Adsorption mechanism in reversed-phase liquid chromatography. Effect of the surface coverage of a monomeric C18-silica stationary phase

Journal of Chromatography A

Volumn 1115, Issue 1-2, 2006, Pages 142-163

  Gritti, Fabrice ^a,b   Guiochon, Georges ^a,b  

^a UNIVERSITY OF TENNESSEE   (United States)

^b OAK RIDGE NATIONAL LABORATORY   (United States)

Author keywords

Adsorbent heterogeneity; Adsorption energy distribution; C18 bonding density; Caffeine; Endcapping; Frontal analysis; Isotherm; Phenol; Retention mechanism; RPLC; Silica C18; Sodium 2 naphthalene sulfonate

Indexed keywords

ADSORPTION; ISOTHERMS; MOLECULAR WEIGHT; PHENOLS; SILICA;

ADSORBENT HETEROGENEITY; ADSORPTION ENERGY DISTRIBUTION; C18 BONDING DENSITY; CAFFEINE; ENDCAPPING; FRONTAL ANALYSIS; RETENTION MECHANISM; RPLC; SILICA-C18; SODIUM 2-NAPHTHALENE SULFONATE;

LIQUID CHROMATOGRAPHY;

CAFFEINE; CARBON 18; METHANOL; PHENOL; RADIOISOTOPE; SILICON DIOXIDE; SODIUM 2 NAPHTHALENE SULFONATE; SULFONIC ACID DERIVATIVE; UNCLASSIFIED DRUG; WATER;

ADSORPTION; ARTICLE; CALCULATION; CHROMATOGRAPHY; ENTHALPY; ENTROPY; EQUILIBRIUM CONSTANT; ISOTHERM; MOLECULAR WEIGHT; PRIORITY JOURNAL; REVERSED PHASE LIQUID CHROMATOGRAPHY; TEMPERATURE;

ADSORPTION; CAFFEINE; CHROMATOGRAPHY, LIQUID; METHANOL; NAPHTHALENESULFONATES; PHENOL; REPRODUCIBILITY OF RESULTS; SILICON DIOXIDE; WATER;

EID: 33646157283     PISSN: 00219673     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.chroma.2006.02.095     Document Type: Article

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