Smart polymer surfaces

Macromolecules

Volumn 36, Issue 6, 2003, Pages 1994-1999

  Anastasiadis, Spiros H ^a,b   Retsos, Haris ^a,b,e   Pispas, Stergios ^c   Hadjichristidis, Nikos ^c   Neophytides, Stylianos ^d  

^a INSTITUTE OF ELECTRONIC STRUCTURE AND LASER   (Greece)

^b UNIVERSITY OF CRETE   (Greece)

^c UNIVERSITY OF ATHENS   (Greece)

^d INSTITUTE OF CHEMICAL ENGINEERING SCIENCES   (Greece)

^e University of California   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BIOTECHNOLOGY; HYDROPHILICITY; INTERFACES (MATERIALS); INTERFACIAL ENERGY; SELF ASSEMBLY; SURFACE TENSION; WETTING;

SURFACE PARTITIONING;

COPOLYMERS;

EID: 0037465861     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma0211129     Document Type: Article

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36. The instrument described in ref 29 has been commercialized by Materials Interface Associates.
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40. The surface tension of PS/additive mixtures was measured at 140 °C using a low molecular weight polystyrene homo-polymer (PS-2) as the matrix. The surface tension of PS-2 is 30.8 ± 0.3 mN/m, whereas the surface tensions at interfacial saturation of the mixtures are 27.2 ± 0.2 mN/m for PS-2/ D-2 (with methyl end groups), 27.1 ± 0.2 mN/m for PS-2/ NIS-31, and 27.2 ± 0.3 mN/m for PS-2/ZIS-31.
41. 25 these adsorbed amounts z* are 7 nm for 2 wt % of NIS-31, 17 nm for 5 wt % of NIS-31, 6 nm for 5 wt % of ZIS-31, 8 nm for 10 wt % of ZIS-31, and 7 nm for 10 wt % of ZIS-25.
42. For the molecular weights and the concentrations used in the present work, a calculation for the critical micelle concentration based on the theoretical expressions for the chemical potentials used in ref 31 and neglecting the effects of the end groups (amine and sulfozwitterionic) indicates that micelles will not be present for NIS-31, NIS-25, ZIS-31, and ZIS-25 whereas they will be present for NIS-49, NIS-72, ZIS-49, and ZIS-72. The work of ref 31 pointed out at the importance of micellization on interfacial partitioning.
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45. Following extensive exposure to water vapor (20 and 25 days), a second peak appears in the S 2p binding energy range at about 162 eV, which corresponds to elemental sulfur probably due to surface contamination or decomposition of the sulfozwitterion. At the same time, the N Is peak becomes very broad and weak.