2427-2437, 1997.
13. FRATINI, L.; SCHAPOVAL, E.E.S. Ciprofloxacin determination by visible light spectrophotometry using iron(III) nitrate. Int. J. Pharm., Amsterdam, v.127, p.279-282, 1996.
14. HARRIS, D.C. Métodos de calibração. In: -. Análise química quantitativa. 5.ed. Rio de Janeiro: Livros Técnicos e Científicos, 2001. p.81-95.
15. HUSAIN, S.; KHALID, S.; NAGARAJU, V.; RAO, R.N. High-performance liquid chromatographic separation and determination of small amounts of process impurities of ciprofloxacin in bulk drugs formulations. J. Chromatogr., A, Amsterdam, v.705, p.380-384, 1995.
16. JOSHI, S. HPLC separation of antibiotics present in formulated and unformulated samples. J. Pharm. Biomed. Anal., Amsterdam, v.28, p.795-809, 2002.
17. KIRKLAND, K.M.; MCCOMBS, D.A.; KIRKLAND, J.J. Rapid, high-resolution high-performance liquid chromatography of antibiotics. J. Chromatogr., A, Amsterdam, v.660, p.327-337, 1994.
18. LACROIX, P.M.; CURRAN, N.M.; SEARS, R.W. High-pressure liquid chromatographic methods for ciprofloxacin hydrochloride and related compounds in raw materials. J. Pharm. Biomed. Anal., Amsterdam, v.14, p.641-654, 1996.
19. LEITE, F. Validação em análise química. 4.ed. São Paulo: Atomo, 2002. p.69-72.
20. LORIAN, V. Antibiotics in Laboratory Medicine. 4.ed. Baltimore: Williams & Wilkins, 1996. p.591-592.
21. MANDEL, G.I.; PETRI JUNIOR, W.A. Antimicrobial agents: sulfonamides, trimethoprim-sulfamethoxazole, quinolones, and agents for tract infections. In: Goodman & Gilman's: The pharmacological basis of therapeutics. 9. ed. New York: Mcgraw-Hill, 1996. p.1065-1068.
22. MARZO, A.; DAL BO, L. Chromatography as an analytical tool for selected antibiotic classes: a reappraisal addressed to pharmacokinetic applications. J. Chromatogr. A, Amsterdam, v.812, p.17-34, 2002.
23. MAZUEL, C. Norfloxacin. Anal. Profiles Drug Subst. Excipients, San Diego, v.20, p.557-600, 1991.
24. MORLEY, J.A.; EROLD Jr., L. Determination of fluorquinolne antibacterial as N-Acyl derivatives. Chromatographia, Wiesbaden, v.37, p.295-299, 1993.
25. SAMANIDOU, V.F.; CHRISTODOULOU, E.A.; PAPADOYANNIS, I.N. Determination of fluoroquinolones in edible animal tissue samples by high performance liquid chromatography after solid phase extraction. J. Sep. Sci., Weinheim, v.28, p.555-565, 2005.
26. SAMANIDOU, V.F.; DEMETRIOU, C.E.; PAPADOYANNIS, I.N. Direct determination of four fluoroquinolones, enoxacin, norfloxacin, ofloxacin, and ciprofloxacin, in pharmaceuticals and blood serum by HPLC. Anal Bioanal. Chem., Heidelberg, v.375, p.623-629, 2003.
27. SOWINSKI, K.M.; KAYS, M.B. Determination of ciprofloxacin concentrations in human serum and urine by HPLC with ultraviolet and fluorescence detection. J. Clin. Pharm. Ther., Oxon, v.29, p.381-387, 2004.
28. SUN, S.-W.; CHEN, L.-Y. Optimization of capillary electrophoretic separation of quinolones antibacterials using the overlapping resolution mapping scheme. J. Chromatogr., A, Amsterdam, v.766, p.215-224, 1997.
29. THOPPIL, S.O.; AMIN, P.D. Stability indicating reversed-phase liquid chromatographic determination of ciprofloxacin as bulk drug and in pharmacetical formulations. J. Pharm. Biomed. Anal., Amsterdam, v.22, p.699-703, 2000.
30. TIEFENBACHER, E.M.; HAEN, E.; PRZYBILLA, B.; KURZ, H. Photodegradation of some quinolones used as antimicrobial therapeutics. J. Pharm. Biomed. Anal., Amsterdam, v.83, p.463-467, 1994.
31. TORNIAINEN, K.; TAMMILEHTO, S.; ULVI, V. The effect of pH, buffer type and drug concentration on the photodegradation of ciprofloxacin. Int. J. Pharm., Amsterdam, v.132, p.53-61, 1996.
32. UNITED States Pharmacopeia. 27.ed. Rockville: United States Pharmacopeial Convention, 2004. p.454-457, 1342-1343.
33. VYBIRALOVA, Z.; NOBILIS, M.; ZOULOVA, J.; KVETINA, J.; PETR, P. High-performance liquid chromatographic determination of ciprofloxacin in plasma samples. J. Pharm. Biomed. Anal., Oxford, v.37, p.851-858, 2005.