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For some recent examples of Ru catalysts for ATRP reactions, see: a) L. Quebatte, M. Haas, E. Solari, R. Scopelliti, Q. T. Nguyen, K. Severin, Angew. Chem. Int. Ed. 2005, 44, 1084-1088;
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33645917514
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note
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-3. Structure solution and refinement by SHELX97 [G. M. Sheldrick, SHELX97, Programs for Crystal Structure Analysis, University of Göttingen, Göttingen/Germany, 1998). H atoms were placed in calculated positions using the riding model. CCDC 280924 contains supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/ const/retrieving.html [or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB21EZ, UK; fax: (+44)1223-336-033; or deposit@ccdc.cam.ac.uk].
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For some recent publications about mixed, halogen-bridged complexes, see: a) S. Gauthier, R. Scopelliti, K. Severin, Helv. Chim. Acta 2005, 88, 435-446;
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33645905910
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note
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Increased temperatures were found to be detrimental for the reaction: when the polymerization was performed at 80°C, the reaction slowed down significantly over the first 2 h and no complete conversion was observed. This can be attributed to the faster decomposition of the catalyst at higher temperatures.
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4444355976
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Some copper complexes also are able to catalyze the ATRP of MMA at ambient temperatures but the catalyst concentrations are higher as well (MMA:Cu ∼100:1), see, for example: a) D. P. Chatterjee, U. Chatterjee, B. M. Mandal, J. Polym. Sci. Part A, 2004, 42, 4132-4142;
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Shooter, A.J.5
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