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note
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Annealing at temperatures higher than 70°C sometimes caused a detachment of the films from the substrate. In view of the fact that the reorganization process occurs below the glass transition temperature of PS, annealing at 70°C in water for a long time (more than 2 h) seems to be sufficient for the purpose of the reorganization process.
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33646004025
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note
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The sample holder possessing a large thermal mass was heated to 60°C before inserting the sample mounted on a small copper carrier block. Owing to the small thermal mass of the sample and its carrier, the sample temperature increased within a few minutes from room temperature to 60°C, i.e., significantly faster than the observed time constant of the surface reorganization.
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