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Volumn 348, Issue 4-5, 2006, Pages 439-442

A bimetallic ruthenium complex as a catalyst precursor for the atom transfer radical polymerization of methacrylates at ambient temperature

Author keywords

Acrylates; Bimetallic complex; Polymerization; Radical reaction; Ruthenium

Indexed keywords


EID: 33645937951     PISSN: 16154150     EISSN: 15213897     Source Type: Journal    
DOI: 10.1002/adsc.200505318     Document Type: Article
Times cited : (33)

References (40)
  • 4
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    • K. Matyjaszwski, (Ed.), ACS Symposium Series No. 854, ACS, Washington
    • a) K. Matyjaszwski, (Ed.), Advances in Controlled/Living Radical Polymerization, ACS Symposium Series No. 854, ACS, Washington, 2003;
    • (2003) Advances in Controlled/Living Radical Polymerization
  • 12
    • 0038373084 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2003, 42, 2876-2879;
    • (2003) Angew. Chem. Int. Ed. , vol.42 , pp. 2876-2879
  • 29
    • 33645917514 scopus 로고    scopus 로고
    • note
    • -3. Structure solution and refinement by SHELX97 [G. M. Sheldrick, SHELX97, Programs for Crystal Structure Analysis, University of Göttingen, Göttingen/Germany, 1998). H atoms were placed in calculated positions using the riding model. CCDC 280924 contains supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/ const/retrieving.html [or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB21EZ, UK; fax: (+44)1223-336-033; or deposit@ccdc.cam.ac.uk].
  • 34
    • 1642426891 scopus 로고    scopus 로고
    • and references cited
    • e) K. Severin, Chem. Eur. J. 2002, 8, 1514-1518, and references cited.
    • (2002) Chem. Eur. J. , vol.8 , pp. 1514-1518
    • Severin, K.1
  • 35
    • 33646767009 scopus 로고    scopus 로고
    • ORTEP 3 for Windows version 1.076
    • ORTEP 3 for Windows version 1.076: L. J. Farrugia, J. Appl. Cryst. 1997, 30, 565.
    • (1997) J. Appl. Cryst. , vol.30 , pp. 565
    • Farrugia, L.J.1
  • 36
    • 33645905910 scopus 로고    scopus 로고
    • note
    • Increased temperatures were found to be detrimental for the reaction: when the polymerization was performed at 80°C, the reaction slowed down significantly over the first 2 h and no complete conversion was observed. This can be attributed to the faster decomposition of the catalyst at higher temperatures.
  • 39
    • 4444355976 scopus 로고    scopus 로고
    • Some copper complexes also are able to catalyze the ATRP of MMA at ambient temperatures but the catalyst concentrations are higher as well (MMA:Cu ∼100:1), see, for example: a) D. P. Chatterjee, U. Chatterjee, B. M. Mandal, J. Polym. Sci. Part A, 2004, 42, 4132-4142;
    • (2004) J. Polym. Sci. Part A , vol.42 , pp. 4132-4142
    • Chatterjee, D.P.1    Chatterjee, U.2    Mandal, B.M.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.