Reaction kinetics of the homogeneously catalyzed esterification of 1-butanol with acetic acid in a wide range of initial compositions

Industrial and Engineering Chemistry Research

Volumn 45, Issue 6, 2006, Pages 1869-1874

  Grob, Sascha ^a   Hasse, Hans ^a  

^a UNIVERSITY OF STUTTGART   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ACETIC ACID; ALCOHOLS; CATALYSIS; CATALYST ACTIVITY; CHEMICAL ANALYSIS; COMPOSITION; CONCENTRATION (PROCESS); CORRELATION METHODS; MATHEMATICAL MODELS; NUCLEAR MAGNETIC RESONANCE; RATE CONSTANTS; REACTION KINETICS;

BATCH REACTORS; BUTANOL; DATA CORRELATIONS; LIQUID PHASE;

ESTERIFICATION;

ACETIC ACID; ALCOHOLS; CATALYSIS; CATALYST ACTIVITY; CHEMICAL ANALYSIS; COMPOSITION; CONCENTRATION (PROCESS); CORRELATION METHODS; ESTERIFICATION; MATHEMATICAL MODELS; NUCLEAR MAGNETIC RESONANCE; RATE CONSTANTS; REACTION KINETICS;

EID: 33645522260     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie050789s     Document Type: Article

References (29)

1. Schmitt, M.; Hasse, H. Chemical equilibrium and reaction kinetics of auto- and heterogeneously catalyzed rc-hexyl acetate esterification. Ind. Eng. Chem. Res., submitted for publication, 2005.
2. Grob, S.; Hasse, H. Thermodynamics of Equilibrium in a Strongly Non-Ideal Reactive System. J. Chem. Eng. Data 2005, 50, 92-101.
3. Leyes, C. E.; Othmer, D. F. Esterification of Butanol and Acetic Acid. Ind. Eng. Chem. 1945, 37, 968-977.
4. Hartig, H.; Regner, H. Verfahrenstechnische Auslegung einer Veresterungskolonne. Chem.-Ing.-Tech. 1971, 43, 1001-1048.
5. Steinigeweg, S.; Gmehling, J. n-Butyl Acetate Synthesis via Reactive Distillation: Thermodynamic Aspects, Reaction Kinetics, Pilot-Plant Experiments, and Simulation Studies. Ind. Eng. Chem. Res. 2002, 41, 5483-5490.
6. Janowsky, R.; Groebel, M. J.; Knippenberg, U. Nichtlineare Dynamik bei der Reaktivdestillation-Phänomene und deren technische Nutzung (Abschlussbericht eines vom Bundesministerium für Bildung, Wissenschaft und Technologie geförderten Projekts mit dem Förderkennzeichen 03 D 0014 B0); Technischer Bericht, Hüls Infracor GmbH, experSCience: Paul-Baumann-Str. 1, D-45764 Marl, Germany, 1997.
7. Gomzi, Z.; Zrncevic, S. Esterification of n-Butanol with Acetic Acid Catalyzed by a Cation Exchange Resin. Croat. Chem. Acta 1980, 53, 25-32.
8. Gangadwala, J.; Mankar, S.; Mahajani, S.; Kienle, A.; Stein, E. Esterification of acetic acid with butanol in the presence of ion-exchange resins as catalysts. Ind. Eng. Chem. Res. 2003, 42, 2146-2155.
9. Hanika, J.; Kucharová, M.; Kolena, J.; Smejkal, Q. Multi-functional trickle bed reactor for butyl acetate synthesis. Catal. Today 2003, 79-80, 83-87.
10. Kekre, S.; Gopala, R. Kinetics of the liquid-phase esterification of n-butanol and acetic acid catalyzed by cation-exchange resins. Indian Chem. Eng. 1969, 11, 115-121.
11. Liao, A.; Tong, Z. Synthesis of n-butyl acetate catalyzed by Amberlyst. Chem. React. Eng, Technol. (Huaxue Fanying Gongcheng Yu Gongy) 1995, 11 (4), 406-408.
12. Parada, S. Reaktionskinetik der n-Butanol-Essigsäure-Veresterung. Report for Sulzer Chemtech, Winterthur/CH: 2002.
13. Venimadhavan, G.; Malone, M.; Doherty, M. A novel distillate policy for batch reactive distillation with application to the production of butyl acetate. Ind. Eng. Chem. Res. 1999, 38, 714-722.
14. Blagov, S.; Parada, S.; Bailer, O.; Moritz, P.; Lam, D.; Weinand, R.; Hasse, H. Influence of ion-exchange resin catalysts on side reactions of the esterification of n-butanol with acetic acid. Chem. Eng. Sci. 2006, 61, 753-765.
15. Al-Saadi A. N.; Jeffreys, G. V. Esterification of Butanol in a Two-Phase Liquid-Liquid System. AIChE J. 1981, 27, 754-773.
16. Blanco, M.; Serrano, D. On-line monitoring and quantification of a process reaction by near-infrared spectroscopy. Catalysed esterification of butan-1-ol by acetic acid. Analyst 2000, 125, 2059-2064.
17. Liao, S.; Xu, B.; Li, Z. Catalysis of solid acid catalyst for esterification (I), preparation and characterization of the catalyst. J. Mol. Catal. (China) 1993, 7 (6), 475-478.
18. Liao, S.; Zhange, X. Study on esterification catalyzed by solid acid catalyzed by solid acid catalyst (II). Kinetics and mechanism of liquid-phase esterification. J. S. China Univ. Technol. (Nat. Sci.) 1997, 25 (11), 88-92.
19. Zheng, R.; Zeng, J. Catalytic synthesis of butyl acetate by using strong acidic cation-exchange resin. J. Xiamen Univ. (Nat. Sci.) 1997, 36 (1), 67-70.
20. Zheng, R.; Zeng, J. Kinetics of esterification of acetic acid and n-butanol on strong cation-exchange resin. J. Xiamen Univ. (Nat. Sci.) 1998, 37 (2), 224-227.
21. Lilja, J.; Murzin, D. Y.; Salmi, T.; Aumo, J.; Mäki-Arvela, P.; Sundell, M. Esterification of different acids over heterogeneous and homogeneous catalysts and correlation with the Taft equation. J. Mol. Catal. A 2002, 182-183, 555-563.
22. Maiwald, M.; Fischer, H. H.; Ott, M.; Peschla, R.; Kuhnert, C.; Kreiter, C. G.; Maurer, G.; Hasse, H. Quantitative NMR Spectroscopy of Complex Liquid Mixtures: Methods and Results for Chemical Equilibria in Formaldehyde-Water- Methanol at Temperatures up to 383 K. Ind. Eng. Chem. Res. 2003, 42, 259-266.
23. Grob, S. Experimentelle Untersuchung und Modellierung von Reaktion und Phasengleichgewicht am Beispiel des Stoffsystems n-Butanol-Essigsäure-n- Butylacetat-Wasser. Ph.D. Thesis, University of Stuttgart, Germany, 2004 (available on the Internet: http://elib.unistuttgart.de/opus/volltexte/2004/ 1769).
24. Streitwieser, A.; Heathcock, C.; Kosower, E. Organische Chemie, 2. Auflage, übersetzt von S. Dehmlow, VCH Verlagsgesellschaft mbH: Weinheim, Germany, 1994.
25. Rönnback, R.; Salmi, T.; Vuori, A.; Haairo, H.; Lehtonen, J., Sundqvist, A., Tirronen, E. Development of a kinetic model for the esterification of acetic acid with methanol in the presence of a homogeneous acid catalyst. Chem. Eng. Sci. 1997, 52 (19), 3369-3381.
26. Abrams, D. S.; Prausnitz, J. M. Statistical Thermodynamics of Liquid Mixtures: A New Expression for the Excess Gibbs Energy of Partly or Completely Miscible Systems. AIChE J. 1975, 21 (1), 116-128.
27. Renon, H.; Prausnitz, J. M. Local Compositions in Thermodynamic Excess Functions for Liquid Mixtures, AIChE J. 1968, 14 (1), 135-144.
28. Gross, J.; Sadowski, G. Application of the Perturbed-Chain SAFT Equation of State to Associating Systems. Ind. Eng. Chem. Res. 2002, 41, 5510-5515.
29. Ung, S.; Doherty, M. Vapor-liquid-phase equilibrium in systems with multiple chemical reactions. Chem. Eng. Sci. 1995, 50 (1), 23-48.