Reduction of 1,4-dien-3-one steroids with LiAl2H4 or NaB2H4: Stereospecific deuterium-labeling at the C-1α position of a 4-en-3-one steroid

Chemical and Pharmaceutical Bulletin

Volumn 54, Issue 4, 2006, Pages 554-556

  Numazawa, Mitsuteru ^a   Handa, Wakako ^a  

^a TOHOKU PHARMACEUTICAL UNIVERSITY   (Japan)

Author keywords

1,4 dien 3 one steroid; 1 2H testosterone; Deuterium labeling; Lithium aluminum deuteride; Reduction; Sodium borodeuteride

Indexed keywords

1,4 DIEN 3 ONE; 17BETA TERT BUTYLDIMETHYLSILOXYANDROSTA 1,4 DIEN 3 ONE; 4 EN 3 ONE; [1ALPHA 2H]17BETA BUTYLDIMETHYLSILOXYANDROSTA 4 EN 3 ONE; [1ALPHA 2H]TESTOSTERONE; ALUMINUM; BOLDENONE; DEUTERIUM; LITHIUM; SODIUM; STEROID; UNCLASSIFIED DRUG;

AROMATIZATION; ARTICLE; CHEMICAL BINDING; DRUG STRUCTURE; ISOTOPE LABELING; KETOGENESIS; STEREOSPECIFICITY; STEROID BINDING; STEROIDOGENESIS;

ALUMINUM COMPOUNDS; BOROHYDRIDES; DEUTERIUM; ISOTOPE LABELING; KETONES; LITHIUM COMPOUNDS; MAGNETIC RESONANCE SPECTROSCOPY; METHANOL; MODELS, CHEMICAL; OXIDATION-REDUCTION; STEREOISOMERISM; STEROIDS; TESTOSTERONE; WATER;

EID: 33645553851     PISSN: 00092363     EISSN: 13475223     Source Type: Journal    
DOI: 10.1248/cpb.54.554     Document Type: Article

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