Reaction rate of the production of dimethyl carbonate directly from the supercritical CO2 and methanol

Journal of Chemical Engineering of Japan

Volumn 38, Issue 12, 2005, Pages 1020-1024

  Iwakabe, Koichi ^a   Nakaiwa, Masaru ^b   Sakakura, Toshiyasu ^b   Choi, Jun Chul ^b   Yasuda, Hiroyuki ^b   Takahashi, Toshikazu ^b   Ooshima, Yoshihiro ^c,d  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

^b Research Institute for Innovation in Sustainable Chemistry   (Japan)

^c CHUO UNIVERSITY   (Japan)

^d UNIVERSITY OF TSUKUBA   (Japan)

Author keywords

CO2; Reaction rate; Supercritical fluid; Water removal

Indexed keywords

CARBON DIOXIDE; CARBONATES; CATALYSTS; CHEMICAL REACTIONS; DEHYDRATION; METHANOL; PRESSURE EFFECTS; REMOVAL; SUPERCRITICAL FLUIDS;

DIMETHYL CARBONATE; FLOW TYPE REACTOR; LINEAR PRESSURE DEPENDENCE; REACTION PRESSURE; SEMI-BATCH REACTOR; TIN LIQUID CATALYST;

CHEMICAL REACTORS;

CARBON DIOXIDE; CARBONATES; CATALYSTS; CHEMICAL REACTIONS; CHEMICAL REACTORS; DEHYDRATION; METHANOL; PRESSURE EFFECTS; REMOVAL; SUPERCRITICAL FLUIDS;

EID: 33646200323     PISSN: 00219592     EISSN: 00219592     Source Type: Journal    
DOI: 10.1252/jcej.38.1020     Document Type: Article

References (4)

1. 2," J. Supercrit. Fluid, 25, 19-32 (2003)
2. Choi, J.-C., L.-N. He, H. Yasuda and T. Sakakura; "Selective and High Yield Synthesis of Dimethyl Carbonate Directly from Carbon Dioxide and Methanol," Green Chemistry, 4, 230-234 (2002)
3. Dahl, S. and M. L. Michelsen; "High-Pressure Vapor-Liquid Equilibrium with a UNIFAC-Based Equation of State," AIChE J., 36, 1829-1836 (1990)
4. Pacheco, M. A. and C. L. Marshall; "Review of Dimethyl Carbonate (DMC) Manufacture and Its Characteristics as a Fuel Additive, " Energy Fuels, 11, 2-29 (1997)